A quantum efficiency of 65% (corresponding to a power efficiency of 2640%) was achieved in up-conversion of λ = 10.8 μ CO2 laser radiation by resonant parametric mixing in sodium vapor.
A study was made of the dependences of the efficiency of resonant parametric frequency conversion in sodium vapor on the infrared radiation wavelength, vapor density, and detuning from two-photon pump resonance. It was found in this conversion system that for each infrared wave the conversion efficiency had three maxima on tuning the frequency of two-photon pumping over the region of a forbidden transition. The principal maximum was realized for accurate two-photon resonance, and the two other maxima resulted from a rise in the cubic susceptibility close to single-photon sum-frequency resonances. A quantum efficiency of 35% was achieved for a 9.26 μ infrared wave.
An experimental investigation was made of resonant nonlinear four-wave frequency mixing processes involving cw laser radiation in sodium vapor. It was found that, in spite of an increase in absorption, the use of resonant atomic nonlinearities can substantially improve the frequency conversion efficiency in the cw regime. The results of the measurements were compared with the theoretical conclusions. Ultraviolet radiation was generated at the sum frequency ( λ s = 268 nm) with the proportionality factor C = W s / W 1 W 2 W 3 ≈2W −2
Frequency conversion of cw CO 2 laser radiation to the 276.8 nm ultraviolet range was achieved in a mixture of thallium and cesium vapor by parametric mixing with radiation from a rhodamine 6G dye laser. Two-photon resonance of the pump radiation with the 6 P 1/2 –7 P 3/2 forbidden transition and the proximity of the converted radiation frequency to the frequency of the 6 D 3/2 –7 P 3/2 transition in the thallium atom were utilized. Cesium vapor was used to match the refractive indices of the interacting waves.