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Condensation and Coherence in Condensed Matter

Superfluidity and Coherence in Bose-Einstein Condensates

Wolfgang Ketterle

Published Mar 1, 2003• 0 citations
Publisher
DOI
10.1142/9789812791269_0006

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arXiv:cond-mat/0312417•Dec 17, 2003•0 citations
The study of exotic states of matter, particularly superfluids and Bose-Einstein condensates (BECs), has revolutionized our understanding of quantum mechanics in macroscopic systems. This article explores the thermodynamic properties of these states, focusing on their unique behavior at ultra-low temperatures. Superfluids exhibit zero viscosity and anomalous flow characteristics, while Bose-Einstein condensates, formed by cooling bosons to near absolute zero, present quantum phenomena on a macroscopic scale. This paper reviews key thermodynamic concepts, such as entropy, heat capacity, and chemical potential, as they apply to these exotic phases. Additionally, the relationship between quantum coherence and thermodynamic stability in superfluids and BECs is examined, along with the practical implications for quantum technologies.
Since the early days of Bose–Einstein condensates (BECs) in atomic gases, comparisons have been drawn to the other familiar bosonic systems: liquid helium-4 and the Cooper pairs of superconductors. Two of the early questions asked of BECs were whether they had similar coherence properties and whether they were superfluids. In He4, it is rather difficult to study properties of the condensate, such as the condensate fraction, whereas the measurement of superfluidity is fairly straightforward. The opposite has proved true for atomic condensates: The condensate fraction as a function of temperature was found early on, but only recently has their superfluidity been placed on firm footing (see PHYSICS TODAY, November 1999, page 17).
We study inter-well coherent quantum tunneling of Bose-Einstein condensates (BEC's) in optical lattices. Irrespective of whether the BEC is a superfluid in the whole lattice, it may or may not be a superfluid within each well of the lattice depending on whether the ratio of the well kinetic energy to the interaction energy is small or large. When the bosons in each well are superfluid, we have Josephson tunneling among the wells driven by the phase difference between the superfluids in the different wells. For typical lattice parameters the Josephson tunneling rate will be somewhat enhanced from the naive estimate of (tunneling energy scale)/ℏ/\hbar/ℏ. Whether it is enhanced or not will depend on lattice parameters, but it can never be zero. When the bosons in each well are not superfluid, there is coherent quantum tunneling of essentially free bosons between the wells. This tunneling is proportional to the boson number difference between the wells.