We report efficient up-conversion of low-level ir radiation near 10 μ to the near ultraviolet. Radiation at 9.26 μ is converted to 3305 Å with a photon conversion efficiency of 58% and a corresponding power gain of 16.2. The process employs resonant two-photon pumping of the nonallowed 3s-3d transition in Na.
A study was made of the dependences of the efficiency of resonant parametric frequency conversion in sodium vapor on the infrared radiation wavelength, vapor density, and detuning from two-photon pump resonance. It was found in this conversion system that for each infrared wave the conversion efficiency had three maxima on tuning the frequency of two-photon pumping over the region of a forbidden transition. The principal maximum was realized for accurate two-photon resonance, and the two other maxima resulted from a rise in the cubic susceptibility close to single-photon sum-frequency resonances. A quantum efficiency of 35% was achieved for a 9.26 μ infrared wave.