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Advances in the Measurement of Atomic Transition Probabilities

Thomas R. O’Brian

Published Jan 1, 1991• 0 citations
OpenAlex

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Calculation of Transition Probabilities in Quantum Mechanics with a Nonnegative Distribution Function in the Maple Computer Algebra System

A. V. Zorin, N. P. Tretyakov

Abstract In the Maple computer algebra system, an algorithm is implemented for symbolic and numerical computations for finding the transition probabilities for hydrogen-like atoms in quantum mechanics with a nonnegative quantum distribution function (QDF). Quantum mechanics with a nonnegative QDF is equivalent to the standard theory of quantum measurements. However, the presence in it of a probabilistic quantum theory in the phase space gives additional possibilities for calculating and interpreting the results of quantum measurements. The methods of computer algebra seem to be necessary for the relevant calculations. The calculation of the matrix elements of operators is necessary for determining the energy levels, oscillator strengths, and radiation transition parameters for atoms and ions with an open shell. Transition probabilities are calculated and compared with experimental data. They are calculated using the Galerkin method with the Sturm functions of the hydrogen atom as coordinate functions. The verification of the model showed good agreement between the calculated and experimentally measured transition probabilities.

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The problem of defining quantum probabilities of composite events is considered. This problem is of great importance for the theory of quantum measurements and for quantum decision theory, which is a part of measurement theory. We show that the Lüders probability of consecutive measurements is a transition probability between two quantum states and that this probability cannot be treated as a quantum extension of the classical conditional probability. The Wigner distribution is shown to be a weighted transition probability that cannot be accepted as a quantum extension of the classical joint probability. We suggest the definition of quantum joint probabilities by introducing composite events in multichannel measurements. The notion of measurements under uncertainty is defined. We demonstrate that the necessary condition for mode interference is the entanglement of the composite prospect together with the entanglement of the composite statistical state. As an illustration, we consider an example of a quantum game. Special attention is paid to the application of the approach to systems with multimode states, such as atoms, molecules, quantum dots, or trapped Bose-condensed atoms with several coherent modes.

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Is a multiple excitation of a single atom equivalent to a single excitation of an ensemble of atoms?

I Kanter, A. Frydman, A Ater

Recent technological advances have enabled to isolate, control and measure the properties of a single atom, leading to the possibility to perform statistics on the behavior of single quantum systems. These experiments have enabled to check a question which was out of reach previously: Is the statistics of a multiple excitation of an atom N times equivalent to a single excitation of an ensemble of N atoms? We present a new method to analyze quantum measurements which leads to the conclusion that the answer is most probably no. We discuss the merits of the analysis and its conclusion.

arXiv:physics/0405081•Europhysics Letters (EPL)•Feb 17, 2005•2 citations
Abstract In the Maple computer algebra system, an algorithm is implemented for symbolic and numerical computations for finding the transition probabilities for hydrogen-like atoms in quantum mechanics with a nonnegative quantum distribution function (QDF). Quantum mechanics with a nonnegative QDF is equivalent to the standard theory of quantum measurements. However, the presence in it of a probabilistic quantum theory in the phase space gives additional possibilities for calculating and interpreting the results of quantum measurements. The methods of computer algebra seem to be necessary for the relevant calculations. The calculation of the matrix elements of operators is necessary for determining the energy levels, oscillator strengths, and radiation transition parameters for atoms and ions with an open shell. Transition probabilities are calculated and compared with experimental data. They are calculated using the Galerkin method with the Sturm functions of the hydrogen atom as coordinate functions. The verification of the model showed good agreement between the calculated and experimentally measured transition probabilities.
The problem of defining quantum probabilities of composite events is considered. This problem is of great importance for the theory of quantum measurements and for quantum decision theory, which is a part of measurement theory. We show that the Lüders probability of consecutive measurements is a transition probability between two quantum states and that this probability cannot be treated as a quantum extension of the classical conditional probability. The Wigner distribution is shown to be a weighted transition probability that cannot be accepted as a quantum extension of the classical joint probability. We suggest the definition of quantum joint probabilities by introducing composite events in multichannel measurements. The notion of measurements under uncertainty is defined. We demonstrate that the necessary condition for mode interference is the entanglement of the composite prospect together with the entanglement of the composite statistical state. As an illustration, we consider an example of a quantum game. Special attention is paid to the application of the approach to systems with multimode states, such as atoms, molecules, quantum dots, or trapped Bose-condensed atoms with several coherent modes.
Recent technological advances have enabled to isolate, control and measure the properties of a single atom, leading to the possibility to perform statistics on the behavior of single quantum systems. These experiments have enabled to check a question which was out of reach previously: Is the statistics of a multiple excitation of an atom N times equivalent to a single excitation of an ensemble of N atoms? We present a new method to analyze quantum measurements which leads to the conclusion that the answer is most probably no. We discuss the merits of the analysis and its conclusion.