An investigation was made of frequency conversion in sodium vapor. When the phase-matching conditions were satisfied and the nonlinear susceptibility increased under signal resonance conditions, the quantum efficiency of the conversion process was 40% at low pumping rates.
An experimental investigation was made of resonant nonlinear four-wave frequency mixing processes involving cw laser radiation in sodium vapor. It was found that, in spite of an increase in absorption, the use of resonant atomic nonlinearities can substantially improve the frequency conversion efficiency in the cw regime. The results of the measurements were compared with the theoretical conclusions. Ultraviolet radiation was generated at the sum frequency ( λ s = 268 nm) with the proportionality factor C = W s / W 1 W 2 W 3 ≈2W −2
A study was made of the dependences of the efficiency of resonant parametric frequency conversion in sodium vapor on the infrared radiation wavelength, vapor density, and detuning from two-photon pump resonance. It was found in this conversion system that for each infrared wave the conversion efficiency had three maxima on tuning the frequency of two-photon pumping over the region of a forbidden transition. The principal maximum was realized for accurate two-photon resonance, and the two other maxima resulted from a rise in the cubic susceptibility close to single-photon sum-frequency resonances. A quantum efficiency of 35% was achieved for a 9.26 μ infrared wave.
This paper reports an investigation of parametric frequency conversion in a vapor of Rb87 atoms in which nearly resonant optical waves are coupled with microwaves at the ground-state hyperfine-structure (hfs) frequency of Rb87 by the nonlinear susceptibilities of Rb87 vapor. These nonlinear susceptibilities are greatly enhanced by optical pumping of the ground-state hfs levels of Rb87 and by using nearly resonant light. The frequency-conversion process generates optical sideband waves which are separated in frequency from the carrier light waves by the ground-state hfs frequency of Rb87 (6.835 GHz). These sidebands have been directly observed in the spectral profiles of Rb85 resonance light which had passed through Rb87 vapor. The conversion efficiency of power from the carrier waves to the sideband waves in a 45-cm length of vapor was greater than 1%. The observed behavior of the sidebands is in excellent qualitative agreement with the predictions of a semiclassical theory.