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arXiv:quant-ph/0403177

An Exact Solution to the Time-dependent Schrodinger Equation for a Model One-dimensional Potential

A. Petridis, L. P. Staunton, Jon Vermedahl, Marshall Luban

Published Mar 24, 2004• 0 citations
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Abstract

Analytical solutions to the time-dependent Shrödinger equation in one dimension are developed for time-independent potentials, one consisting of an infinite wall and a repulsive delta function. An exact solution is obtained by means of a convolution of time-independent solutions spanning the given Hilbert space with appropriately chosen spectral functions. Square-integrability and the boundary conditions are satisfied. The probability for the particle to be found inside the potential well is calculated and shown to exhibit non-exponential decay decreasing at large times as $t^{-3}$. The result is generalized for all square-integrable solutions to this problem.

DOI
10.48550/arxiv.quant-ph/0403177

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We found a simple procedure for the solution of the time - independent Schrodinger equation in one dimension without making any approximation. The wave functions are always periodic. Two difficulties may be encountered: one is to solve the equation E=U(x), where E and U(x) are the total and potential energies, respectively, and the other is to calculate the integral of the square root of U(x). If these calculations cannot be made analytically, it should then be performed by numerical methods. To find the energy and the wave function of the ground state, there is no need to calculate this integral, it is sufficient to find the classical turning points, that is to solve the equation E=U(x).

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Analytical solutions to the time-dependent Shrödinger equation in one dimension are developed for time-independent potentials, one consisting of an infinite wall and a repulsive delta function. An exact solution is obtained by means of a convolution of time-independent solutions spanning the given Hilbert space with appropriately chosen spectral functions. Square-integrability and the boundary conditions are satisfied. The probability for the particle to be found inside the potential well is calculated and shown to exhibit non-exponential decay decreasing at large times as t−3t^{-3}t−3. The result is generalized for all square-integrable solutions to this problem.
The departure at large times from exponential decay in the case of resonance wavefunctions is mathematically demonstrated. Then, exact, analytical solutions to the time-dependent Schrödinger equation in one dimension are developed for a time-independent potential consisting of an infinite wall and a repulsive delta function. The exact solutions are obtained by means of a superposition of time-independent solutions spanning the given Hilbert space with appropriately chosen spectral functions for which the resulting integrals can be evaluated exactly. Square-integrability and the boundary conditions are satisfied. The simplest of the obtained solutions is presented and the probability for the particle to be found inside the potential well as a function of time is calculated. The system exhibits non-exponential decay for all times; the probability decreases at large times as . Other exact solutions found exhibit power law behavior at large times. The results are generalized to all normalizable solutions to this problem. Additionally, numerical solutions are obtained using the staggered leap-frog algorithm for select potentials exhibiting the prevalence of non-exponential decay at short times.
A simple procedure has been found for the general solution of the time-independent Schrödinger equation (SE) with the help of quantization of potential area in one dimension without making any approximation. Energy values are not dependent on wave functions. So, to find the energy values, it is enough to find the classic turning points of the potential function. Two different solutions were obtained, namely, symmetric and antisymmetric in bound states. These normalized wave functions are always periodic. It is enough to take the integral of the square root of the potential energy function to find the normalized wave functions. If these calculations cannot be made analytically, they should then be performed by numerical methods. The SE has been solved for a particle in many one-dimension and the spherical symmetric central potential wells as examples. Their energies and normalized wave functions were found as examples. These solutions were also applied to the theories of scattering and alpha decay. The results obtained with the experimental values were compared with the calculated values. One was seen to be very fit.
Total Absorption in Finite Time in an iδiδiδ Potential
We consider the evolution of Green's function of the one-dimensional Schrödinger equation in the presence of the complex potential −ikδ(x)-ikδ(x)−ikδ(x). Our result is the construction of an explicit time-dependent solution which we use to calculate the time-dependent survival probability of a quantum particle. The survival probability decays to zero in finite time, which means that the complex delta potential well is a total absorber for quantum particles. This potential can be interpreted as a killing measure with infinite killing rate concentrated at the origin.
We found a simple procedure for the solution of the time - independent Schrodinger equation in one dimension without making any approximation. The wave functions are always periodic. Two difficulties may be encountered: one is to solve the equation E=U(x), where E and U(x) are the total and potential energies, respectively, and the other is to calculate the integral of the square root of U(x). If these calculations cannot be made analytically, it should then be performed by numerical methods. To find the energy and the wave function of the ground state, there is no need to calculate this integral, it is sufficient to find the classical turning points, that is to solve the equation E=U(x).