Switching from opaque via transparent to a strongly amplifying state is shown to be possible for molecular media without a change in the noninverted population of their energy levels.
Specific features of nonlinear interference processes at quantum transitions in near- and fully resonant Doppler-broadened optically dense media are studied. The possibility of all-optical switching of the medium to opaque or, alternatively, to absolutely transparent, or even to strongly amplifying states is explored, which is controlled by a small variation of two driving or probe radiations and does not require any change of the level populations. Optimum conditions for inversionless amplification of short-wavelength radiation above the oscillation threshold at the expense of the longer-wavelength control fields are investigated. The feasibility of overcoming the fundamental limitation on a velocity-interval of resonantly coupled molecules imposed by the Doppler effect is shown, based on quantum coherence.
Switching anisotropic molecules from strongly-absorbing to strongly-amplifying through a transparent state is shown to be possible by application of dc or ac control electric fields without the requirement of the population inversion. It is based on decoupling of the lower-level molecules from the resonant light while the excited ones remain emitting due to their state-dependent alignment. The amplification index may become dependent only on a number of excited molecules and not on the population of the lower state. A suitable class of molecules and applications in optoelectronics, fiberoptics and nanophotonics are outlined.