The dissipative dynamics of a quantum system weakly coupled to one or several reservoirs is usually described in terms of a Lindblad generator. The popularity of this approach is certainly due to the linear character of the latter. However, while such linearity finds justification from an underlying Hamiltonian evolution in some scaling limit, it does not rely on solid physical motivations at small but finite values of the coupling constants, where the generator is typically used for applications. The Markovian quantum master equations we propose are instead supported by very natural thermodynamic arguments. They themselves arise from Markovian master equations for the system and the environment which preserve factorized states and mean energy and generate entropy at a non-negative rate. The dissipative structure is driven by an entropic map, called modular, which introduces nonlinearity. The generated modular dynamical semigroup (MDS) guarantees for the positivity of the time evolved state the correct steady state properties, the positivity of the entropy production, and a positive Onsager matrix with symmetry relations arising from Green-Kubo formulas. We show that the celebrated Davies Lindblad generator, obtained through the Born and the secular approximations, generates a MDS. In doing so we also provide a nonlinear MDS which is supported by a weak coupling argument and is free from the limitations of the Davies generator.
The dissipative dynamics of a quantum system weakly coupled to one or several reservoirs is usually described in terms of a Lindblad generator. The popularity of this approach is certainly due to the linear character of the latter. However, while such linearity finds justification from an underlying Hamiltonian evolution in some scaling limit, it does not rely on solid physical motivations at small but finite values of the coupling constants, where the generator is typically used for applications. The Markovian quantum master equations we propose are instead supported by very natural thermodynamic arguments. They themselves arise from Markovian master equations for the system and the environment which preserve factorized states and mean energy and generate entropy at a non-negative rate. The dissipative structure is driven by an entropic map, called modular, which introduces nonlinearity. The generated modular dynamical semigroup (MDS) guarantees for the positivity of the time evolved state the correct steady state properties, the positivity of the entropy production, and a positive Onsager matrix with symmetry relations arising from Green-Kubo formulas. We show that the celebrated Davies Lindblad generator, obtained through the Born and the secular approximations, generates a MDS. In doing so we also provide a nonlinear MDS which is supported by a weak coupling argument and is free from the limitations of the Davies generator.
A finite-dimensional quantum system is coupled to a bath of oscillators in thermal equilibrium at temperature T>0 . We show that for fixed, small values of the coupling constant λ , the true reduced dynamics of the system is approximated by the completely positive, trace preserving Markovian semigroup generated by the Davies-Lindblad generator. The difference between the true and the Markovian dynamics is O(|λ|1/4) for all times, meaning that the solution of the Gorini-Kossakowski-Sudarshan-Lindblad master equation is approximating the true dynamics to accuracy O(|λ|1/4) for all times. Our method is based on a recently obtained expansion of the full system-bath propagator. It applies to reservoirs with correlation functions decaying in time as 1/t4 or faster, which is a significant improvement relative to the previously required exponential decay.
In the weak-coupling limit approach to open quantum systems, the presence of the bath is eliminated and accounted for by a master equation that introduces dissipative contributions to the system reduced dynamics: within this framework, there are no bath entropy contributions to the entropy balance. We show that, as a consequence, the entropy production fails to be positive for a class of physically legitimate, that is completely positive and trace preserving, non-Markovian dynamical maps. Moreover, in absence of the semigroup property, if the reduced dynamics has a thermal asymptotic state, this need not be stationary. Then even the integrated entropy production becomes negative. These observations imply that, when the conditions leading to reduced dynamics of semigroup type are relaxed, a consistent formulation of the second law of thermodynamics requires that the environment contribution to the entropy balance be explicitly taken into account.
We study the role of correlations with the environment as the source of non-Markovian quantum evolutions. We first focus on the impact that correlations with the environment can have on the dynamical map that evolve the system. We expand the set of initial states of a system and its environment that are known to guarantee completely positive reduced dynamics for the system when the combined state evolves unitarily. We characterize the correlations in the initial state in terms of its quantum discord. The induced maps can be not completely positive when quantum correlations including, but not limited to, entanglement are present. We discuss the implications and limitations of the Markov approximation necessary to derive the Kossakowski-Lindblad master equation. A generalized non-Markovian master equation is derived from the dynamical map of systems correlated with their environment. The physical meaning of not completely positive maps is studied to obtain a consistent theory of non-Markovian quantum dynamics. These are associated to inverse maps necessary to establish correlations and they give rise to a canonical embedding map that is local in time. This master equation goes beyond the Kossakowski-Lindblad master equation. Non-equilibrium quantum thermodynamics can be be studied within this theory. Through out this discussion, the general dynamics of two interacting qubits is used as an example for illustrations.
We investigate the mathematical structure of entropy-weighted quantum evolution within the framework of open quantum systems. Starting from a system–reservoir interaction model with weak entropy-coupled dynamics, we derive the reduced evolution of the system density matrix under the Born–Markov approximation. The resulting generatoris shown to be of Gorini–Kossakowski–Sudarshan–Lindblad (GKSL) form, ensuring complete positivity and trace preservation. We further demonstrate that the associated dynamical semigroup admits both Stinespring dilation and Kraus operator representations, establishing that entropy-weighted reduced dynamics can be embedded into a fully unitary system environment framework. The entropy operator appearing in the effective description is identified with the positive-semidefinite dissipative structure induced by reservoir corre lation functions.The construction does not modify standard quantum mechanics but provides a parameterization of dissipative generators in terms of entropy-weighted couplings. This establishes a mathematically consis tent bridge between entropy-based dynamical formulations and conventional open quantum system theory.
Markovian reservoir engineering, in which time evolution of a quantum system is governed by a Lindblad master equation, is a powerful technique in studies of quantum phases of matter and quantum information.It can be used to drive a quantum system to a desired (unique) steady state, which can be an exotic phase of matter difficult to stabilize in nature.It can also be used to drive a system to a unitarily evolving subspace, which can be used to store, protect, and process quantum information.In this paper, we derive a formula for the map corresponding to asymptotic (infinite-time) Lindbladian evolution and use it to study several important features of the unique state and subspace cases.We quantify how subspaces retain information about initial states and show how to use Lindbladians to simulate any quantum channels.We show that the quantum information in all subspaces can be successfully manipulated by small Hamiltonian perturbations, jump operator perturbations, or adiabatic deformations.We provide a Lindblad-induced notion of distance between adiabatically connected subspaces.We derive a Kubo formula governing linear response of subspaces to time-dependent Hamiltonian perturbations and determine cases in which this formula reduces to a Hamiltonian-based Kubo formula.As an application, we show that (for gapped systems) the zerofrequency Hall conductivity is unaffected by many types of Markovian dissipation.Finally, we show that the energy scale governing leakage out of the subspaces, resulting from either Hamiltonian or jump-operator perturbations or corrections to adiabatic evolution, is different from the conventional Lindbladian dissipative gap and, in certain cases, is equivalent to the excitation gap of a related Hamiltonian.
An open quantum system is a quantum system that interacts with some environment whose degrees of freedom have been coarse grained away. This model describes non-equilibrium processes more general than scattering-matrix formulations. Furthermore, the microscopically-derived environment provides a model of noise, dissipation and decoherence far more general than Markovian (white noise) models. The latter are fully characterized by Lindblad equations and can be motivated phenomenologically. Non-Markovian processes consistently account for backreaction with the environment and can incorporate effects such as finite temperature and spatial correlations. We consider linear systems with bilinear coupling to the environment, or quantum Brownian motion, and nonlinear systems with weak coupling to the environment. For linear systems we provide exact solutions with analytical results for a variety of spectral densities. Furthermore, we point out an important mathematical subtlety which led to incorrect master-equation coefficients in earlier derivations, given nonlocal dissipation. For nonlinear systems we provide perturbative solutions by translating the formalism of canonical perturbation theory into the context of master equations. It is shown that unavoidable degeneracy causes an unfortunate reduction in accuracy between perturbative master equations and their solutions. We also extend the famous theorem of Lindblad, Gorini, Kossakowski and Sudarshan on completely positivity to non-Markovian master equations. Our application is primarily to model atoms interacting via a common electromagnetic field. The electromagnetic field contains correlations in both space and time, which are related to its relativistic (photon-mediated) nature. As such, atoms residing in the same field experience different environmental effects depending upon their relative position and orientation. Our more accurate solutions were necessary to assess sudden death of entanglement at zero temperature. In contrast to previous claims, we found that all initial states of two-level atoms undergo finite-time disentanglement. We were also able to access regimes which cannot be described by Lindblad equations and other simpler methods, such as near resonance. Finally we revisit the infamous Abraham-Lorentz force, wherein a single particle in motion experiences backreaction from the electromagnetic field. This leads to a number of well-known problems including pre-acceleration and runaway solutions. We found a more a more-suitable open-system treatment of the nonrelativistic particle to be perfectly causal and dissipative without any extraneous requirements for finite size of the particle, weak coupling to the field, etc..