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ACS Photonics

On-Demand Generation of Single Silicon Vacancy Defects in Silicon Carbide

Junfeng Wang, Qiang Li, Fei-Fei Yan, He Liu, Guo‐Ping Guo, Weiping Zhang, Xiong Zhou, Liping Guo, Zhi-Hai Lin, Jin‐Ming Cui, Xiao‐Ye Xu, Jin‐Shi Xu, Chuan‐Feng Li, Guang‐Can Guo

Published May 28, 2019• 96 citations
Publisher

Abstract

Defects in silicon carbide have been explored as promising spin systems in quantum technologies. However, for practical quantum metrology and quantum communication, it is critical to achieve on-demand single spin-defect generation. In this work, we present the generation and characterization of shallow silicon vacancies in silicon carbide by using different implanted ions and annealing conditions. The conversion efficiency of a silicon vacancy of helium ions is shown to be higher than that by carbon and hydrogen ions in a wide implanted fluence range. Furthermore, after optimizing the annealing conditions, the conversion efficiency can be increased more than 2 times. Due to the high density of the generated ensemble defects, the sensitivity of sensing a static magnetic field can be reached as high as, which is about 9 times smaller than previous results. By carefully optimizing implanted conditions, we further show that a single silicon vacancy array can be generated with a high conversion efficiency of about 80%. The results pave the way for using an on-demand-generated single silicon vacancy for quantum information processing and quantum photonics.

DOI
10.1021/acsphotonics.9b00451

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Defects in silicon carbide have been explored as promising spin systems in quantum technologies. However, for practical quantum metrology and quantum communication, it is critical to achieve on-demand single spin-defect generation. In this work, we present the generation and characterization of shallow silicon vacancies in silicon carbide by using different implanted ions and annealing conditions. The conversion efficiency of a silicon vacancy of helium ions is shown to be higher than that by carbon and hydrogen ions in a wide implanted fluence range. Furthermore, after optimizing the annealing conditions, the conversion efficiency can be increased more than 2 times. Due to the high density of the generated ensemble defects, the sensitivity of sensing a static magnetic field can be reached as high as, which is about 9 times smaller than previous results. By carefully optimizing implanted conditions, we further show that a single silicon vacancy array can be generated with a high conversion efficiency of about 80%. The results pave the way for using an on-demand-generated single silicon vacancy for quantum information processing and quantum photonics.
In this work the creation of silicon vacancy spin defects in silicon carbide with predictable properties is demonstrated. Neutron and electron irradiation was used to create silicon vacancy ensembles and proton beam writing to create isolated vacancies at a desired position. The coherence properties of the created silicon vacancies as a function of the emitter density were investigated and a power-law function established. Sample annealing was implemented to increase the coherence properties of existing silicon vacancies. Further, spectral hole burning was used to implement absolute dc-magnetometry.
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Abstract The negatively charged nitrogen-vacancy centre (so-called NV-centre) in diamond is one of the most promising systems for applications in quantum technologies because of the possibility to optically manipulate and read out the spin state of this defect, even at room temperature. Nevertheless, obtaining high NV densities (>500 ppb) close to the surface (5–20 nm) while maintaining good spin properties remain challenging. In this work we rely on a versatile ion implantation system allowing both implanting nitrogen using N 2 + and creating vacancies with He + ion bombardment at variable energies and fluence to create shallow NV ensembles. By optimizing the ion irradiation conditions as well as the surface preparation prior to treatment we successfully increase the amount of created colour centres while demonstrating narrow magnetic resonance linewidths.
In the past decade, color centers in silicon carbide (SiC) have emerged as promising platforms for various quantum information technologies. There are three main types of color centers in SiC: silicon-vacancy centers, divacancy centers, and nitrogen-vacancy centers. Their spin states can be polarized by laser and controlled by microwave. These spin defects have been applied in quantum photonics, quantum information processing, quantum networks, and quantum sensing. In this review, we first provide a brief overview of the progress in single-color center fabrications for the three types of spin defects, which form the foundation of color center-based quantum technology. We then discuss the achievements in various quantum sensing, such as magnetic field, electric field, temperature, strain, and pressure. Finally, we summarize the current state of fabrications and quantum sensing of spin defects in SiC and provide an outlook for future developments.
Solid-state color centers with manipulatable spin qubits and telecom-ranged fluorescence are ideal platforms for quantum communications and distributed quantum computations. In this work, we coherently control the nitrogen-vacancy (NV) center spins in silicon carbide at room temperature, in which telecom-wavelength emission is detected. We increase the NV concentration sixfold through optimization of implantation conditions. Hence, coherent control of NV center spins is achieved at room temperature, and the coherence time T_{2} can be reached to around 17.1 μs. Furthermore, an investigation of fluorescence properties of single NV centers shows that they are room-temperature photostable single-photon sources at telecom range. Taking advantage of technologically mature materials, the experiment demonstrates that the NV centers in silicon carbide are promising platforms for large-scale integrated quantum photonics and long-distance quantum networks.
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