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Joint Conference of the European Frequency and Time Forum and IEEE International Frequency Control Symposium (EFTF/IFCS)

CPT spectroscopy on low-temperature sealed MEMS rubidium vapour cells

C. Schori, Yves Pétremand, Frank Seigneur, Thomas Maeder, Herbert R. Shea, Nico F. de Rooij, G. Mileti, P. Thomann

Published Jan 1, 2009• 1 citation
OpenAlex

Abstract

In recent years there has been a strong effort to reduce the size and power consumption of vapour cell atomic clocks [1,2]. The progress in this direction is driven by several factors such as the use low power laser diodes (VCSEL), Coherent Population Trapping resonances (CPT), and micro-fabricated (MEMS) alkali-vapour cells. Here the micro-fabrication of vapour cells has proven a challenging task. All results reported on this task use anodic bonding at high-temperatures (>300°C) to seal the cell [3]. However, the low melting point and high vapour pressure of the alkali-metal combined with long bonding-times (>1hour) complicate this process. We have recently developed a low temperature (~150°C) sealing technique with fast process time (<1min) based on soldering [4]. We report here on the measurement of 85Rb σ+ CPT resonance in low temperature sealed MEMS-fabricated vapour cells containing natural rubidium and buffer gas. The resonance is recorded on the rubidium D1-line (795nm) using a circular polarized and current-modulated VCSEL. We record the resonance shift, linewidth and amplitude as function of several experimental parameters such as light intensity, cell-temperature, and buffer gas pressure- and mixture. In addition we perform noise measurements on the resonance signal to characterize the cell for clock-applications. Preliminary results show a contrast of 1.7% and linewidth of 900Hz for a 4mm long cell with 70mbar of nitrogen buffer gas. Finally we present and characterize two problems related to the application of 85Rb resonance in clock-applications. First, the low modulation frequency of the VCSEL (1.5GHz) leads to a strong asymmetry in the first order sideband spectrum due to the combined effect of AM- and FM modulation. Second, the buffer gas broadening of the absorption spectrum combined with the small separation between VCSEL carrier and sideband reduces the CPT contrast due to off-resonant absorption. We demonstrate that the impact of both these effects can be reduced by modulating the VCSEL at 3GHz and probing the CPT resonance with the carrier and first order sideband. We acknowledge support from the European Space Agency ESA (ESTEC contract number 20794/07/NL/GLC), the Conference Universitaire Suisse CUS (project CIMENT), the Swiss Space Office SSO, and SpectraTime SA (Neuchâtel, Switzerland).

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In recent years there has been a strong effort to reduce the size and power consumption of vapour cell atomic clocks [1,2]. The progress in this direction is driven by several factors such as the use low power laser diodes (VCSEL), Coherent Population Trapping resonances (CPT), and micro-fabricated (MEMS) alkali-vapour cells. Here the micro-fabrication of vapour cells has proven a challenging task. All results reported on this task use anodic bonding at high-temperatures (>300°C) to seal the cell [3]. However, the low melting point and high vapour pressure of the alkali-metal combined with long bonding-times (>1hour) complicate this process. We have recently developed a low temperature (~150°C) sealing technique with fast process time (<1min) based on soldering [4]. We report here on the measurement of 85Rb σ+ CPT resonance in low temperature sealed MEMS-fabricated vapour cells containing natural rubidium and buffer gas. The resonance is recorded on the rubidium D1-line (795nm) using a circular polarized and current-modulated VCSEL. We record the resonance shift, linewidth and amplitude as function of several experimental parameters such as light intensity, cell-temperature, and buffer gas pressure- and mixture. In addition we perform noise measurements on the resonance signal to characterize the cell for clock-applications. Preliminary results show a contrast of 1.7% and linewidth of 900Hz for a 4mm long cell with 70mbar of nitrogen buffer gas. Finally we present and characterize two problems related to the application of 85Rb resonance in clock-applications. First, the low modulation frequency of the VCSEL (1.5GHz) leads to a strong asymmetry in the first order sideband spectrum due to the combined effect of AM- and FM modulation. Second, the buffer gas broadening of the absorption spectrum combined with the small separation between VCSEL carrier and sideband reduces the CPT contrast due to off-resonant absorption. We demonstrate that the impact of both these effects can be reduced by modulating the VCSEL at 3GHz and probing the CPT resonance with the carrier and first order sideband. We acknowledge support from the European Space Agency ESA (ESTEC contract number 20794/07/NL/GLC), the Conference Universitaire Suisse CUS (project CIMENT), the Swiss Space Office SSO, and SpectraTime SA (Neuchâtel, Switzerland).
We describe the microfabrication of 85 Rb vapour cells using a glass-silicon anodic bonding technique and in situ chemical reaction between rubidium chloride and barium azide to produce Rb. Under controlled conditions, the pure metallic Rb drops and buffer gases were obtained in the cells with a few mm 3 internal volumes during the cell sealing process. At an ambient temperature of 90 °C the optical absorption resonance of 85 Rb D1 transition with proper broadening and the corresponding coherent population trapping (CPT) resonance, with a signal contrast of 1.5% and linewidth of about 1.7 kHz, have been detected. The sealing quality and the stability of the cells have also been demonstrated experimentally by using the helium leaking detection and the after-9-month optoelectronics measurement which shows a similar CPT signal as its original status. In addition, the physics package of chip-scale atomic clock (CSAC) based on the cell was realized. The measured frequency stability of the physics package can reach to 2.1 × 10 −10 at one second when the cell was heated to 100 °C which proved that the cell has the quality to be used in portable and battery-operated devices.
We report the characterization of dark line resonances observed in Cs vapor microcells filled with a unique neon (Ne) buffer gas. The impact on the coherent population trapping (CPT) resonance of some critical external parameters such as laser intensity, cell temperature, and microwave power is studied. We show the suppression of the first-order light shift by proper choice of the microwave power. The temperature dependence of the Cs ground state hyperfine resonance frequency is shown to be canceled in the 77–80 °C range for various Ne buffer gas pressures. The necessity to adjust the Ne buffer gas pressure or the cell dimensions to optimize the CPT signal height at the frequency inversion temperature is pointed out. Based on such Cs–Ne microcells, we preliminary demonstrate a 852 nm vertical cavity surface emitted laser (VCSEL)-modulated based CPT atomic clock exhibiting a short term fractional frequency instability σy(τ)=1.5×10−10τ−1/2 until 30 s. These results, similar to those published in the literature by others groups, prove the potential of our original microcell technology in view of the development of high-performance chip scale atomic clocks.
Nowadays, the portable atomic clocks with small size and low power consumption have attracted much attention. With the development of the coherent population trapping (CPT) and the micro-electro-mechanical systems (MEMS) technologies, it is possible to fabricate the miniature atomic clocks with power consumption less than 100mW. Researchers have already made great progress in the miniaturization of VCSELs, RF circuits, and photodiodes, which are the key technologies of the chip-scale atomic clock (CSAC). However, the fabrication of micro alkali atomic vapor cells is still to be improved. In this article, we describe the fabrication of micro Rb atomic vapor cells with inner dimensions of 3 mm length and 3 mm radius using anodic bonding and chemical reaction between BaN6and RbCl. The optical absorption and CPT resonances of the cells were measured slightly above the room temperature. In this condition, the consumption in the temperature control will be very low. Moreover, the long life (more than four years) of the cells makes it possible to use them in CSACs.
Controlling buffer-gas conditions in vapor cells is essential for frequency stabilization and atomic-clock performance. This study investigated the dependence of coherent population trapping (CPT) signal characteristics on nitrogen (N 2{}_{2}2​ ) buffer-gas pressure in micro-fabricated vapor cells containing natural-abundance rubidium (Rb) generated from Rb azide (RbN 3{}_{3}3​ ) for chip-scale atomic clocks. A wafer-level fabrication method enabling individual control of N2 pressure was developed by inkjet patterning of RbN3 and subsequent krypton fluoride (KrF) excimer laser decomposition. An increasing N2 pressure was found to reduce the CPT linewidth and cause a significant decrease in the signal amplitude, which resulted in monotonic degradation in the CPT figure of merit with higher pressures. A CPT-based laser frequency stabilization method that locked the laser wavelength to the CPT resonance peak yielded significantly larger signal amplitudes than a conventional absorption-based method in the low-pressure regime below 8 kPa. These results show that CPT performance in micro-fabricated Rb vapor cells is more restricted by the signal amplitude rather than the linewidth. They also offer practical buffer-gas design guidelines for enhancing short-term frequency stability in chip-scale atomic clocks.
We describe the fabrication of Rubidium (Rb) vapor cells using glass-silicon anodic bonding techniques and chemical reaction between rubidium chloride and barium azide. The pure metallic Rb drops and buffer gases were obtained in the cells with few mm3internal volumes. The optical absorption resonance of85Rb D1 transition with proper broadening and the corresponding coherent population trapping (CPT) resonance, with a signal contrast of 1.5% and linewidth of about 1.7 KHz, have been detected at 90degC.
We report the characterization of Coherent Population Trapping (CPT) resonances in Cs vapor microcells filled with Neon (Ne) buffer gas. The impact on the atomic hyperfine resonance of some external parameters such as laser intensity and cell temperature is studied. We show the suppression of the first-order light shift by proper choice of the microwave power. The temperature dependence of the Cs ground state hyperfine resonance frequency is shown to be canceled in the 77-80°C range for various Ne buffer gas pressures. We preliminary demonstrate a 852 nm VCSEL-modulated based CPT atomic clock exhibiting a short term fractional frequency instability σy(τ) = 1.5×10-10τ-1/2until 200 s.