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American Journal of Physics

A Development of the WKB Approximation by Use of Transformations

Ray Engelke

Published Apr 1, 1971• 0 citations
Publisher

Abstract

The WKB wavefunctions for one-dimensional nonrelativistic problems are derived by a simple transformation method. By applying the Liouville substitution to Schrödinger's equation and then neglecting certain “small” terms in the transformed equation, one arrives at the WKB solutions. The terms neglected in obtaining the WKB solutions are explicit. No asymptotic expansions are used in the derivation. Use of a known criterion from the theory of differential equations gives assurance that the WKB solutions are asymptotic to exact solutions of Schrödinger's equation in certain cases.

DOI
10.1119/1.1986170

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The WKB wavefunctions for one-dimensional nonrelativistic problems are derived by a simple transformation method. By applying the Liouville substitution to Schrödinger's equation and then neglecting certain “small” terms in the transformed equation, one arrives at the WKB solutions. The terms neglected in obtaining the WKB solutions are explicit. No asymptotic expansions are used in the derivation. Use of a known criterion from the theory of differential equations gives assurance that the WKB solutions are asymptotic to exact solutions of Schrödinger's equation in certain cases.
Solution of the Schrödinger's equation in the zero order WKB approximation is analyzed. We observe and investigate several remarkable features of the WKB0_00​ method. Solution in the whole region is built with the help of simple connection formulas we derive from basic requirements of continuity and finiteness for the wave function in quantum mechanics. We show that, for conservative quantum systems, not only total energy, but also momentum is the constant of motion. We derive the quantization conditions for two and more turning point problems. Exact energy eigenvalues for solvable and some ``insoluble'' potentials are obtained. The eigenfunctions have the form of a standing wave, Ancos⁡(knx+δn)A_n\cos(k_nx+δ_n)An​cos(kn​x+δn​), and are the asymptote of the exact solution.
In this chapter we study another very important and powerful approximation method, the so-called eikonal approximation or Wentzel-Kramer-Brillouin (WKB) method, which is used in studying quantum mechanical systems that are subjected to complicated potentials. This method can be used to find approximate solutions to differential equations where the highest derivative is multiplied by a small parameter. The WKB method gives approximate solution to the Schrödinger equation irrespective of its complicated potential and is mostly used to study one-dimensional systems and also the radial equations for higher-dimensional systems with rotational symmetry.
A method of approximating solutions of the one-dimensional Schr\"odinger equation is presented in this paper. The method closely resembles the usual WKB approximation. Whereas in the ordinary WKB method the exponential function is used as the basis of the approximation, in this paper the solutions of an arbitrary Schr\"odinger equation are used. The general advantage is that by proper choice of the arbitrary equation an improved approximation can be obtained. The method is illustrated by treating the potential well and potential barrier problems when there are two turning points. The approximations to the wave functions are continuous even across the turning points. The barrier transmission problem is treated uniformly for energies above and below the peak of the barrier.
The method of Froman and Froman for proving exact quantization conditions is reviewed. This formalism, unlike the usual WKB approximation to which it bears a close resemblance, requires consideration of the behavior of the potential everywhere it is defined. This approach leads to proofs that certain quantization conditions are exact without having to compare the results to solutions of the Schrödinger equation obtained by other means. Using the formalism, we prove the correctness of all previously known exact quantization rules for the one-dimensional and radial cases. Furthermore, it is shown that exact quantization rules can be proved for two other potentials. For one of these, no analytic solutions to the Schrödinger equation are known. For the latter case, the proof is checked by numerical integration of the Schrödinger equation for a special case.
Recently developed simple approach for the exact/approximate solution of Schrodinger equations with constant/position-dependent mass, in which the potential is considered as in the perturbation theory, is shown to be equivalent to the one leading to the construction of exactly solvable potentials via the solution of second-order differential equations in terms of known special functions. The formalism in the former solves difficulties encountered in the latter in revealing the corrections explicitly to the unperturbed piece of the solutions whereas the other obviate cumbersome procedures used in the calculations of the former.