Generalized Bloch equations for time-dependent N-level systems

Junichi Shinde, S. C. Mehrotra

Thomas E. Skinner

The Bloch equation and its variants constitute the fundamental dynamical model for arbitrary two-level systems. Many important processes, including those in more complicated systems, can be modeled and understood through the two-level approximation. It is therefore of widespread relevance, especially as it relates to understanding dissipative processes in current cutting-edge applications of quantum mechanics. Although the Bloch equation has been the subject of considerable analysis in the 70 years since its inception, there is still, perhaps surprisingly, significant work that can be done. This paper extends the scope of previous analyses. It provides a framework for more fully understanding the dynamics of dissipative two-level systems. A solution is derived that is compact, tractable, and completely general, in contrast to previous results. Any solution of the Bloch equation depends on three roots of a cubic polynomial that are crucial to the time dependence of the system. The roots are typically only sketched out qualitatively, with no indication of their dependence on the physical parameters of the problem. Degenerate roots, which modify the solutions, have been ignored altogether. Here the roots are obtained explicitly in terms of a single real-valued root that is expressed as a simple function of the system parameters. For the conventional Bloch equation, a simple graphical representation of this root is presented that makes evident the explicit time dependence of the system for each point in the parameter space. Several intuitive, visual models of system dynamics are developed. A Euclidean coordinate system is identified in which any generalized Bloch equation is separable, i.e., the sum of commuting rotation and relaxation operators. The time evolution in this frame is simply a rotation followed by relaxation at modified rates that play a role similar to the standard longitudinal and transverse rates. These rates are functions of the applied field, which provides information towards control of the dissipative process. The Bloch equation also describes a system of three coupled harmonic oscillators, providing additional perspective on dissipative systems.

Christopher Feuillade

Eitan Geva, Ronnie Kosloff, James L. Skinner

A detailed and unified account of the theory of the generalized Bloch equations is presented. The equations apply to a two-level system weakly coupled to a heat bath and subject to a monochromatic rotating field of arbitrary intensity. The relaxation tensor obtained is explicitly field-dependent. The derivation is valid for general coupling to a quantum heat bath. The generalized Bloch equations are shown to be thermodynamically consistent, as opposed to the standard Bloch equations. Different limits of the generalized Bloch equations are examined and related to previous studies. The potential use of the generalized Bloch equations as a probe of the bath spectral density is demonstrated for the case of a two-level system embedded in a Debye solid.

Gen Kimura

Duncan G. Steel

Abstract One of the most powerful tools for calculating quantum device performance is based on the density matrix operator. The operator is unique because it is time dependent in the Schrödinger picture. The approach is quite general, but in the systems of interest here, the Hilbert space of the operator includes both the quantum system such as a nano-vibrator or two-level system and the quantized vacuum radiation field. The equation of motion follows from the time dependent Schrödinger equation. It is possible, as we show, to include the generation of spontaneous emission in this system and then, because observables of interest do not depend on the vacuum field, trace over the vacuum field to create a new density matrix called the reduced density matrix. The resulting equations of motion are the Bloch equations. We use these equations to analyze several problems involving two- and three-level systems.