Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Log inSign up
Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Blog
Job Board
Q3AS

© 2026 Aqora Quantum S.A.S.

TermsPrivacyLegal Notice

Physical Review A

Nonadiabatic transitions in finite-time adiabatic rapid passage

Tianshi Lü, X. Miao, H. Metcalf

Published Jun 26, 2007• 20 citations
Publisher

Abstract

To apply the adiabatic rapid passage process repetitively [T. Lu, X. Miao, and H. Metcalf, Phys. Rev. A 71, 061405(R) (2005)], the nonadiabatic transition probability of a two-level atom subject to chirped light pulses over a finite period of time needs to be calculated. Using a unitary first-order perturbation method in the rotating adiabatic frame, an approximate formula has been derived for such transition probabilities in the entire parameter space of the pulses.

DOI
10.1103/physreva.75.063422

Related papers

Population Inversion in Optical Adiabatic Rapid Passage with Phase Relaxation

Yōsuke Kayanuma

The transition probability $P$ in the optical adiabatic rapid passage is calculated for a two-level model with dephasing. In the limit $\frac{{T}_{2}}{{\ensuremath{\tau}}_{p}}\ensuremath{\rightarrow}0$, where ${T}_{2}$ is the dephasing time and ${\ensuremath{\tau}}_{p}$ is the time scale of passage through the resonance region, $P$ is given by $P=\frac{[1\ensuremath{-}\mathrm{exp}(\ensuremath{-}\frac{\ensuremath{\pi}{\ensuremath{\chi}}^{2}}{|\stackrel{\ifmmode \dot{}\else \.{}\fi{}}{\ensuremath{\omega}}|})]}{2}$ in which $\ensuremath{\chi}$ is the Rabi flopping frequency at resonance and $\stackrel{\ifmmode \dot{}\else \.{}\fi{}}{\ensuremath{\omega}}$ is the time derivative of the offset angular frequency. Generally, $P$ takes its maximum value at an intermediate $\stackrel{\ifmmode \dot{}\else \.{}\fi{}}{\ensuremath{\omega}}$ for fixed $\ensuremath{\chi}$ and is bounded by the above formula and by $P=1\ensuremath{-}\mathrm{exp}(\ensuremath{-}\frac{\ensuremath{\pi}{\ensuremath{\chi}}^{2}}{2|\stackrel{\ifmmode \dot{}\else \.{}\fi{}}{\ensuremath{\omega}}|})$, which gives the asymptotic value in the limit $\frac{{T}_{2}}{{\ensuremath{\tau}}_{p}}\ensuremath{\rightarrow}\ensuremath{\infty}$.

Physical Review Letters•May 11, 1987•39 citations

Short-pulse chirped adiabatic population transfer in diatomic molecules

Shimshon Kallush, Y. B. Band

Using the concept of light-induced potentials introduced by Garraway and Suominen [Phys. Rev. Lett. 80, 932 (1998)], we study alternative schemes of adiabatic population transfer in a diatomic molecule from the lowest vibrational level of the ground electronic state to the lowest vibrational level of a third electronic state via allowed optical transitions from the ground and third electronic states to a second electronic state. Our chirped-pulse rapid adiabatic passage scheme is implemented with short-duration optical pulses, and can be understood in terms of ``road design engineering'' of the light-induced time-dependent adiabatic potential upon which the dynamics occurs. We explicitly show that complete adiabatic vibronic population transfer occurs using chirped picosecond-duration pulses in the sodium dimer example.

Physical Review A•Feb 28, 2000•49 citations

Coherent population transfer in molecules coupled with a dissipative environment by intense ultrashort chirped pulse. II. A simple model

Boris D. Fainberg, Vladimir A. Gorbunov

We have developed a simple and physically clear picture of adiabatic rapid passage (ARP) in molecules in solution by careful examination of all the conditions needed for ARP. The relaxation effects were considered in the framework of the Landau-Zener model for random crossing of levels. The model enables us to include into consideration non-Markovian Gaussian-correlated noise. It explains all the numerical results obtained in the first paper of the series [B. D. Fainberg and V. A. Gorbunov, J. Chem. Phys. 117, 7222 (2002)], in particular, that for positive chirp pulse excitation relaxation favors more efficient population transfer with respect to the relaxation-free system with frozen nuclear motion. We also relate parameters of non-Markovian Gaussian-correlated noise with irreversible dephasing time of an optical transition by calculating the photon echo signal attenuation.

The Journal of Chemical Physics•Nov 2, 2004•18 citations

Bloch theorem on the Bloch sphere

Tianshi Lü, X. Miao, H. Metcalf

Motivated by the production of strong optical forces on atoms, we have done numerical studies of adiabatic rapid passage in light that is both frequency and amplitude modulated in the form of chirped pulses, and we found unanticipated regularities. We have quantified these regularities in terms of a periodic Hamiltonian, and obtained a result similar to the Bloch theorem, but in the time domain. This led to further numerical studies and a quantitative description of the behavior of an atom under multiply repetitive sweeps.

Physical Review A•Jun 27, 2005•30 citations

Control of molecular processes by a sequence of linearly chirped pulses

K. Nagaya, Yoshiaki Teranishi, Hiroki Nakamura

A new scheme of controlling molecular processes by a sequence of linearly chirped pulses is proposed and is applied to selective excitation of an energy level among closely lying ones and to complete electronic excitation of a diatomic molecule. The basic idea is quite different from the conventional ones utilizing chirped pulses in the sense that the present one does not rely on the idea of adiabatic rapid passage at all, but tries to control basic nonadiabatic transitions explicitly. Control of molecular processes can be achieved by controlling nonadiabatic transitions among Floquet (or dressed) states with use of the interference effects. The scheme can be formulated with use of the analytical theories of nonadiabatic transitions, and the proper control parameters can be estimated theoretically. Numerical demonstrations are provided to confirm the robustness of the method in comparison with the other conventional ones. Namely, the present scheme is shown to be stable against the variation of pulse area, complete and selective in population transfer, and fast to accomplish the transition. It is expected that the method can be applied to general multilevel systems and various types of wave packet dynamics. Its experimental realizability can also be expected, since linear chirping can now be relatively easily realized and manipulated.

The Journal of Chemical Physics•Nov 14, 2002•15 citations

Generation of Dicke states using adiabatic passage

Kenji Toyoda, Toshikazu Watanabe, T. Kimura +3 more

Entangled states of two ions are realized by using an adiabatic process. Based on the proposal by Linington and Vitanov [Phys. Rev. A 77, 010302 (2008)], we have generated Dicke states in optical qubits of two $^{40}\mathrm{Ca}$${}^{+}$ ions by applying frequency-chirped optical pulses with time-dependent envelopes to perform rapid adiabatic passage on sideband transitions. One of the biggest advantages of adiabatic approaches is their robustness against variations in experimental parameters, which is verified by performing experiments for different pulse widths or peak Rabi frequencies. Fidelities exceeding 0.5, which is the threshold for inseparable states, are obtained over wide ranges of parameter values.

arXiv:1101.4515•Physical Review A•Feb 17, 2011•30 citations
To apply the adiabatic rapid passage process repetitively [T. Lu, X. Miao, and H. Metcalf, Phys. Rev. A 71, 061405(R) (2005)], the nonadiabatic transition probability of a two-level atom subject to chirped light pulses over a finite period of time needs to be calculated. Using a unitary first-order perturbation method in the rotating adiabatic frame, an approximate formula has been derived for such transition probabilities in the entire parameter space of the pulses.
The transition probability PPP in the optical adiabatic rapid passage is calculated for a two-level model with dephasing. In the limit $\frac{{T}_{2}}{{\ensuremath{\tau}}_{p}}\ensuremath{\rightarrow}0$, where T2{T}_{2}T2​ is the dephasing time and ${\ensuremath{\tau}}_{p}$ is the time scale of passage through the resonance region, PPP is given by $P=\frac{[1\ensuremath{-}\mathrm{exp}(\ensuremath{-}\frac{\ensuremath{\pi}{\ensuremath{\chi}}^{2}}{|\stackrel{\ifmmode \dot{}\else \.{}\fi{}}{\ensuremath{\omega}}|})]}{2}$ in which $\ensuremath{\chi}$ is the Rabi flopping frequency at resonance and $\stackrel{\ifmmode \dot{}\else \.{}\fi{}}{\ensuremath{\omega}}$ is the time derivative of the offset angular frequency. Generally, PPP takes its maximum value at an intermediate $\stackrel{\ifmmode \dot{}\else \.{}\fi{}}{\ensuremath{\omega}}$ for fixed $\ensuremath{\chi}$ and is bounded by the above formula and by $P=1\ensuremath{-}\mathrm{exp}(\ensuremath{-}\frac{\ensuremath{\pi}{\ensuremath{\chi}}^{2}}{2|\stackrel{\ifmmode \dot{}\else \.{}\fi{}}{\ensuremath{\omega}}|})$, which gives the asymptotic value in the limit $\frac{{T}_{2}}{{\ensuremath{\tau}}_{p}}\ensuremath{\rightarrow}\ensuremath{\infty}$.
Using the concept of light-induced potentials introduced by Garraway and Suominen [Phys. Rev. Lett. 80, 932 (1998)], we study alternative schemes of adiabatic population transfer in a diatomic molecule from the lowest vibrational level of the ground electronic state to the lowest vibrational level of a third electronic state via allowed optical transitions from the ground and third electronic states to a second electronic state. Our chirped-pulse rapid adiabatic passage scheme is implemented with short-duration optical pulses, and can be understood in terms of ``road design engineering'' of the light-induced time-dependent adiabatic potential upon which the dynamics occurs. We explicitly show that complete adiabatic vibronic population transfer occurs using chirped picosecond-duration pulses in the sodium dimer example.
We have developed a simple and physically clear picture of adiabatic rapid passage (ARP) in molecules in solution by careful examination of all the conditions needed for ARP. The relaxation effects were considered in the framework of the Landau-Zener model for random crossing of levels. The model enables us to include into consideration non-Markovian Gaussian-correlated noise. It explains all the numerical results obtained in the first paper of the series [B. D. Fainberg and V. A. Gorbunov, J. Chem. Phys. 117, 7222 (2002)], in particular, that for positive chirp pulse excitation relaxation favors more efficient population transfer with respect to the relaxation-free system with frozen nuclear motion. We also relate parameters of non-Markovian Gaussian-correlated noise with irreversible dephasing time of an optical transition by calculating the photon echo signal attenuation.
Motivated by the production of strong optical forces on atoms, we have done numerical studies of adiabatic rapid passage in light that is both frequency and amplitude modulated in the form of chirped pulses, and we found unanticipated regularities. We have quantified these regularities in terms of a periodic Hamiltonian, and obtained a result similar to the Bloch theorem, but in the time domain. This led to further numerical studies and a quantitative description of the behavior of an atom under multiply repetitive sweeps.
A new scheme of controlling molecular processes by a sequence of linearly chirped pulses is proposed and is applied to selective excitation of an energy level among closely lying ones and to complete electronic excitation of a diatomic molecule. The basic idea is quite different from the conventional ones utilizing chirped pulses in the sense that the present one does not rely on the idea of adiabatic rapid passage at all, but tries to control basic nonadiabatic transitions explicitly. Control of molecular processes can be achieved by controlling nonadiabatic transitions among Floquet (or dressed) states with use of the interference effects. The scheme can be formulated with use of the analytical theories of nonadiabatic transitions, and the proper control parameters can be estimated theoretically. Numerical demonstrations are provided to confirm the robustness of the method in comparison with the other conventional ones. Namely, the present scheme is shown to be stable against the variation of pulse area, complete and selective in population transfer, and fast to accomplish the transition. It is expected that the method can be applied to general multilevel systems and various types of wave packet dynamics. Its experimental realizability can also be expected, since linear chirping can now be relatively easily realized and manipulated.
Entangled states of two ions are realized by using an adiabatic process. Based on the proposal by Linington and Vitanov [Phys. Rev. A 77, 010302 (2008)], we have generated Dicke states in optical qubits of two 40Ca^{40}\mathrm{Ca}40Ca+{}^{+}+ ions by applying frequency-chirped optical pulses with time-dependent envelopes to perform rapid adiabatic passage on sideband transitions. One of the biggest advantages of adiabatic approaches is their robustness against variations in experimental parameters, which is verified by performing experiments for different pulse widths or peak Rabi frequencies. Fidelities exceeding 0.5, which is the threshold for inseparable states, are obtained over wide ranges of parameter values.