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Nanotechnology

An integrated superconductive magnetic nanosensor for high-sensitivity nanoscale applications

C. Granata, E. Esposito, Antonio Vettoliere, Lucia Petti, M. Russo

Published May 27, 2008• 82 citations
Publisher

Abstract

An integrated magnetic nanosensor based on a niobium dc SQUID (superconducting quantum interference device) for nanoscale applications is presented. The sensor, having a washer shape with a hole of 200 nm and two Josephson-Dayem nanobridges of 80 nm × 100 nm, consists of a Nb(30 nm)/Al(30 nm) bilayer patterned by electron beam lithography (EBL) and shaped by lift-off and reactive ion etch (RIE) processes. The presence of the niobium coils, integrated on-chip and tightly coupled to the SQUID, allows us to easily excite the sensor in order to get the voltage-flux characteristics and to flux bias the SQUID at its optimal point. The measurements were performed at liquid helium temperature. A voltage swing of 75 µV and a maximum voltage-flux transfer coefficient (responsivity) as high as 1 mV/Φ(0) were directly measured from the voltage-flux characteristic. The noise measurements were performed in open loop mode, biasing the SQUID with a dc magnetic flux at its maximum responsivity point and using direct-coupled low-noise readout electronics. A white magnetic flux noise spectral density as low as 2.5 μΦ(0) Hz(-1/2) was achieved, corresponding to a magnetization or spin sensitivity in units of the Bohr magneton of 100 spin Hz(-1/2). Possible applications of this nanosensor can be envisaged in magnetic detection of nanoparticles and small clusters of atoms and molecules, in the measurement of nanoobject magnetization, and in quantum computing.

DOI
10.1088/0957-4484/19/27/275501

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We have performed preliminary measurements with and without iron oxide nanoparticles on the SQUID loop showing that the presence of magnetic nanoparticles can be easily detected and the magnetic relaxation curve measured. To test the capability of our devices in order to detect the magnetization of nanoparticles, we deposited iron oxide nanoparticles, having an average diameter of about 16nm, on chips containing characterized sensors. Here we report the measurement performed on the device with 1μm loop. The presence of iron nanoparticles did not change appreciably the magnetic pattern obtained using the integrated coil (magnetic field normal to the SQUID plane), however the nanoparticle presence was evident by the critical current measurement performed with magnetic field generated using the external solenoid (magnetic field parallel to the SQUID plane). Using the measured responsivity for this particular device (27μA/Φ0) the critical current variation was converted to magnetic flux variation. It is worth to note that with the present electronic at 100Hz to acquire 104 measurements it takes about 100s. The above results clearly indicating that the sensor can be effectively used in nano-magnetism applications.

•Jan 1, 2010•0 citations

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IEEE Transactions on Applied Superconductivity•Dec 11, 2012•6 citations
An integrated magnetic nanosensor based on a niobium dc SQUID (superconducting quantum interference device) for nanoscale applications is presented. The sensor, having a washer shape with a hole of 200 nm and two Josephson-Dayem nanobridges of 80 nm × 100 nm, consists of a Nb(30 nm)/Al(30 nm) bilayer patterned by electron beam lithography (EBL) and shaped by lift-off and reactive ion etch (RIE) processes. The presence of the niobium coils, integrated on-chip and tightly coupled to the SQUID, allows us to easily excite the sensor in order to get the voltage-flux characteristics and to flux bias the SQUID at its optimal point. The measurements were performed at liquid helium temperature. A voltage swing of 75 µV and a maximum voltage-flux transfer coefficient (responsivity) as high as 1 mV/Φ(0) were directly measured from the voltage-flux characteristic. The noise measurements were performed in open loop mode, biasing the SQUID with a dc magnetic flux at its maximum responsivity point and using direct-coupled low-noise readout electronics. A white magnetic flux noise spectral density as low as 2.5 μΦ(0) Hz(-1/2) was achieved, corresponding to a magnetization or spin sensitivity in units of the Bohr magneton of 100 spin Hz(-1/2). Possible applications of this nanosensor can be envisaged in magnetic detection of nanoparticles and small clusters of atoms and molecules, in the measurement of nanoobject magnetization, and in quantum computing.
We report on the design, the fabrication and the performance of an integrated magnetic nano-sensor based on niobium dc-SQUID (Superconducting QUantum Interference Device) for nanoscale applications is presented. The nano-sensors are based on nanometric niobium constrictions (Dayem bridges) inserted in a square loop having a side length of 200 nm. Measurements of voltage-flux characteristic, flux to voltage transfer factor and noise performances are reported. In small signal mode, the sensors have shown a magnetic flux noise spectral density of 1.5 μΦ 0 /Hz 1/2 corresponding to a spin sensitivity in unit of Bohr magneton of 60 spin/Hz 1/2 . Supercurrent decay measurements of these devices are also reported. Such measurements provide useful information for applications which employ the SQUID as a trigger where the sensor works on the zero voltage state. The experimental data, have shown an intrinsic current fluctuation less than 0.2% of the critical current at liquid helium temperature, corresponding to an intrinsic sensor magnetic flux resolution of a few mΦ 0 . In view of the nano-SQUID employments in the detection of small spin populations, the authors calculated the spin sensitivity and the magnetic response relative to the single spin, as a function of its position within the SQUID hole. The results show that the SQUID response depends strongly on the spin position.
Dayem Bridge Based Nano-SQUID for High Sensitive Nanoscale Applications A recent progress in nanotechnology formulates the fabrication of SQUIDs loop less than 100 nm; its obtaining an adequate sensitivity to detect the magnetic nano-objects. These nano-SQUIDs can be employed to measure small clusters of atomic magnetic moment, to obtain an inductive readout sensor in single-photon detectors and they have been proposed as a magnetic qubit for quantum computing. The research activities at CNR-ICIB has been devoted to the design, fabrication and characterization of nano-SQUIDs based on niobium Dayem Bridge and its magnetization measurements of nanoparticles for advance study of nanomagnetism. Here, I have reported the designs, the fabrication processes and the experimental performances (voltage flux characteristics, spin noise performance) of these nano-devices and also the groundwork measurement of nanoparticles magnetization using switching current measurement method operating in CNR-ICIB laboratory. Design and Fabrication: Many devices are fabrication using advanced electron beam lithography techniques with conventional photolithography, lift off and reactive ion etching techniques. The fabricated devices can be divided into two categories, first bilayer device or non hysteretic device and second single layer device or hysteretic device. a)Non-Hysteretic Device: The bilayer device consists of a niobium loop with a hole of 200nm interrupted by two bridges having length and width dimensions of 100nm X 80nm, 80nm X 60nm etc. The superconducting loop has a washer shape in order to enhance the heat dissipation during the working operations when the sensor is current biased in resistive mode. The device includes a micrometric integrated niobium coil located very close to the nano-sensor in order to modulate, tune and operate the SQUID in FLL mode. b)Hysteretic Device: The single layer devices having two Dayem Bridges of 90nm x 250nm and loop sizes of 2, 1 and 0.75μm, consist of a single niobium layer 20nm thick pattern by electron beam lithography and shaped by lift-off. The SQUIDs were designed to have a hysteretic current-voltage characteristic in order to work as a magnetic flux-current transducer. Performances: a)Non-Hysteretic Device: An intrinsic voltage swing and a maximum responsivity of 75 μV and 1.5 mV/Φ0 can be estimated from the experimental data. Our interest is focused on the characterization in small signal mode, because the magnetic flux coupled into device is expected to be much smaller than Ф0. In fact, such devices are designed to measure very small magnetic fields arising from a local nano-object. The sensor exhibits a magnetic flux noise level of 1.5μΦ0/Hz1/2 in the white region corresponding to a spin noise, in unit of Bohr magneton, of Sn1/2=2aSΦ1/2/(μBμ0)~60 spin/Hz1/2 where a is the radius of the SQUID loop, μ0 is the magnetic vacuum permeability and μB = 9.27 × 10−24 J/T. This value is comparable with the best value reported in the literature. It is worth noting that these sensors show a wide linear region in the V- Φ characteristics; the non-linearity effects are not evident up to 0.02 Φ0. b)Hysteretic Device: The second single layer device shows hysteretic I-V characteristics which are used as magnetic flux-current transducer. The magnetic pattern determines the responsivity of the SQUID, defined as the variation of the critical current as function of the external magnetic flux variation dIc/dΦ; in the present work responsivity up to 30μA/Φ0 have been obtained. The maximum magnetic flux coupled to the 2 and 1 micron loop size is about 2 and 0.5 Φ0 respectively. A critical current modulation is about 20%. An intrinsic sensor magnetic flux resolution less than 1 mΦ0, can be estimated from the intrinsic current fluctuation. The main interest of such devices is magnetization measurement of small magnetic particles by switching current techniques. Simulation Results: We have computed performance of nano-superconducting-quantum-interference devices (SQUIDs) in view of their employment in the detection of small spin populations. The analysis has been focused on nano-SQUID sensors having a square loop with a side length of 200 nm. We have calculated the spin sensitivity and the magnetic response relative to the single Bohr magneton (single spin), as a function of its position within the SQUID hole. The results predict that the SQUID response depends strongly on the spin position. The projected information’s are very useful to optimize the sensor performance in view of the most nanomagnetism applications. Preliminary Measurements of Nanoparticle Magnetization: We have effectively employed non-hysteretic sensor for nanoparticle magnetization investigation in view of nano-magnetism applications. We have performed preliminary measurements with and without iron oxide nanoparticles on the SQUID loop showing that the presence of magnetic nanoparticles can be easily detected and the magnetic relaxation curve measured. To test the capability of our devices in order to detect the magnetization of nanoparticles, we deposited iron oxide nanoparticles, having an average diameter of about 16nm, on chips containing characterized sensors. Here we report the measurement performed on the device with 1μm loop. The presence of iron nanoparticles did not change appreciably the magnetic pattern obtained using the integrated coil (magnetic field normal to the SQUID plane), however the nanoparticle presence was evident by the critical current measurement performed with magnetic field generated using the external solenoid (magnetic field parallel to the SQUID plane). Using the measured responsivity for this particular device (27μA/Φ0) the critical current variation was converted to magnetic flux variation. It is worth to note that with the present electronic at 100Hz to acquire 104 measurements it takes about 100s. The above results clearly indicating that the sensor can be effectively used in nano-magnetism applications.
A superconducting quantum interference device (SQUID) miniaturized into the nanoscale is promising in the inductive detection of a single electron spin. A nano-SQUID with a strong spin coupling coefficient, a low flux noise, and a wide working magnetic field range is highly desired in a single spin resonance measurement. Nano-SQUIDs with Dayem bridge junctions excel in a high working field range and in the direct coupling from spins to the bridge. However, the common planar structure of nano-SQUIDs is known for problems such as a shallow flux modulation depth and a troublesome hysteresis in current–voltage curves. Here, we developed a fabrication process for creating three-dimensional (3-D) niobium (Nb) nano-SQUIDs with nanobridge junctions that can be tuned independently. Characterization of the device shows up to 45.9% modulation depth with a reversible current–voltage curve. Owning to the large modulation depth, the measured flux noise is as low as 0.34 μΦ 0 /Hz 1/2 . The working field range of the SQUID is greater than 0.5 T parallel to the SQUID plane. We believe that 3-D Nb nano-SQUIDs provide a promising step toward effective single-spin inductive detection.
Abstract Nano-superconducting quantum interference devices (nano-SQUIDs) with high energy sensitivity and spatial resolution are essential in many applications such as single spin detection, nano-electromechanical vibration detection and microscale magnetic imaging. This paper studies a Dayem-type niobium nano-SQUID using focus ion beam milling technology. The device has two 42 nm × 60 nm nano-bridges and an integrated on-chip Nb modulation flux line located beside the SQUID loop with a 100 nm nanogap. The non-hysteretic temperature range of the nano-SQUID is about 1.4 K from 4.6 K to 6.0 K, which could broaden the operation temperature range of the device. The maximal transfer coefficient V Φ and peak-to-peak voltage ΔV are 8.53 mV/Φ 0 and 430 μV at 4.8 K, respectively.
The growing interest in the development of nano-superconducting quantum interference devices (nanoSQUIDs) and their applications in nanoscience demands a deep study of these ultra-high-sensitivity nanodevices. In this paper, the main features of niobium planar nanointerferometers as a function of the temperature have been investigated. In particular, two types of nanodevices have been realized and studied: one based on nanobridges and the other on sub-micron Josephson tunnel junctions (JTJs). The nanobridge-based nanointerferometer, fabricated by electron beam lithography (EBL), consists of a sub-micrometric loop (effective area of 0.5 μ m 2 ), interrupted by two Dayem nanobridges having a width and length of 50 and 80 nm respectively. The JTJs-based nanointerferometer has two Nb/Al-AlO x /Nb SNIS (superconductor/normal-insulator/superconductor) junctions with an area of 0.09 μ m 2 , connected by a rectangular loop (1 μ m × 0.2 μ m), and realized by the three-dimensional focused ion beam (3D FIB) sculpting technique. For both nanodevices, measurements of current–voltage characteristics and critical current versus external magnetic flux have been performed at operating temperatures ranging from 4.2 to 1.2 K. The critical current modulation depths, magnetic flux to current transfer factor (current responsivity) and magnetic flux resolution as a function of the temperature have been evaluated for both nanosensors. Furthermore, measurements of the voltage–magnetic flux characteristics and the spectral density of magnetic flux noise have been performed at T = 4.2 K.
We report on the low-frequency noise performance of niobium dc superconducting quantum interference devices (SQUIDs), which contain nanobridges fabricated by focused ion beam lithography as the active Josephson elements. The devices have feature sizes down to 70 nm. We have measured devices of different loop sizes in two readout configurations: nano-scale loop sizes in small signal mode using a series SQUID array as a low-temperature pre-amplifier, and larger micron-scale loop sizes in a conventional flux-locked loop. We investigate the different contributions to the low frequency noise and report on electrical measurements made in applied magnetic fields of up to 0.5 T (in-plane) and 0.1 T (perpendicular to the plane) at operating temperatures around 7 K. We compare the measurements with the existing theories of noise in a dc SQUID.