This Ph.D. thesis concerns a very active area of current research in theoretical physics, which is non-equilibrium statistical mechanics. More specifically, the focus will be on the study of the non-equilibrium dynamics and fluctuations in isolated many body systems driven out of equilibrium. We shall consider primarily quantum systems, albeit many of the theoretical techniques that will be used can be applied to both classical and quantum statistical systems. The novel contribution of this work is two-fold. First, we have developed new analytical techniques to study exactly the large-deviation statistics of physical quantities relevant for the description of systems driven out of equilibrium, like the work done in a quantum quench or the time-integrated current characterizing transport of matter, energy or charge etc, discussed in Part I of the thesis. Second, we have singled out a class of experimentally relevant nondisordered quantum systems showing a dramatically slow approach to thermal equilibrium and we have provided quantitative predictions for this behavior, which is discussed in Part II.
This Ph.D. thesis concerns a very active area of current research in theoretical physics, which is non-equilibrium statistical mechanics. More specifically, the focus will be on the study of the non-equilibrium dynamics and fluctuations in isolated many body systems driven out of equilibrium. We shall consider primarily quantum systems, albeit many of the theoretical techniques that will be used can be applied to both classical and quantum statistical systems. The novel contribution of this work is two-fold. First, we have developed new analytical techniques to study exactly the large-deviation statistics of physical quantities relevant for the description of systems driven out of equilibrium, like the work done in a quantum quench or the time-integrated current characterizing transport of matter, energy or charge etc, discussed in Part I of the thesis. Second, we have singled out a class of experimentally relevant nondisordered quantum systems showing a dramatically slow approach to thermal equilibrium and we have provided quantitative predictions for this behavior, which is discussed in Part II.
The study of non-equilibrium behaviors of quantum matter is one of the research directions at the frontiers of condensed matter physics and, in general, of theoretical and experimental physics. Understanding the mechanisms which prevent many quantum particles from reaching thermal equilibrium can ultimately shed light on the foundations of statistical physics and provide insight into the anomalous long-time collective behaviors observed in experiments. In this thesis, we present new theoretical developments in this direction. In the first part of the thesis we discuss the non-equilibrium dynamics of the two-dimensional quantum Ising model, the prototypical model of magnetism. In particular, we investigate the dynamics of interfaces separating different spin domains. In some regimes, we can provide an exact description of their unitary time evolution, but we also discuss the robustness of our predictions away from the exactly-solvable limit. Moreover, we address the same problem in the presence of disorder and provide a hydrodynamic interpretation of our findings. In the second part of the thesis, we investigate the localization properties of disordered quantum systems. In particular, we develop a renormalization-group picture of the Anderson localization transition in generic geometries. This provides a new framework to understand the phase diagram of such systems and their critical behavior beyond the usual finite-size scaling analysis. We also provide further insights on this topic both by studying resonances and their connection with observables and by employing unsupervised non-parametric learning techniques to probe disordered systems in an experimentally accessible form. The results presented in this thesis constitute a step forward in understanding the non-equilibrium phases and regimes of quantum matter and they pave the way to interesting future developments.
This thesis reports the results obtained during my PhD research in the field of out of equilibrium quantum many-body systems. Chapter 1 consists in a brief introduction of the field and the introduction of concept that are useful for the following chapters. In Chapter 2 the statistics of the work as a tool for characterizing the dynamics of many-body quantum systems is introduced its general features discussed. Then, such a statistics is computed for generic time-dependent protocols (both global and local) in the quantum Ising chain and in the Gaussian field theory, showing, in particular, that in its low-energy part there are features that are independent of the details of the specific chosen protocol. Chapter 3 is devoted to the study of the dynamical phase transition in the O(N) quantum vector model in the N→∞ limit, whose critical properties in generic dimensions are characterized. Moreover, a strong connection between such a transition and the statistics of excitations produced in a double quench as a function of the waiting time is showed. The chapter ends by studying the fate of the dynamical transition and the its critical properties when a ramp of finite duration τ is applied to the system instead of a sudden quench. In particular, we will show that when τ→∞ the critical point tends to the equilibrium critical point (at zero temperature) in a power-law fashion and that for every finite τ the critical properties are always the same (and different from the equilibrium critical properties). Finally in Chapter 4 we will discuss the emergence of a non adiabatic behavior in the dynamics of the order parameter for a low dimensional quantum system driven within a gapped phase by considering in detail the case of a quantum Ising chain subject to a linear variation in time of the transverse field, showing that, no matter how slowly the ramp is performed, such a change leads eventually to the disruption of the order.
This purely theoretical thesis covers aspects of two contemporary research fields: the non-equilibrium dynamics in quantum systems \nand the electronic properties of three-dimensional topological insulators. \n \nIn the first part we investigate the non-equilibrium dynamics in closed quantum systems. Thanks to recent technologies, especially from the field \nof ultracold quantum gases, it is possible to realize such systems in the laboratory. The focus is on the influence of hydrodynamic slow \nmodes on the thermalization process. \nGeneric systems in equilibrium, either classical or quantum, in equilibrium are described by thermodynamics. \nThis is characterized by an ensemble of maximal entropy, but constrained by macroscopically conserved quantities. We will show that these \nconservation laws slow down thermalization and the final equilibrium state can be approached only algebraically in time. \nWhen the conservation laws are violated thermalization takes place exponential in time. \nIn a different study we calculate probability distributions of projective quantum measurements. \nNewly developed quantum microscopes provide the opportunity to realize new measurement protocols which go far beyond the conventional \nmeasurements of correlation functions. \n \nThe second part of this thesis is dedicated to a new class of materials known as three-dimensional topological insulators. \nAlso here new experimental techniques have made it possible to fabricate these materials to a high enough quality that their topological nature is revealed. \nHowever, their transport properties are not fully understood yet. Motivated by unusual experimental results in the optical conductivity \nwe have investigated the formation and thermal destruction of spatially localized electron- and hole-doped regions. \nThese are caused by charged impurities which are introduced into the material in order to make the bulk insulating. \nOur theoretical results are in agreement with the experiment and can explain the results semi-quantitatively. \nFurthermore, we study emergent lengthscales in the bulk as well as close to the conducting surface.
This thesis summarizes a course of investigation of various aspects of non-equilibrium dynamics in isolated quantum systems which can be controlled to the extent that one can speak of not just realizing but rather simulating a desired physical effect. The first subject considered concerns a general question of relaxation in a large class of physical models. It is rigorously proven that equilibration can occur for arbitrary local observables despite the entire system being perfectly isolated. Various mechanisms responsible for convergence to local equilibrium are highlighted. These involve in particular the memory loss of non-Gaussian correlations following an interaction quench, a notion of Gaussian ergodicity and a proof of the emergence of translation invariance of correlations due to the presence of this symmetry in the Hamiltonian governing the evolution. These results provide the long time and large system size asymptotics facilitating a thermodynamic limit, but at the same time are relevant for state-of-the-art quantum simulation experiments with large numbers of ultra-cold atoms: A related effect has been observed in a one-dimensional phononic quantum field simulator and additionally a method is provided to study relaxation dynamics of this type in optical lattice quantum simulators. Within the second theme explored in this thesis a novel quantum read-out method is proposed and applied in continuous field quantum simulators which allowed for the first time to measure experimentally various thermodynamical properties of one-dimensional quasi-condensates. In particular, tomographic results concerning thermal properties, non-commuting observables, momentum and time-resolved occupation numbers of phonons are presented. Finally, ideas for practical benchmarking of the dynamics of certain closed quantum systems are put forward, based on the concept of a fidelity witness. It is demonstrated that fidelity, despite being a sensitive measure for large systems, can be efficiently estimated for non-equilibrium dynamics in coherent quantum simulators implementing paradigmatic models of condensed matter physics. The method developed has already found an independent application in studies of variational quantum circuits aiming at achieving so-called quantum chemistry accuracy using the Sycamore quantum processor. The fact that all three themes of research laid out in this thesis have found an experimental realization hints at a prognosis for future developments in physics that it will become standard that quantum simulators will realize experimentally novel theoretical ideas on demand and the time between theoretical insights and experimental observations will be dramatically shortened.
Among the few lessons that Physics teaches us on a daily basis, one in particular is hard to miss: thermalization processes are ubiquitous. With the same degree of certainty, one can predict an apple to fall onto the ground if its stalk is cut, or a cup of tea to be found cold if left on the table for too long. In this respect, generic classical and quantum mechanical systems seem to behave in the same way. This is also one of the main difficulties in the experimental observation of the bizarre effects predicted from the quantum theory, as several of these are known to disappear at finite temperatures. It has been known for a long time that thermalization is associated with “chaotic” behavior at the microscopic level, but recently systematic efforts, both theoretical and experimental, have allowed us to understand its mechanisms at an unprecedented level of accuracy. Indeed, it has been realized that thermalization generally occurs also in isolated systems, where the absence of interactions with the environment allows for first principle theoretical investigations1. In this case thermalization takes place locally, as the whole system acts as a thermal bath for its own subsystems. Theoretical research has been motivated and paralleled by exciting experimental progress in cold-atom physics, which has provided robust, nearly ideal realizations of several theoretical models2. As an established piece of knowledge, recent research has now confirmed that two outstanding exceptions actually exist in the quantum realm, where thermalization is prevented to occur. These are many-body localized systems3, where disorder plays a crucial role, and integrable ones, which are protected by the existence of higher conservation laws. By their own nature, these systems display exceptional non-equilibrium features, which are not washed out by the onset of thermalization as relaxation occurs. At the core of the present thesis lie the remarkable properties of integrable systems out of equilibrium, with a special attention to physical effects which could be observed in cold-atom realizations. The work collected here is part of a large theoretical effort4 which in the past decade has focused on the study of relatively simple protocols to bring a quantum system out of equilibrium, such as the so-called quantum quench. In these “theoretical laboratories” it has been possible to provide quantitative predictions which helped us to develop an intuition on general questions regarding non-equilibrium and thermalization processes. Furthermore, in some cases these studies have highlighted interesting physical effects which could be directly probed experimentally within cold-atom settings. The contribution of the present thesis is two-fold. On the one hand, we have developed new technical tools for the study of integrable systems out of equilibrium, and for the computation of measurable physical quantities such as correlation functions. The techniques employed are mainly analytical and rooted within the mathematical structures of integrability. On the other hand, we have singled out physically relevant nonequilibrium situations where exotic, non-thermal states of matter emerge after relaxation occurs, and provided quantitative analytical predictions in these cases. A comprehensive discussion of the motivations and results of our work will be presented in Chapter 1, where we provide a complete overview of this thesis and discuss the organization of its content.
The work presented in this thesis is divided into two main parts: strong zero modes in quantum spin chains with open boundaries and large deviations in classical spin systems. The results concerning the strong zero modes are presented in chapters 2 and 3, while chapter 4 contains the results about large deviations in systems of many, but independent, classical degrees of freedom. These two distinct classes of problems in spin chains are both about aspects of slow relaxation to equilibrium in many-body systems. Nowadays slow dynamics and non-ergodicity in many-body quantum systems are receiving much attention due to their notable technological potential for storing and processing, for very long times, the quantum information encoded in boundary degrees of freedom. In the first part of the work presented in this thesis we mainly focus on quantum spin chains with open boundaries, which can display coherence times for edge spins, that diverge with the system size, as a consequence of the emergence, in the thermodynamic limit, of conserved local quantities, called strong zero modes. First, we discuss the fate of these coherence times when dynamics becomes dissipative. Understanding the behavior of these long correlation times in open quantum systems, undergoing Markovian (memoryless) dynamics, would allow for the possibility of exploiting the protected information encoded in the boundary spins for applications in quantum devices in realistic non-equilibrium settings. Second, we study one possible simple generalization of the transverse field Ising model to a class of ladder spin systems with plaquette interactions in the presence of a transverse field. Also for these systems one can explicitly construct the strong zero mode operators and understand the behavior of the consequential long coherence times for the edge degrees of freedom under isolated (unitary) dynamics. This is possible because the models we consider, while appearing complex superficially, can be brought to simple forms by exploiting an extensive number of conserved quantities they possess. The results presented in chapters 2 and 3 are closely related, even if they focus on different models and investigate different aspects of their dynamics. Nevertheless, the underlying concept they are based on is the same one, that is, an eigenstate phase transition for the strong zero modes that has interesting consequences for the full energy spectrum. In the second part of the thesis we focus on a different type of phase transitions. Here we address the issue of dynamical large deviation phase transitions from a disordered phase to an ordered one, in classical systems which consist in a collection of independent Ising spins evolving stochastically. Surprisingly, by reweighing trajectories accordingly to a certain type of time-integrated observable, even a system of independently evolving spins can display some critical behavior, at the fluctuation level, in trajectory space in the large size and long time limit. By making use of the tilted generator techniques we study the statistics of two particular time-integrated observables. Their associated tilted generators have an exact Kramers-Wannier duality and they look like, up to a sign and an additive constant, some specific well known quantum Hamiltonians. In this sense, the dynamical large deviation phase transitions we observe in these classical stochastic systems translate in ground state quantum phase transitions taking place at the self dual point of the tilted generators we study.