In this chapter we shall present the basic postulates of quantum physics, generalizing the results obtained in the preceding chapter for the two special cases of photon polarization and spin 1/2. In general, the space of states will a priori have any dimension N, which may even be infinite, rather than only two dimensions. The postulates which we present in this chapter fix the general conceptual framework of quantum mechanics and do not directly provide the tools necessary for solving specific problems. The solution of a specific physical problem always involves a modeling stage, where the system to be studied is simplified, the approximations to be used are defined, and so on, and this modeling stage inevitably rests on more or less heuristic arguments which cannot be derived within the general framework of quantum physics. In Section 3.2.5 we gave an example of a heuristic procedure leading to the solution of a specific problem, that of the motion of a spin 1/2 in a magnetic field. Other sets of postulates can be used. For example, another approach is to state the postulates of quantum mechanics in terms of path integrals. As is often the case, the same physical theory can be dressed in various different mathematical clothes. Finally, it should be emphasized that the postulates of quantum physics give rise to some difficult epistemological problems which are still largely under debate and which we do not discuss in this book. The interested reader may consult, for example, the book by Isham [1995].
In this chapter we shall present the basic postulates of quantum physics, generalizing the results obtained in the preceding chapter for the two special cases of photon polarization and spin 1/2. In general, the space of states will a priori have any dimension N, which may even be infinite, rather than only two dimensions. The postulates which we present in this chapter fix the general conceptual framework of quantum mechanics and do not directly provide the tools necessary for solving specific problems. The solution of a specific physical problem always involves a modeling stage, where the system to be studied is simplified, the approximations to be used are defined, and so on, and this modeling stage inevitably rests on more or less heuristic arguments which cannot be derived within the general framework of quantum physics. In Section 3.2.5 we gave an example of a heuristic procedure leading to the solution of a specific problem, that of the motion of a spin 1/2 in a magnetic field. Other sets of postulates can be used. For example, another approach is to state the postulates of quantum mechanics in terms of path integrals. As is often the case, the same physical theory can be dressed in various different mathematical clothes. Finally, it should be emphasized that the postulates of quantum physics give rise to some difficult epistemological problems which are still largely under debate and which we do not discuss in this book. The interested reader may consult, for example, the book by Isham [1995].
In this chapter the basic concepts of quantum theory are formulated via a self-consistent set of six postulates. These six postulates deal with the following: operator images of physical observables; properties of state vectors and wave functions; the connection with experimental measurements; coordinate-space forms of those operators having classical analogs; the primary dynamical equation of quantum mechanics; and the completeness of the eigenvectors of observables. The postulates are the framework on which the edifice of quantum mechanics is constructed. A separate section is devoted to the statement of each postulate and to a few examples chosen to illustrate or apply it. A comprehensive set of applications is presented in Chapters 6 and 7, where various 1-D systems are used as the vehicles for illustrating the postulates. The basic theory of this chapter is extended and developed in Chapters 8 and 9. Since probability is a key interpretational concept, a brief introduction to this topic is given in an appendix. We emphasize that our formulation of quantum theory (in this chapter and throughout this book) is restricted to the case of pure states. This is not a major restriction. It means that, when we consider ensembles of individual quantum systems (e.g., single particles, atoms, nuclei, etc.), all of the systems in the ensemble are assumed to be in the same quantum state, not necessarily an eigenstate of a quantal operator. Ensembles for which this assumption does not hold are described by a density operator or density matrix rather than by a pure state; treatments of such cases can be found in references cited later.
In this chapter we build up the basic concepts of quantum mechanics using two simple examples, following a heuristic approach which is more inductive than deductive. We start with a familiar phenomenon, that of the polarization of light, which will allow us to introduce the necessary mathematical formalism. We show that the description of polarization leads naturally to the need for a two-dimensional complex vector space, and we establish the correspondence between a polarization state and a vector in this space, referred to as the space of polarization states. We then move on to the quantum description of photon polarization and illustrate the construction of probability amplitudes as scalar products in this space. The second example will be that of spin 1/2, where the space of states is again two-dimensional. We construct the most general states of spin 1/2 using rotational invariance. Finally, we introduce dynamics, which allows us to follow the time evolution of a state vector. The analogy with the polarization of light will serve as a guide to constructing the quantum theory of photon polarization, but no such classical analog is available for constructing the quantum theory for spin 1/2. In this case the quantum theory will be constructed without reference to any classical theory, using an assumption about the dimension of the space of states and symmetry principles. The polarization of light and photon polarization The polarization of an electromagnetic wave The polarization of light or, more generally, of an electromagnetic wave, is a familiar phenomenon related to the vector nature of the electromagnetic field. Let us consider a plane wave of monochromatic light of frequency ω propagating in the positive z direction.
This chapter gives a summary of the mathematical formalism used in quantum mechanics, with a short bibliography put directly at its end. It should be seen as a complement, to be used by readers who wish to know more than what has been recalled about the mathematical tools in the other chapters. Some results are given without explicit proofs; they can be found for instance in Chapters II and IV of [1] . Many quantum mechanics textbooks introduce its general formalism in a more complete way, for instance Chapter VII of [2] , Chapter 3 of [3] , or Chapter 2 of [4] . We first summarize the general formalism of quantum mechanics for any physical system (§11.1), with the Dirac notation; we then study how this formalism treats the grouping of several physical systems into one single quantum system (§11.2); finally, we study a few simple special cases (§11.3), for instance a single particle in an external potential, with or without spin; the reader who prefers wave functions to more abstract reasonings in spaces of states may begin with this section. General physical system The general formalism of quantum mechanics applies to all physical systems, whether they contain a single particle, many particles of various sorts, one or several fields, etc. Quantum space of states The physical state of a system at each time is defined in quantum mechanics by a state vector which, in Dirac notation, is written ∣ ψ 〈 – or ∣ ψ(t) 〈 if one wishes to make the time dependence explicit.
Basic scientific theories usually start with a set of hypotheses or “postulates.” There is generally no logical reason, apart from internal consistency, that can be given to justify such postulates absolutely. They come from ‘revelations’ in the minds of ‘geniuses,’ most likely with hints from Nature based on extensive careful observations. Their general validity can only be established through experimental verification. If numerous rigorously derived logical consequences of a very small set of postulates all agree with experimental observations without exception, one is inclined to accept these postulates as correct descriptions of the laws of Nature and use them confidently to explain and predict other natural phenomena. Quantum mechanics is no exception. It is based on a few postulates. For the purpose of the present discussion, we begin with three basic postulates involving: the “state functions,” “operators,” and “equations of motion.” In this chapter, this set of basic postulates and some of the corollaries and related definitions of terms are introduced and discussed. We will first simply state these postulates and introduce some of the related mathematical tools and concepts that are needed to arrive at their logical consequences later. To those who have not been exposed to the subject of quantum mechanics before, each of these postulates taken by itself may appear puzzling and meaningless at first. It should be borne in mind, however, that it is the collection of these postulates as a whole that forms the foundations of quantum mechanics.
It is not surprising that our language should be incapable of describing processes occurring within atoms, for, as has been remarked, it was invented to describe the experiences of daily life, … Fortunately, mathematics is not subject to this limitation, and it has been possible to invent a mathematical scheme–the quantum theory–which seems entirely adequate for the treatment of atomic processes. Werner Heisenberg, The Physical Principles of the Quantum Theory (1930) In this chapter we introduce the mathematical structure of quantum theory, for a finite number of systems and finite dimension, starting from three simple Hilbert-space postulates, and based on the intuitive notions of state, transformation, and effect, within a causal context. Such notions will be formalized in a general non-causal context in Chapter 3, which is devoted to the informational framework. We will assume the reader has a basic knowledge of matrix analysis and of operators over Hilbert spaces. Comments about the extension to infinite dimensions, continuous outcome-spaces, and infinitely many systems can be found in the notes at the end of the chapter. From the three simple Hilbert-space postulates, the present chapter extracts six principles, which will become the postulates for quantum theory in the axiomatic derivation presented in Part III of the book. In addition, we will take the opportunity to present and explore many relevant features of the theory – including its convex and causal structure, the Choi–Jamiołkowski isomorphism, and relevant notions, such as those of POVM, complete positivity of maps, quantum operation and channels, entangled states, state discrimination, tomography of states, and transformations. The purification principle will open the stage to the dilation theorems of the theory of quantum open systems, along with other consequences, such as the existence of faithful and steering states, the theorem of no information without disturbance, quantum teleportation, and more. We will review the quantum no-cloning and no-programming theorems, and finally provide a thorough derivation of the theory of quantum channel inversion, which is the backbone of the general theory of quantum error correction in quantum information. Additional interesting topics will be classical information theory as a restriction of quantum information theory, and a critical reconsideration of the von Neumann postulate and the notion of observable.
Hilbert space The prototype qubit systems of the last chapter are very simple, but they can be generalized to more complicated versions. We can send a photon through an interferometer with three, four or more distinct beams. We can perform experiments on particles with higher intrinsic angular momentum than the spin-½ particles we have discussed. And we can analyze atomic systems in situations that involve more than two different energy levels. For these cases and others, we will need a more general version of quantum theory. That theory will include two pieces. First, we will have a general mathematical structure that is applicable to many kinds of system. Here the qubit case will be our guide, since many of the basic concepts for other quantum systems are already present in the qubit case. Second, we will have to describe how to apply the quantum formalism to specific physical situations. Though the quantum systems we discuss will appear quite various, they share strong family resemblances that are expressed in the common mathematical framework. Keeping the framework in mind will help us understand specific examples; keeping the examples in mind will help us understand the framework. The states of a quantum system are described by kets |ψ〉, which obey the principle of superposition. This means that the kets are elements of an abstract vector space ℋ called a Hilbert space .