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Physics of the Solid State

Superluminescence of Er3+ in an amorphous silicon matrix

Vladimir I Emel'yanov, Boris V. Kamenev, Pavel K. Kashkarov, Ekaterina I. Konstantinova, Victor Yu. Timoshenko, Е. И. Теруков, Mikhail S. Bresler, Oleg B. Gusev

Published Aug 1, 2000• 2 citations
Publisher

Abstract

The photoluminescence of Er 3+ ions in thin films of amorphous silicon has been studied under conditions of intense pumping. A superlinear increase in the amplitude and a shortening of the photoluminescence relaxation times are revealed at a pumping intensity above 200 kW/cm 2 . The data obtained are explained by the threshold “switching-on” of the superluminescence mechanism.

DOI
10.1134/1.1307043

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Based on a detailed consideration of excitation mechanisms of erbium in crystalline and amorphous matrix we present an analysis of the physical meaning of the Auger excitation cross section of ${\mathrm{Er}}^{3+}$ ions in semiconductor. It is demonstrated that large values of Auger excitation cross sections under optical pumping in semiconductor matrices are due to large values of band-to-band absorption coefficient exceeding by several orders of magnitude the absorption coefficient of erbium in dielectric ${\mathrm{SiO}}_{2}$ and ${\mathrm{Al}}_{2}{\mathrm{O}}_{3}$ matrix. The Auger excitation cross section of ${\mathrm{Er}}^{3+}$ in semiconductor matrices is roughly given by the ratio of the matrix absorption coefficient to concentration of ${\mathrm{Er}}^{3+}$ ions. While the analysis of the excitation cross section is carried out for Er-doped crystalline and amorphous silicon, the results are expected to be applicable to the other rare-earth doped semiconductors. Based on low-temperature experimental results for crystalline silicon we get the Auger excitation coefficient of ${c}_{A}^{\mathrm{cryst}}\ensuremath{\approx}7\ifmmode\times\else\texttimes\fi{}{10}^{\ensuremath{-}10} {\mathrm{cm}}^{3}{\mathrm{s}}^{\ensuremath{-}1}$ and the effective excitation cross section ${\ensuremath{\sigma}}_{\mathrm{eff}}^{\mathrm{cryst}}=(2\ensuremath{-}8)\ifmmode\times\else\texttimes\fi{}{10}^{\ensuremath{-}12} {\mathrm{cm}}^{2}.$ For amorphous silicon at 100 K we obtain ${\ensuremath{\sigma}}_{\mathrm{eff}}^{\mathrm{amorph}}\ensuremath{\approx}1.4\ifmmode\times\else\texttimes\fi{}{10}^{\ensuremath{-}14} {\mathrm{cm}}^{2}.$

Physical review. B, Condensed matter•Jul 5, 2001•52 citations
The photoluminescence of Er 3+ ions in thin films of amorphous silicon has been studied under conditions of intense pumping. A superlinear increase in the amplitude and a shortening of the photoluminescence relaxation times are revealed at a pumping intensity above 200 kW/cm 2 . The data obtained are explained by the threshold “switching-on” of the superluminescence mechanism.
Photoluminescence (PL) spectra of Er3+ in an Er-doped silicon film were recorded at 2 and 77 K over the wavelength range from 1.52 to 1.68 μm, which includes optical transitions between the Er3+ I13/24 and I15/24 manifolds. These spectra were then analyzed to determine the nature of the electrostatic field at the site of the Er ion that governs the ion’s optical behavior. The PL spectra were analyzed three different ways: by considering the Er3+ ions to be occupying sites of Td, C3, or D2d point group symmetry. Transition energies and magnetic dipole transition probabilities were calculated for each case by diagonalizing a Hamiltonian representing the free-ion and crystal-field interactions in a Russell–Saunders basis of states spanning the lowest 15 J multiplets of the 4f11 electronic configuration of Er3+. Crystal-field parameters were varied in each case to find the best agreement with the experiment. Our results showed that the site symmetry of the Er3+ ions most consistent with the data is D2d. For this case, the rms deviation between the experimental and calculated energy levels is 3.3 cm−1 with the calculated magnetic dipole transition probabilities in qualitative agreement with the experiment.
We report a strong increase in the intensity of spontaneous emission from erbium ions embedded into an active layer of amorphous silicon oxide (a-SiO x ) in a planar microcavity based on a-Si:H/a-SiO x layers. Using eigenmodes of this microcavity both for excitation (pumping) and for the extraction of photoluminescence, it is possible to increase the spontaneous emission intensity from erbium ions by a factor of about 500 as compared to the photoluminescence from a single doped a-SiO x (Er) film.
The spectra and photoluminescence kinetics of Er 3+ ions embedded in amorphous fluorine- and chlorine-doped silica matrices synthesized by surface-plasma chemical vapor deposition were investigated at 27–300 K. Luminescence was excited with an Ar + laser at a wavelength of 514.5 nm and with a diode laser at a wavelength of 975 nm. Narrow and well-expressed components of Stark sublevels with a small contribution of inhomogeneous broadening intrinsic to Er 3+ ions in crystalline rather than amorphous matrices were revealed and identified in photoluminescence spectra. The structure of Stark sublevels was well-resolved at low temperatures. The presence of the well-resolved Stark structure in spectra was indicative of stable anion complex formation in Er 3+ environment presumably associated with halogen incorporation. This environment was formed at a stage of the low-temperature plasma-chemical synthesis and was destroyed at glass fusion.
Dependences of the erbium photoluminescence intensity in Si:Er/Si structures have been studied in cases of homogeneous (over the sample surface) and inhomogeneous optical excitation. It is shown that the excitation mode strongly affects the type of the dependences obtained. A method for determining the excitation cross section of the Er ion under both continuous and pulsed optical pumping is discussed. The value obtained for the effective excitation cross section of erbium ions in silicon, σ = 5 × 10 −14 cm 2 at a temperature of 8 K, is an order of magnitude larger than the values known from published material.
Based on a detailed consideration of excitation mechanisms of erbium in crystalline and amorphous matrix we present an analysis of the physical meaning of the Auger excitation cross section of Er3+{\mathrm{Er}}^{3+}Er3+ ions in semiconductor. It is demonstrated that large values of Auger excitation cross sections under optical pumping in semiconductor matrices are due to large values of band-to-band absorption coefficient exceeding by several orders of magnitude the absorption coefficient of erbium in dielectric SiO2{\mathrm{SiO}}_{2}SiO2​ and Al2O3{\mathrm{Al}}_{2}{\mathrm{O}}_{3}Al2​O3​ matrix. The Auger excitation cross section of Er3+{\mathrm{Er}}^{3+}Er3+ in semiconductor matrices is roughly given by the ratio of the matrix absorption coefficient to concentration of Er3+{\mathrm{Er}}^{3+}Er3+ ions. While the analysis of the excitation cross section is carried out for Er-doped crystalline and amorphous silicon, the results are expected to be applicable to the other rare-earth doped semiconductors. Based on low-temperature experimental results for crystalline silicon we get the Auger excitation coefficient of ${c}_{A}^{\mathrm{cryst}}\ensuremath{\approx}7\ifmmode\times\else\texttimes\fi{}{10}^{\ensuremath{-}10} {\mathrm{cm}}^{3}{\mathrm{s}}^{\ensuremath{-}1}$ and the effective excitation cross section ${\ensuremath{\sigma}}_{\mathrm{eff}}^{\mathrm{cryst}}=(2\ensuremath{-}8)\ifmmode\times\else\texttimes\fi{}{10}^{\ensuremath{-}12} {\mathrm{cm}}^{2}.$ For amorphous silicon at 100 K we obtain ${\ensuremath{\sigma}}_{\mathrm{eff}}^{\mathrm{amorph}}\ensuremath{\approx}1.4\ifmmode\times\else\texttimes\fi{}{10}^{\ensuremath{-}14} {\mathrm{cm}}^{2}.$