Time-dependent N-Level Systems

J. Aliaga, J. L. Gruver, Araceli N. Proto

Phoenix M. M. Paing, Daniel F. V. James

We analyze the time-dependence of N-level systems under the Rotating Wave Approximation and dipole selection rules. Such systems can be solved straightforwardly if the Hamiltonian can be transformed into a time-independent form. The conditions under which a unitary transformation can be used to render time-dependent Hamiltonians into a time-independent form, thereby making the solution, are examined. After case-by-case analysis of different four and five-level systems, we conclude that systems having only one odd or even parity level achieve time-independence. In contrast, the others must satisfy a condition of laser detuning to achieve time-independence.

James P. Lavine

How does a driven system with many energy levels approach its steady state? Insights are gained by studying a system with three energy levels when the ground state is excited by a laser. The time-dependent occupation probabilities of the three energy levels show students how the system develops in time. The occupation probabilities come from the numerical solution of the Liouville-von Neumann equations for the density operator matrix elements when relaxation is included. A combination of the Interaction Picture, the Rotating Wave Approximation, and the assumption of resonance permit the eigenvalues of the Liouville-von Neumann equations to be found numerically and in closed-form in certain limits. The two methods are complementary and help students understand time-dependent systems. In addition, the eigenvalues allow the short-time and the long-time occupation probabilities to be connected to the relaxation parameters and the magnitude of the laser's electric field. Thus, this model three-level system illuminates how a driven system behaves over time and provides guidance for students studying time-dependent systems.

V. M. Akulin