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Journal of Physics A Mathematical and Theoretical

A spin Hamiltonian for non-relativistic electrons and their interaction with an external field

E. S. Santos, Roberto Rivelino, M. de Montigny, G R de Melo

Published Jul 16, 2010• 4 citations
Publisher

Abstract

We investigate the spin of the electron in a non-relativistic context by using the Galilean covariant Pauli-Dirac equation. From a non-relativistic Lagrangian density, we find an appropriate Dirac-like Hamiltonian in the momentum representation, which includes the spin operator in the Galilean covariant framework. Within this formalism, we show that the total angular momentum appears as a constant of motion. Additionally, we propose a non-minimal coupling that describes the Galilean interaction between an electron and the electromagnetic field. Thereby, we obtain, in a natural way, the Hamiltonian including all the essential interaction terms for the electron in a general vector field.

DOI
10.1088/1751-8113/43/33/335304

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We investigate the spin of the electron in a non-relativistic context by using the Galilean covariant Pauli-Dirac equation. From a non-relativistic Lagrangian density, we find an appropriate Dirac-like Hamiltonian in the momentum representation, which includes the spin operator in the Galilean covariant framework. Within this formalism, we show that the total angular momentum appears as a constant of motion. Additionally, we propose a non-minimal coupling that describes the Galilean interaction between an electron and the electromagnetic field. Thereby, we obtain, in a natural way, the Hamiltonian including all the essential interaction terms for the electron in a general vector field.
By a canonical transformation on the Dirac Hamiltonian for a free particle, a representation of the Dirac theory is obtained in which positive and negative energy states are separately represented by two-component wave functions. Playing an important role in the new representation are new operators for position and spin of the particle which are physically distinct from these operators in the conventional representation. The components of the time derivative of the new position operator all commute and have for eigenvalues all values between $\ensuremath{-}c$ and ccc. The new spin operator is a constant of the motion unlike the spin operator in the conventional representation. By a comparison of the new Hamiltonian with the non-relativistic Pauli-Hamiltonian for particles of spin \textonehalf{}, one finds that it is these new operators rather than the conventional ones which pass over into the position and spin operators in the Pauli theory in the non-relativistic limit. The transformation of the new representation is also made in the case of interaction of the particle with an external electromagnetic field. In this way the proper non-relativistic Hamiltonian (essentially the Pauli-Hamiltonian) is obtained in the non-relativistic limit. The same methods may be applied to a Dirac particle interacting with any type of external field (various meson fields, for example) and this allows one to find the proper non-relativistic Hamiltonian in each such case. Some light is cast on the question of why a Dirac electron shows some properties characteristic of a particle of finite extension by an examination of the relationship between the new and the conventional position operators.
The external electromagnetic interactions of hydrogenic atoms, which exhibit global Galilean invariance but preserve the relativistic description of the electron, are investigated. The Hamiltonian for the free atom consists of the Breit Hamiltonian for a relativistic electron interacting with a nonrelativistic spinless proton. Approximate generators of the Galilean group are constructed in terms of individual-particle position, momentum, and spin operators in several unitarily equivalent representations. In one of these the Hamiltonian is separable in conventional relative and center-of-mass coordinates. This separability facilitates the treatment of a number of external-field problems. An effective Hamiltonian for the interaction of the atom with a constant external electric field is given and compared to that obtained by other authors. The low-energy theorem for Compton scattering from the composite system is explicitly verified including corrections due to atomic binding. This also gives an independent verification of recently obtained bound-state corrections to the atomic magnetic moment. Finally, an effective interaction of a charged Dirac particle with a hydrogenic atom is given in the representation in which the atomic Hamiltonian is separable.
A relativistic spin operator cannot be uniquely defined within relativistic quantum mechanics. Previously, different proper relativistic spin operators have been proposed, such as spin operators of the Foldy-Wouthuysen and Pryce type, that both commute with the free-particle Dirac Hamiltonian and represent constants of motion. Here we consider the dynamics of a relativistic electron spin in an external electromagnetic field. We use two different Hamiltonians to derive the corresponding spin dynamics. These two are: (a) the Dirac Hamiltonian in the presence of an external field, and (b) the semirelativistic expansion of the same. Considering the Foldy-Wouthuysen and Pryce spin operators we show that these lead to different spin dynamics in an external electromagnetic field, which offers possibilities to distinguish their action. We find that the dynamics of both spin operators involve spin-dependent and spin-independent terms, however, the Foldy-Wouthuysen spin dynamics additionally accounts for the relativistic particle-antiparticle coupling. We conclude that the Pryce spin operator provides a suitable description of the relativistic spin dynamics in a weak-to-intermediate external field, whereas the Foldy-Wouthuysen spin operator is more suitable in the strong field regime.
A relativistically invariant representation of the generalized momentum of a particle in an external field is proposed. In this representation, the dependence of the potentials of the interaction of the particle with the field on the particle velocity is taken into account. The exact correspondence of the expressions of energy and potential energy for the classical Hamiltonian is established, which makes identical the solutions to the problems of mechanics with relativistic and nonrelativistic approaches. The invariance of the proposed representation of the generalized momentum makes it possible to equivalently describe a physical system in geometrically conjugate spaces of kinematic and dynamic variables. Relativistic invariant equations are proposed for the action function and the wave function based on the invariance of the representation of the generalized momentum. The equations have solutions for any values of the constant interaction of the particle with the field, for example, in the problem of a hydrogen-like atom, when the atomic number of the nucleus is Z > 137. Based on the parametric representation of the action, the expression for the canonical Lagrangian, the equations of motion, and the expression for the force acting on the charge are derived when moving in an external electromagnetic field. The Dirac equation with the correct inclusion of the interaction for a particle in an external field is presented. In this form, the solutions of the equations are not limited by the value of the interaction constant. The solutions of the problem of charge motion in a constant electric field, the problems for a particle in a potential well and the passage of a particle through a potential barrier, the problems of motion in an exponential field (Morse), and also the problems of a hydrogen atom are given.
Physical processes are usually described using four-dimensional vector quantities - coordinate vector, momentum vector, current vector. But at the fundamental level they are characterized by spinors - coordinate spinors, momentum spinors, spinor wave functions. The propagation of fields and their interaction takes place at the spinor level, and since each spinor uniquely corresponds to a certain vector, the results of physical processes appear before us in vector form. For example, the relativistic Schrödinger equation and the Dirac equation are formulated by means of coordinate vectors, momentum vectors and quantum operators corresponding to them. In the Dirac equation a step forward is taken and the wave function is a spinor with complex components, but still coordinates and momentum are vectors. For a closed description of nature using only spinor quantities, it is necessary to have an equation similar to the Dirac equation in which momentum, coordinates and operators are spinors. It is such an equation that is presented in this paper. Using the example of the interaction between an electron and an electromagnetic field, we can see that the spinor equation contains more detailed information about the interaction than the vector equations. This is not new for quantum mechanics, since it describes interactions using complex wave functions, which cannot be observed directly, and only when measured goes to probabilities in the form of squares of the moduli of the wave functions. In the same way spinor quantities are not observable, but they completely determine observable vectors. In Section 2 of the paper, we analyze the quadratic form for an arbitrary four-component complex vector based on Pauli matrices. The form is invariant with respect to Lorentz transformations including any rotations and boosts. The invariance of the form allows us to construct on its basis an equation for a free particle combining the properties of the relativistic wave equation and the Dirac equation. For an electron in the presence of an electromagnetic potential it is shown that taking into account the commutation relations between the momentum and coordinate components allows us to obtain from this equation the known results describing the interactions of the electron spin with the electric and magnetic field. In the presence of a potential the momentum components cease to commute with each other. To neutralize this effect, the Schrödinger equation is supplemented by several equations with mixed derivatives on coordinates. In section 3 of the paper this quadratic form is expressed through momentum spinors, which makes it possible to obtain an equation for the spinor wave function in spinor coordinate space by replacing the momentum spinor components by partial derivative operators on the corresponding coordinate spinor component. Section 4 presents a modification of the theory of the path integral, which consists in considering the path integral in the spinor coordinate space. The Lagrangian densities for the scalar field and for the electron field, along with their corresponding propagators, are presented. An equation of motion for the electron is proposed that is relativistically invariant, in contrast to the Dirac equation, which lacks this invariance. This novel equation permitted the construction of an actually invariant procedure for the second quantization of the fermion field in spinor coordinate space. Furthermore, it is demonstrated that the field operators are a combination of plane waves in spinor or vector space, with the coefficients of which being pseudospinors or pseudovectors. Each of these pseudovectors or pseudospinors corresponds to one of the particles presented in the theory of electrodynamics. Furthermore, each plane wave possesses an additional coefficient in the form of a birth or annihilation operator. In vector space, these operators commute, whereas in spinor space they anticommutate. The paper presents the spinor and vector representations of the field operators in explicit form, comprising sets of 16 pseudospinors or 4 pseudovectors corresponding to particles represented in electrodynamics.
Physical processes are usually described using four-dimensional vector quantities - coordinate vector, momentum vector, current vector. But at the fundamental level they are characterized by spinors - coordinate spinors, momentum spinors, spinor wave functions. The propagation of fields and their interaction takes place at the spinor level, and since each spinor uniquely corresponds to a certain vector, the results of physical processes appear before us in vector form. For example, the relativistic Schrödinger equation and the Dirac equation are formulated by means of coordinate vectors, momentum vectors and quantum operators corresponding to them. In the Dirac equation a step forward is taken and the wave function is a spinor with complex components, but still coordinates and momentum are vectors. For a closed description of nature using only spinor quantities, it is necessary to have an equation similar to the Dirac equation in which momentum, coordinates and operators are spinors. It is such an equation that is presented in this paper. Using the example of the interaction between an electron and an electromagnetic field, we can see that the spinor equation contains more detailed information about the interaction than the vector equations. This is not new for quantum mechanics, since it describes interactions using complex wave functions, which cannot be observed directly, and only when measured goes to probabilities in the form of squares of the moduli of the wave functions. In the same way spinor quantities are not observable, but they completely determine observable vectors.In Section 2 of the paper, we analyze the quadratic form for an arbitrary four-component complex vector based on Pauli matrices. The form is invariant with respect to Lorentz transformations including any rotations and boosts. The invariance of the form allows us to construct on its basis an equation for a free particle combining the properties of the relativistic wave equation and the Dirac equation. For an electron in the presence of an electromagnetic potential it is shown that taking into account the commutation relations between the momentum and coordinate components allows us to obtain from this equation the known results describing the interactions of the electron spin with the electric and magnetic field. In the presence of a potential the momentum components cease to commute with each other. To neutralize this effect, the Schrödinger equation is supplemented by several equations with mixed derivatives on coordinates. In section 3 of the paper this quadratic form is expressed through momentum spinors, which makes it possible to obtain an equation for the spinor wave function in spinor coordinate space by replacing the momentum spinor components by partial derivative operators on the corresponding coordinate spinor component. Section 4 presents a modification of the theory of the path integral, which consists in considering the path integral in the spinor coordinate space. The Lagrangian densities for the scalar field and for the electron field, along with their corresponding propagators, are presented. An equation of motion for the electron is proposed that is relativistically invariant, in contrast to the Dirac equation, which lacks this invariance. This novel equation permitted the construction of an actually invariant procedure for the second quantization of the fermion field in spinor coordinate space. Furthermore, it is demonstrated that the field operators are a combination of plane waves in spinor or vector space, with the coefficients of which being pseudospinors or pseudovectors. Each of these pseudovectors or pseudospinors corresponds to one of the particles presented in the theory of electrodynamics. Furthermore, each plane wave possesses an additional coefficient in the form of a creation or annihilation operator. In vector space, these operators commute, whereas in spinor space they anticommutate. The paper presents the spinor and vector representations of the field operators in explicit form, comprising sets of 16 pseudospinors or 4 pseudovectors corresponding to particles represented in electrodynamics. An explicit form of the symmetric traceless tensor with spin two, zero mass and two polarizations is presented, which can serve as a model of the graviton. The results obtained may prompt changes in some aspects of the construction of Feynman diagrams.