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Theoretical and experimental forbidden atomic transition probabilities

Roy H. Garstang

Published Jan 1, 1969• 4 citations
OpenAlex

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The magnetic field-induced giant modification of probabilities for seven components of 6S 1/2 , F g = 3 → 6P 3/2 , F e = 5 transition of the Cs D 2 line, forbidden by selection rules, is observed experimentally for the first time. For the case of excitation with circularly polarized laser radiation, the probability of a F g = 3, m F = −3 → F e = 5, m F = −2 transition becomes the largest of 25 transitions of the F g = 3 → F e = 2,3,4,5 group in a wide-range magnetic field of 200–3200 G. Moreover, the modification is the largest among D 2 lines of alkali metals. A half-wave-thick cell (the length along the beam propagation axis L = 426 nm) filled with Cs has been used in order to achieve sub-Doppler resolution, which allows the large number of atomic transitions that appear in the absorption spectrum to be separated when an external magnetic field is applied. For B > 3000 G the group of seven transitions F g = 3 → F e = 5 is completely resolved and is located at the high frequency level of F g = 3 → F e = 2,3,4 transitions. The applied theoretical model describes very well the experimental curves.

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Magnetically Induced Atomic Transitions of the Potassium D2 Line

Armen D. Sargsyan, Emmanuel Klinger, Claude Leroy +2 more

Abstract Magnetically induced (MI) transitions of the D2 line of 39K atom in an external magnetic field of 10–600 G have been experimentally and theoretically investigated for the first time using circularly polarized σ+ and σ− radiations. According to the selection rules, the transitions between the sublevels of the ground and excited levels of a hyperfine structure with Fe – Fg = ΔF = ±2 are forbidden in the zero magnetic field, whereas their probabilities increase radically in a magnetic field. For the Fg = 1 → Fe = 3 (ΔF = +2) and Fg = 2 → Fe = 0 MI transitions, the highest probabilities are achieved using the σ+ and σ– radiations, respectively. The atomic transitions have been spectrally resolved using selective reflection of laser radiation from a nanocell filled with potassium atomic vapor, which makes it possible to investigate the behavior of the MI transitions. The experimental and theoretical data are shown to be in good agreement.

Optics and Spectroscopy•Sep 1, 2019•7 citations
The magnetic field-induced giant modification of probabilities for seven components of 6S 1/2 , F g = 3 → 6P 3/2 , F e = 5 transition of the Cs D 2 line, forbidden by selection rules, is observed experimentally for the first time. For the case of excitation with circularly polarized laser radiation, the probability of a F g = 3, m F = −3 → F e = 5, m F = −2 transition becomes the largest of 25 transitions of the F g = 3 → F e = 2,3,4,5 group in a wide-range magnetic field of 200–3200 G. Moreover, the modification is the largest among D 2 lines of alkali metals. A half-wave-thick cell (the length along the beam propagation axis L = 426 nm) filled with Cs has been used in order to achieve sub-Doppler resolution, which allows the large number of atomic transitions that appear in the absorption spectrum to be separated when an external magnetic field is applied. For B > 3000 G the group of seven transitions F g = 3 → F e = 5 is completely resolved and is located at the high frequency level of F g = 3 → F e = 2,3,4 transitions. The applied theoretical model describes very well the experimental curves.
Abstract Magnetically induced (MI) transitions of the D2 line of 39K atom in an external magnetic field of 10–600 G have been experimentally and theoretically investigated for the first time using circularly polarized σ+ and σ− radiations. According to the selection rules, the transitions between the sublevels of the ground and excited levels of a hyperfine structure with Fe – Fg = ΔF = ±2 are forbidden in the zero magnetic field, whereas their probabilities increase radically in a magnetic field. For the Fg = 1 → Fe = 3 (ΔF = +2) and Fg = 2 → Fe = 0 MI transitions, the highest probabilities are achieved using the σ+ and σ– radiations, respectively. The atomic transitions have been spectrally resolved using selective reflection of laser radiation from a nanocell filled with potassium atomic vapor, which makes it possible to investigate the behavior of the MI transitions. The experimental and theoretical data are shown to be in good agreement.