In this chapter we build up the basic concepts of quantum mechanics using two simple examples, following a heuristic approach which is more inductive than deductive. We start with a familiar phenomenon, that of the polarization of light, which will allow us to introduce the necessary mathematical formalism. We show that the description of polarization leads naturally to the need for a two-dimensional complex vector space, and we establish the correspondence between a polarization state and a vector in this space, referred to as the space of polarization states. We then move on to the quantum description of photon polarization and illustrate the construction of probability amplitudes as scalar products in this space. The second example will be that of spin 1/2, where the space of states is again two-dimensional. We construct the most general states of spin 1/2 using rotational invariance. Finally, we introduce dynamics, which allows us to follow the time evolution of a state vector. The analogy with the polarization of light will serve as a guide to constructing the quantum theory of photon polarization, but no such classical analog is available for constructing the quantum theory for spin 1/2. In this case the quantum theory will be constructed without reference to any classical theory, using an assumption about the dimension of the space of states and symmetry principles. The polarization of light and photon polarization The polarization of an electromagnetic wave The polarization of light or, more generally, of an electromagnetic wave, is a familiar phenomenon related to the vector nature of the electromagnetic field. Let us consider a plane wave of monochromatic light of frequency ω propagating in the positive z direction.
In this chapter we build up the basic concepts of quantum mechanics using two simple examples, following a heuristic approach which is more inductive than deductive. We start with a familiar phenomenon, that of the polarization of light, which will allow us to introduce the necessary mathematical formalism. We show that the description of polarization leads naturally to the need for a two-dimensional complex vector space, and we establish the correspondence between a polarization state and a vector in this space, referred to as the space of polarization states. We then move on to the quantum description of photon polarization and illustrate the construction of probability amplitudes as scalar products in this space. The second example will be that of spin 1/2, where the space of states is again two-dimensional. We construct the most general states of spin 1/2 using rotational invariance. Finally, we introduce dynamics, which allows us to follow the time evolution of a state vector. The analogy with the polarization of light will serve as a guide to constructing the quantum theory of photon polarization, but no such classical analog is available for constructing the quantum theory for spin 1/2. In this case the quantum theory will be constructed without reference to any classical theory, using an assumption about the dimension of the space of states and symmetry principles. The polarization of light and photon polarization The polarization of an electromagnetic wave The polarization of light or, more generally, of an electromagnetic wave, is a familiar phenomenon related to the vector nature of the electromagnetic field. Let us consider a plane wave of monochromatic light of frequency ω propagating in the positive z direction.
Classically, light is an electromagnetic phenomenon, described by Maxwell's equations. However, under certain conditions, such as low intensity or in the presence of certain nonlinear optical materials, light starts to behave differently, and we have to construct a ‘quantum theory of light’. We can exploit this quantum behaviour of light for quantum information processing, which is the subject of this book. In this chapter, we develop the quantum theory of the free electromagnetic quantum field. This means that we do not yet consider the interaction between light and matter; we postpone that to Chapter 7. We start from first principles, using the canonical quantization procedure in the Coulomb gauge: we derive the field equations of motion from the classical Lagrangian density for the vector potential, and promote the field and its canonical momentum to operators and impose the canonical commutation relations. This will lead to the well-known creation and annihilation operators, and ultimately to the concept of the photon. After quantization of the free electromagnetic field we consider transformations of the mode functions of the field. We will demonstrate the intimate relation between these linear mode transformations and the effect of beam splitters, phase shifters, and polarization rotations, and show how they naturally give rise to the concept of squeezing. Finally, we introduce coherent and squeezed states.
In this chapter we shall present the basic postulates of quantum physics, generalizing the results obtained in the preceding chapter for the two special cases of photon polarization and spin 1/2. In general, the space of states will a priori have any dimension N, which may even be infinite, rather than only two dimensions. The postulates which we present in this chapter fix the general conceptual framework of quantum mechanics and do not directly provide the tools necessary for solving specific problems. The solution of a specific physical problem always involves a modeling stage, where the system to be studied is simplified, the approximations to be used are defined, and so on, and this modeling stage inevitably rests on more or less heuristic arguments which cannot be derived within the general framework of quantum physics. In Section 3.2.5 we gave an example of a heuristic procedure leading to the solution of a specific problem, that of the motion of a spin 1/2 in a magnetic field. Other sets of postulates can be used. For example, another approach is to state the postulates of quantum mechanics in terms of path integrals. As is often the case, the same physical theory can be dressed in various different mathematical clothes. Finally, it should be emphasized that the postulates of quantum physics give rise to some difficult epistemological problems which are still largely under debate and which we do not discuss in this book. The interested reader may consult, for example, the book by Isham [1995].
The aim of this chapter is to present the vector nature of quantum states. We shall also become acquainted with the concepts of projectors and the mathematical tool of matrix calculation. In this chapter we shall elaborate the concepts presented in the previous chapter. To this end, let us consider another important property of the photon: polarization. Light is an electromagnetic wave and ordinarily it oscillates in all directions orthogonal to its propagation direction, as it happens for the light coming from the sun or spreading out of a normal electric bulb. However, when passing through a polarization filter (e.g., polarized sunglasses) light may acquire a privileged oscillation direction, and in this casewe say that it is polarized in that direction (in this way polarized sunglasses are able to eliminate reflected glare).
We have seen in the previous chapter how useful wave mechanics can be in solving physical problems. But wave mechanics has several limitations. It describes physical states by means of wave functions, which are functions of the positions of the particles of the system, but why should we single out position as the fundamental physical observable? For instance, we might want to describe states in terms of probability amplitudes for particles to have certain values of the momentum or energy rather than the position. A more fundamental limitation is that there are attributes of physical systems that cannot be described at all in terms of the positions and momenta of a set of particles. One of these attributes is spin , which will be a chief subject of Chapter 4. Another is the value of the electric or magnetic field at some point in space, treated in Chapter 11. This chapter will describe the principles of quantum mechanics in a formalism which is essentially the “transformation theory” of Dirac, mentioned briefly in Section 1.4. This formalism generalizes both the wave mechanics of Schrödinger and the matrix mechanics of Heisenberg, and is sufficiently comprehensive to apply to any sort of physical system. States The first postulate of quantum mechanics is that physical states can be represented as vectors in a sort of abstract space known as Hilbert space . Before getting into Hilbert space, I need to say a bit about vectors in general. In kindergarten we learn that vectors are quantities with both magnitude and direction. Later, when we study analytic geometry, we learn instead to describe a vector in d dimensions as a string of d numbers, the components of the vector. The latter approach lends itself well to calculation, but in some respects the kindergarten version is better, because it allows us to describe relations among vectors without specifying a coordinate system. For instance, a statement that one vector is parallel to a second vector, or perpendicular to a third, has nothing to do with how we choose our coordinate system. Here we will formulate what we mean by vector spaces in general, and Hilbert space in particular, in a way that is independent of the coordinates we use to describe directions in these spaces.
We have seen in the previous chapter how useful wave mechanics can be in solving physical problems. But wave mechanics has several limitations. It describes physical states by means of wave functions, which are functions of the positions of the particles of the system, but why should we single out position as the fundamental physical observable? For instance, we might want to describe states in terms of probability amplitudes for particles to have certain values of the momentum or energy rather than the position. A more fundamental limitation: There are attributes of physical systems that cannot be described at all in terms of the positions and momenta of a set of particles. One of these attributes is spin , which will be the subject of Chapter 4. Another is the value of the electric or magnetic field at some point in space, treated in Chapter 11. This chapter will describe the principles of quantum mechanics in a formalism which is essentially the “transformation theory” of Dirac, mentioned briefly in Section 1.4. This formalism generalizes both the wave mechanics of Schrödinger and the matrix mechanics of Heisenberg, and is sufficiently comprehensive to apply to any sort of physical system. States The first postulate of quantum mechanics is that physical states can be represented as vectors in a sort of abstract space known as Hilbert space . Before getting into Hilbert space, I need to say a bit about vectors in general. In kindergarten we learn that vectors are quantities with both magnitude and direction. Later, when we study analytic geometry, we learn instead to describe a vector in d dimensions as a string of d numbers, the components of the vector. This latter approach lends itself well to calculation, but in some respects the kindergarten version is better, because it allows us to describe relations among vectors without specifying a coordinate system. For instance, a statement that one vector is parallel to a second vector, or perpendicular to a third, has nothing to do with how we choose our coordinate system.
Quantum mechanics is based on linear algebra. The general theory uses infinite dimensional vector spaces. Fortunately for us, to describe spin or polarization we need only finite dimensions, which makes things much easier. In fact, we need only a few tools. At the end of this chapter I have given a list. The rest of the chapter explains how to use these tools and what the calculations mean. There are many examples. It is important to work carefully through all of them. The mathematics introduced here is essential to everything that follows. Like much mathematics, it can seem complicated when it is first introduced, but it becomes almost second nature with practice. The actual computations only involve addition and multiplication of numbers, along with an occasional square root and trigonometric function.