Using Terwiel's cumulants the Markovian approximation to arrive to the Quantum Master Equation, for a system interacting with a thermal bath, is revisited.The second order weak coupling approximation is analyzed, then a Kossakowski-Lindblad form for the generator is written in terms of the position and momentum operators.A weak coupling approximation for the stochastic non-Markovian wave function is worked out.A free particle model interacting with a thermal quantum bath is studied in the context of Schr ödinger-Langevin picture.A phenomenological point of view is introduced in order to overcome certain difficulties in the time evolution -in the second order approximation -for the free particle Hamiltonian.
The exact dynamics of a system coupled to an environment can be described by an integro-differential stochastic equation for the reduced density. The influence of the environment is incorporated through a mean field which is both stochastic and nonlocal in time and where the standard two-time correlation functions of the environment appear naturally. Since no approximation is made, the presented theory incorporates exactly dissipative and non-Markovian effects. Applications to the spin-boson model coupled to a heat bath with various coupling regimes and temperature show that the presented stochastic theory can be a valuable tool to simulate exactly the dynamics of open quantum systems. Links with the stochastic Schrödinger equation method and possible extensions to "imaginary time" propagation are discussed.
Positivity preservation is naturally guaranteed in exact non-Markovian master equations for open quantum system dynamics. However, in many approximated non-Markovian master equations, the positivity of the reduced density matrix is not guaranteed. In this paper we provide a general class of time-local, perturbative, and positivity-preserving non-Markovian master equations generated from stochastic Schr\"odinger equations, particularly quantum-state-diffusion equations. Our method has an expanded range of applicability for accommodating a variety of non-Markovian environments. We show the positivity-preserving master equation for a three-level system coupled to a dissipative bosonic environment as a particular example to exemplify our general approach. We illustrate the numerical simulations with an analysis explaining why the previous approximated non-Markovian master equations cannot guarantee positivity. Our work provides a consistent master equation for studying the non-Markovian dynamics in ultrafast quantum processes and strong-coupling systems.
Building upon the work of Hu, Paz, and Zhang [1,2] on open quantum systems we consider the quantum Brownian motion (QBM) model with one oscillator (position variable
x) as the system, {\it nonlinearly} coupled to an environment of
N harmonic oscillators (with mass
mn, natural frequency
ωn, position
qn and momentum
pn variables) in the form
∑n(vn1(x)qnk+vn2(x)pnl) where
k,l are integers (the present work only considers the
k=l=2 cases). The vertex functions $v_{n1}, v_{n2} $ are of the form
vn1=λCn1f(x),vn2(x)=−λCn2mn−2ωn−2f(x) where
Cn1,2 are the coupling constants with the
nth oscillator,
f(x) is any arbitrary function of
x, and
λ is a dimensionless constant. Employing the closed-time-path formalism the influence action
SIF is calculated using a perturbative expansion in
λ. It is possible to identify the terms in
SIF quadratic or higher in
Δ(s)≡f(x+(s))−f(x−(s)) to constitute the noise kernel, while terms linear in
Δ to that of the dissipation kernel. The non-Gaussian noise kernel gives rise to non-zero three-point correlation function of the corresponding stochastic force. The pathway presented here should be useful for the exploration of \textit{non-Gaussian properties of systems nonlinearly coupled with their environments}; examples in early universe cosmology and in quantum optomechanics (QOM) are mentioned. A modified fluctuation-dissipation relation (FDR) is also established, which ensures the consistency of the model and the accuracy of results even at higher perturbative orders. Another result of significance is the derivation of a nonlinear Langevin equation which is expected to be useful for many open quantum system applications.
The dissipative dynamics of a quantum system weakly coupled to one or several reservoirs is usually described in terms of a Lindblad generator. The popularity of this approach is certainly due to the linear character of the latter. However, while such linearity finds justification from an underlying Hamiltonian evolution in some scaling limit, it does not rely on solid physical motivations at small but finite values of the coupling constants, where the generator is typically used for applications. The Markovian quantum master equations we propose are instead supported by very natural thermodynamic arguments. They themselves arise from Markovian master equations for the system and the environment which preserve factorized states and mean energy and generate entropy at a non-negative rate. The dissipative structure is driven by an entropic map, called modular, which introduces nonlinearity. The generated modular dynamical semigroup (MDS) guarantees for the positivity of the time evolved state the correct steady state properties, the positivity of the entropy production, and a positive Onsager matrix with symmetry relations arising from Green-Kubo formulas. We show that the celebrated Davies Lindblad generator, obtained through the Born and the secular approximations, generates a MDS. In doing so we also provide a nonlinear MDS which is supported by a weak coupling argument and is free from the limitations of the Davies generator.
A finite-dimensional quantum system is coupled to a bath of oscillators in thermal equilibrium at temperature T>0 . We show that for fixed, small values of the coupling constant λ , the true reduced dynamics of the system is approximated by the completely positive, trace preserving Markovian semigroup generated by the Davies-Lindblad generator. The difference between the true and the Markovian dynamics is O(|λ|1/4) for all times, meaning that the solution of the Gorini-Kossakowski-Sudarshan-Lindblad master equation is approximating the true dynamics to accuracy O(|λ|1/4) for all times. Our method is based on a recently obtained expansion of the full system-bath propagator. It applies to reservoirs with correlation functions decaying in time as 1/t4 or faster, which is a significant improvement relative to the previously required exponential decay.