Among the few lessons that Physics teaches us on a daily basis, one in particular is hard to miss: thermalization processes are ubiquitous. With the same degree of certainty, one can predict an apple to fall onto the ground if its stalk is cut, or a cup of tea to be found cold if left on the table for too long. In this respect, generic classical and quantum mechanical systems seem to behave in the same way. This is also one of the main difficulties in the experimental observation of the bizarre effects predicted from the quantum theory, as several of these are known to disappear at finite temperatures. It has been known for a long time that thermalization is associated with “chaotic” behavior at the microscopic level, but recently systematic efforts, both theoretical and experimental, have allowed us to understand its mechanisms at an unprecedented level of accuracy. Indeed, it has been realized that thermalization generally occurs also in isolated systems, where the absence of interactions with the environment allows for first principle theoretical investigations1. In this case thermalization takes place locally, as the whole system acts as a thermal bath for its own subsystems. Theoretical research has been motivated and paralleled by exciting experimental progress in cold-atom physics, which has provided robust, nearly ideal realizations of several theoretical models2. As an established piece of knowledge, recent research has now confirmed that two outstanding exceptions actually exist in the quantum realm, where thermalization is prevented to occur. These are many-body localized systems3, where disorder plays a crucial role, and integrable ones, which are protected by the existence of higher conservation laws. By their own nature, these systems display exceptional non-equilibrium features, which are not washed out by the onset of thermalization as relaxation occurs. At the core of the present thesis lie the remarkable properties of integrable systems out of equilibrium, with a special attention to physical effects which could be observed in cold-atom realizations. The work collected here is part of a large theoretical effort4 which in the past decade has focused on the study of relatively simple protocols to bring a quantum system out of equilibrium, such as the so-called quantum quench. In these “theoretical laboratories” it has been possible to provide quantitative predictions which helped us to develop an intuition on general questions regarding non-equilibrium and thermalization processes. Furthermore, in some cases these studies have highlighted interesting physical effects which could be directly probed experimentally within cold-atom settings. The contribution of the present thesis is two-fold. On the one hand, we have developed new technical tools for the study of integrable systems out of equilibrium, and for the computation of measurable physical quantities such as correlation functions. The techniques employed are mainly analytical and rooted within the mathematical structures of integrability. On the other hand, we have singled out physically relevant nonequilibrium situations where exotic, non-thermal states of matter emerge after relaxation occurs, and provided quantitative analytical predictions in these cases. A comprehensive discussion of the motivations and results of our work will be presented in Chapter 1, where we provide a complete overview of this thesis and discuss the organization of its content.
One of the distinguishing achievements of physics has been the ability to describe the Universe based upon underlying microscopic principles. When there are many participating objects being governed by these microscopic principles, the resultant behavior often harbors emergent collective phenomena that may not be obviously related to the microscopic description. Phase transitions, quantum or classical, are a canonical example of such many-body phenomena that are understood in equilibrium through a framework of thermodynamic constraints, statistical ensembles, and a growth of system-wide correlations at the transition. However, a new class of quantum phase transitions has recently emerged for non-equilibrium systems with behavior that is not captured by this traditional framework. In the case of isolated quantum systems, these transitions occur among excited eigenstates and requires knowledge of the structure of these individual eigenstates in the quantum system. Understanding what drives such a phase transition requires a deeper microscopic knowledge of the role of correlations at the transition. \nThe use of ultracold atoms in optical lattices has paved the way for faithfully realizing quantum phase transitions. In particular, the advent of the quantum gas microscope realized an experimental platform that is highly controllable and provides microscopic access to the many-bodied wave functions. All experiments presented in this thesis use such a quantum gas microscope architecture where a quantum degenerate gas of Rb is used to probe the behavior of non-equilibrium quantum systems in one spatial dimension.\nThis thesis briefly discusses some studies of entanglement in equilibrium quantum phase transitions near the ground state of the system. In the first experiment, we directly measure the second-order R\\'enyi entanglement entropy that develops as a Bose-Hubbard system transitions from a Mott insulator to a superfluid. This is followed by a study of entanglement growth at the transition in the transverse Ising model. \nThese studies progress to the investigation of two particular non-equilibrium quantum phases and their transition into one another: quantum thermalization and many-body localization. We investigate the development of entanglement entropy that mimics thermodynamic entropy for an isolated quantum system which locally thermalizes under its own unitary dynamics. We then investigate the only known robust exception to this thermalizing behavior by studying the onset of many-body localization due to disorder. We observe the breakdown of thermalization in this phase and the logarithmically slow growth of entanglement throughout the system, which identifies the localized system to be an interacting one. Lastly, we investigate the role of correlations in the critical dynamics that emerge at high-orders where the system transitions from thermalizing behavior to many-body localization.
This Ph.D. thesis concerns a very active area of current research in theoretical physics, which is non-equilibrium statistical mechanics. More specifically, the focus will be on the study of the non-equilibrium dynamics and fluctuations in isolated many body systems driven out of equilibrium. We shall consider primarily quantum systems, albeit many of the theoretical techniques that will be used can be applied to both classical and quantum statistical systems. The novel contribution of this work is two-fold. First, we have developed new analytical techniques to study exactly the large-deviation statistics of physical quantities relevant for the description of systems driven out of equilibrium, like the work done in a quantum quench or the time-integrated current characterizing transport of matter, energy or charge etc, discussed in Part I of the thesis. Second, we have singled out a class of experimentally relevant nondisordered quantum systems showing a dramatically slow approach to thermal equilibrium and we have provided quantitative predictions for this behavior, which is discussed in Part II.
Statistical mechanics characterizes systems in or near equilibrium using in terms of a handful of "state" variables, e.g. temperature, rather than infinitely many degrees of freedom. Statistical physics describes the expansion of the early universe, aspects of black holes, and most fruitfully, phases of matter and their properties. Quantum considerations have improved this understanding over time and revealed new phenomena, especially in complicated "strongly correlated" systems. Topological phases of matter, e.g., are of both fundamental and practical interest: these phases cannot be distinguished locally, unlike ice and water, which also allows them to store and process quantum information in a "fault-tolerant" manner, recently proposed for application to quantum computation. However, above zero temperature, thermal effects can overwrite this information.Recent experiments on isolated systems have raised fundamental questions and revealed new routes to quantum computing. We now know that entanglement, generated dynamically as a quantum state evolves, "hides" local information about the past, producing familiar equilibrium states, described by a temperature. However, many systems do not thermalize: strong disorder can lead to MBL, which supports numerous phenomena forbidden in equilibrium and can protect quantum information at infinite temperature. In particular, both MBL and thermal systems are robust phases of matter, with a novel, athermal phase transition between them. This thesis begins with an overview of MBL and thermalization, followed by an overview of exactly soluble quantum systems. We then turn to an important result in the field by this author: we introduce the first nontrivial example of an integrable Floquet model and comment on its solution and salient features. We then discuss how integrable models can provide insight into quantum thermalization, e.g. in terms of entanglement growth and demonstrating that conserved charges diffuse. We then investigate thermalization away from the integrable limit, also known as "quantum chaos." We review the standard techniques in this field and, briefly, several important results, before reproducing work by this author establishing definitively the long-conjectured result that the onset of thermalization in the presence of a conserved charge is governed by diffusion of said charge. We then investigate the interplay of conventional and topological order with nonequilibrium phase structure, with applications to quantum computation in mind. We review localization-protected quantum order in several models. We then investigate two models with non-Abelian symmetry, and show that MBL in such models can only realize if the symmetry breaks spontaneously to an Abelian subgroup. Finally, we conclude by examining open quantum systems, where we find several counterintuitive results that show that baths can, in some cases, enhance localization in certain systems, which may have use in realizing quantum computation.
The study of non-equilibrium behaviors of quantum matter is one of the research directions at the frontiers of condensed matter physics and, in general, of theoretical and experimental physics. Understanding the mechanisms which prevent many quantum particles from reaching thermal equilibrium can ultimately shed light on the foundations of statistical physics and provide insight into the anomalous long-time collective behaviors observed in experiments. In this thesis, we present new theoretical developments in this direction. In the first part of the thesis we discuss the non-equilibrium dynamics of the two-dimensional quantum Ising model, the prototypical model of magnetism. In particular, we investigate the dynamics of interfaces separating different spin domains. In some regimes, we can provide an exact description of their unitary time evolution, but we also discuss the robustness of our predictions away from the exactly-solvable limit. Moreover, we address the same problem in the presence of disorder and provide a hydrodynamic interpretation of our findings. In the second part of the thesis, we investigate the localization properties of disordered quantum systems. In particular, we develop a renormalization-group picture of the Anderson localization transition in generic geometries. This provides a new framework to understand the phase diagram of such systems and their critical behavior beyond the usual finite-size scaling analysis. We also provide further insights on this topic both by studying resonances and their connection with observables and by employing unsupervised non-parametric learning techniques to probe disordered systems in an experimentally accessible form. The results presented in this thesis constitute a step forward in understanding the non-equilibrium phases and regimes of quantum matter and they pave the way to interesting future developments.
Thermalization, the evolution of an interacting many-body system towards a thermal Gibbs ensemble after initialization in an arbitrary non-equilibrium state, is currently a phenomenon of great interest, both in theory and experiment. As the time evolution of a quantum system is unitary, the proposed mechanism of thermalization in quantum many-body systems corresponds to the so-called eigenstate thermalization hypothesis (ETH) and the typicality of eigenstates. Although this formally solves the contradiction of thermalizing but unitary dynamics in a closed quantum many-body system, it does neither make any statement on the dynamical process of thermalization itself nor in which way the coupling of the system to an environment can hinder or modify the relaxation dynamics. In this thesis, we address both the question whether or not a quantum system driven away from equilibrium is able to relax to a thermal state, which fulfills detailed balance, and if one can identify universal behavior in the non-equilibrium relaxation dynamics. As a first realization of driven quantum systems out of equilibrium, we investigate a system of Ising spins, interacting with the quantized radiation field in an optical cavity. For multiple cavity modes, this system forms a highly entangled and frustrated state with infinite correlation times, known as a quantum spin glass. In the presence of drive and dissipation, introduced by coupling the intra-cavity radiation field to the photon vacuum outside the cavity via lossy mirrors, the quantum glass state is modified in a universal manner. For frequencies below the photon loss rate, the dissipation takes over and the system shows the universal behavior of a dissipative spin glass, with a characteristic spectral density
mathcalA(omega)simsqrtomega. On the other hand, for frequencies above the loss rate, the system retains the universal behavior of a zero temperature, quantum spin glass. Remarkably, at the glass transition, the two subsystems of spins and photons thermalize to a joint effective temperature, even in the presence of photon loss. This thermalization is a consequence of the strong spin-photon interactions, which favor detailed balance in the system and detain photons from escaping the cavity. In the thermalized system, the features of the spin glass are mirrored onto the photon degrees of freedom, leading to an emergent photon glass phase. Exploiting the inherent photon loss of the cavity, we make predictions of possible measurements on the escaping photons, which contain detailed information of the state inside the cavity and allow for a precise, non-destructive measurement of the glass state. As a further set of non-equilibrium systems, we consider one-dimensional quantum fluids driven out of equilibrium, whose universal low energy theory is formed by the so-called Luttinger Liquid description, which, due to its large degree of universality, is of intense theoretical and experimental interest. A set of recent experiments in research groups in Vienna, Innsbruck and Munich have probed the non-equilibrium time-evolution of one-dimensional quantum fluids for different experimental realizations and are pushing into a time regime, where thermalization is expected. From a theoretical point of view, one-dimensional quantum fluids are particular interesting, as Luttinger Liquids are integrable and therefore, due to an infinite number of constants of motion, do not thermalize. The leading order correction to the quadratic theory is irrelevant in the sense of the renormalization group and does therefore not modify static correlation functions, however, it breaks integrability and will therefore, even if irrelevant, induce a completely different non-equilibrium dynamics as the quadratic Luttinger theory alone. In this thesis, we derive for the first time a kinetic equation for interacting Luttinger Liquids, which describes the time evolution of the excitation densities for arbitrary initial states. The resonant character of the interaction makes a straightforward derivation of the kinetic equation, using Fermi\'s golden rule, impossible and we have to develop non-perturbative techniques in the Keldysh framework. We derive a closed expression for the time evolution of the excitation densities in terms of self-energies and vertex corrections. Close to equilibrium, the kinetic equation describes the exponential decay of excitations, with a decay rate
sigmaR=mboxImSigmaR, determined by the self-energy at equilibrium. However, for long times
tau, it also reveals the presence of dynamical slow modes, which are the consequence of exactly energy conserving dynamics and lead to an algebraic decay
simtau−etasubD with
etaD=0.58. The presence of these dynamical slow modes is not contained in the equilibrium Matsubara formalism, while they emerge naturally in the non-equilibrium formalism developed in this thesis. In order to initialize a one-dimensional quantum fluid out of equilibrium, we consider an interaction quench in a model of interacting, dispersive fermions in Chap.~\\ref{sec:Quench}. In this scenario, the fermionic interaction is suddenly changed at time
t=0, such that for
t>0 the system is not in an eigenstate and therefore undergoes a non-trivial time evolution. For the quadratic theory, the stationary state in the limit
trightarrowinfty is a non-thermal, or prethermal, state, described by a generalized Gibbs ensemble (GGE). The GGE takes into account for the conservation of all integrals of motion, formed by the eigenmodes of the Hamiltonian. On the other hand, in the presence of non-linearities, the final state for
trightarrowinfty is a thermal state with a finite temperature
T>0. . The spatio-temporal, dynamical thermalization process can be decomposed into three regimes: A prequench regime on the largest distances, which is determined by the initial state, a prethermal plateau for intermediate distances, which is determined by the metastable fixed point of the quadratic theory and a thermal region on the shortest distances. The latter spreads sub-ballistically
simtalpha in space with
0<alpha<1 depending on the quench. Until complete thermalization (i.e. for times
t<infty), the thermal region contains more energy than the prethermal and prequench region, which is expressed in a larger temperature
Tt>Tinfty, decreasing towards its final value
Tinfty. As the system has achieved local detailed balance in the thermalized region, energy transport to the non-thermal region can only be performed by the macroscopic dynamical slow modes and the decay of the temperature
Tt−Tinftysimt−etasubD again witnesses the presence of these slow modes. The very slow spreading of thermalization is consistent with recent experiments performed in Vienna, which observe a metastable, prethermal state after a quench and only observe the onset of thermalization on much larger time scales. As an immediate indication of thermalization, we determine the time evolution of the fermionic momentum distribution after a quench from non-interacting to interacting fermions. For this quench scenario, the step in the Fermi distribution at the Fermi momentum
ksubF decays to zero algebraically in the absence of a non-linearity but as a stretched exponential (the exponent being proportional to the non-linearity) in the presence of a finite non-linearity. This can serve as a proof for the presence or absence of the non-linearity even on time-scales for which thermalization can not yet be observed. Finally, we consider a bosonic quantum fluid, which is driven away from equilibrium by permanent heating. The origin of the heating is atomic spontaneous emission of laser photons, which are used to create a coherent lattice potential in optical lattice experiments. This process preserves the system\'s
U(1)-invariance, i.e. conserves the global particle number, and the corresponding long-wavelength description is a heated, interacting Luttinger Liquid, for which phonon modes are continuously populated with a momentum dependent rate
partialtnqsimgamma∣q∣. In the dynamics, we identify a quasi-thermal regime for large momenta, featuring an increasing time-dependent effective temperature. In this regime, due to fast phonon-phonon scattering, detailed balance has been achieved and is expressed by a time-local, increasing temperature. The thermal region emerges locally and spreads in space sub-ballistically according to
xtsimt4/5. For larger distances, the system is described by an non-equilibrium phonon distribution
nqsim∣q∣, which leads to a new, non-equilibrium behavior of large distance observables. For instance, the phonon decay rate scales universally as
gammaqsim∣q∣5/3, with a new non-equilibrium exponent
eta=5/3, which differs from equilibrium. This new, universal behavior is guaranteed by the
U(1) invariant dynamics of the system and is insensitive to further subleading perturbations. The non-equilibrium long-distance behavior can be determined experimentally by measuring the static and dynamic structure factor, both of which clearly indicate the exponents for phonon decay,
eta=5/3 and for the spreading of thermalization
etaT=4/5. Remarkably, even in the presence of this strong external drive, the interactions and their aim to achieve detailed balance are strong enough to establish a locally emerging and spatially spreading thermal region. The physical setups in this thesis do not only reveal interesting and new dynamical features in the out-of-equilibrium time evolution of interacting systems, but they also strongly underline the high degree of universality of thermalization for the classes of models studied here. May it be a system of coupled spins and photons, where the photons are pulled away from a thermal state by Markovian photon d