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Amplification without population inversion and optical switching through state-dependent alignment of molecules

A. K. Popov, Vitaliy V. Slabko

Published Jan 1, 2004• 0 citations
Publisher

Abstract

Effective switching anisotropic molecules from strongly absorbing to amplifying state is shown to be possible without population inversion by dc or ac control electric fields. Suitable class of molecules and application in nanophotonics are outlined.
DOI
10.1364/ipr.2004.jwb7

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We propose a modified Stark-chirped rapid adiabatic passage technique for a robust rovibrational population transfer in the gas phase molecules in the presence of certain inhomogeneous electric fields. As an example application, the new state switching scheme is shown to greatly enhance the process of slowing polar ammonia molecules in the Stark decelerator. High-level quantum mechanical simulations show that a virtually complete population inversion between a selected pair of weak-field and strong-field seeking states of NH3_33​ can be achieved. Strong dc electric fields within the Stark decelerator are used as part of the rovibrational population transfer protocol. Classical-dynamics simulations for ammonia demonstrate notable improvements in the longitudinal phase space acceptance of the Stark decelerator upgraded with the state switching and an increased deceleration efficiency with respect to the standard Stark deceleration technique.