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arXiv:2608.28904

Spin-spin effects from non-relativistic limit of Dirac-Pauli-Maxwell Lagrangian

Radmehr Fathi, Nima Khosravi

quant-phcond-mat.str-elhep-thSubmitted Aug 28, 2026• Announced Sep 1, 2026• 0 citations
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Abstract

It is natural to expect that the electromagnetic spin-spin interaction has roots in a more fundamental theory: quantum electrodynamics in this case. To show this, we take the non-relativistic limit of the Dirac-Maxwell Lagrangian, using the Foldy-Wouthuysen transformation and derive the Breit interaction by an alternative approach. By adding the Pauli term (i.e., a higher-order interaction between spin and the electromagnetic field), we calculate the correction terms to electromagnetic spin-spin interactions in the non-relativistic limit. Finally, we study some of the physical effects of these terms regarding spin-spin interactions and spin-spin entanglements. Accordingly, we provide theoretical estimates that are not yet accessible with current experiments.

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12 pages

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It is natural to expect that the electromagnetic spin-spin interaction has roots in a more fundamental theory: quantum electrodynamics in this case. To show this, we take the non-relativistic limit of the Dirac-Maxwell Lagrangian, using the Foldy-Wouthuysen transformation and derive the Breit interaction by an alternative approach. By adding the Pauli term (i.e., a higher-order interaction between spin and the electromagnetic field), we calculate the correction terms to electromagnetic spin-spin interactions in the non-relativistic limit. Finally, we study some of the physical effects of these terms regarding spin-spin interactions and spin-spin entanglements. Accordingly, we provide theoretical estimates that are not yet accessible with current experiments.
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It has long been speculated that the Dirac or, more generally, the Dirac-Pauli spinor in the Foldy-Wouthuysen (FW) representation should behave like a classical relativistic spinor in the low-energy limit when the probability of particle-antiparticle pair creation and annihilation is negligible. In the weak-field limit of static and homogeneous electromagnetic fields, by applying the method of direct perturbation theory inductively on the orders of 1/c1/c1/c in the power series, we rigorously prove that it is indeed the case: the FW transformation of the Dirac-Pauli Hamiltonian is in full agreement with the classical counterpart, which is the sum of the orbital Hamiltonian for the Lorentz force equation and the spin Hamiltonian for the Thomas-Bargmann-Michel-Telegdi equation.
We investigate the spin of the electron in a non-relativistic context by using the Galilean covariant Pauli-Dirac equation. From a non-relativistic Lagrangian density, we find an appropriate Dirac-like Hamiltonian in the momentum representation, which includes the spin operator in the Galilean covariant framework. Within this formalism, we show that the total angular momentum appears as a constant of motion. Additionally, we propose a non-minimal coupling that describes the Galilean interaction between an electron and the electromagnetic field. Thereby, we obtain, in a natural way, the Hamiltonian including all the essential interaction terms for the electron in a general vector field.
The classical dynamics for a charged spin particle is governed by the Lorentz force equation for orbital motion and by the Thomas-Bargmann-Michel-Telegdi (T-BMT) equation for spin precession. In static and homogeneous electromagnetic fields, it has been shown that the Foldy-Wouthuysen (FW) transform of the Dirac-Pauli Hamiltonian, which describes the relativistic quantum theory for a spin-1/21/21/2 particle, is consistent with the classical Hamiltonian (with both the orbital and spin parts) up to the order of 1/m141/{m}^{14}1/m14 (mmm is the particle's mass) in the low-energy and weak-field limit. In this paper, we extend this correspondence to the case of inhomogeneous fields. Regardless of the field gradient (e.g. Stern-Gerlach) force, the T-BMT equation is unaltered and thus the classical Hamiltonian remains the same, but subtleties arise and need to be clarified. For the relativistic quantum theory, we apply Eriksen's method to obtain the exact FW transformations for the two special cases, which in conjunction strongly suggest that, in the weak-field limit, the FW transformed Dirac-Pauli Hamiltonian (except for the Darwin term) is in agreement with the classical Hamiltonian in a manner that classical variables correspond to quantum operators via a specific Weyl ordering. Meanwhile, the Darwin term is shown to have no classical correspondence.
By a canonical transformation on the Dirac Hamiltonian for a free particle, a representation of the Dirac theory is obtained in which positive and negative energy states are separately represented by two-component wave functions. Playing an important role in the new representation are new operators for position and spin of the particle which are physically distinct from these operators in the conventional representation. The components of the time derivative of the new position operator all commute and have for eigenvalues all values between $\ensuremath{-}c$ and ccc. The new spin operator is a constant of the motion unlike the spin operator in the conventional representation. By a comparison of the new Hamiltonian with the non-relativistic Pauli-Hamiltonian for particles of spin \textonehalf{}, one finds that it is these new operators rather than the conventional ones which pass over into the position and spin operators in the Pauli theory in the non-relativistic limit. The transformation of the new representation is also made in the case of interaction of the particle with an external electromagnetic field. In this way the proper non-relativistic Hamiltonian (essentially the Pauli-Hamiltonian) is obtained in the non-relativistic limit. The same methods may be applied to a Dirac particle interacting with any type of external field (various meson fields, for example) and this allows one to find the proper non-relativistic Hamiltonian in each such case. Some light is cast on the question of why a Dirac electron shows some properties characteristic of a particle of finite extension by an examination of the relationship between the new and the conventional position operators.