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arXiv:2003.02226 · Journal of Physics Condensed Matter

Dynamics of the relativistic electron spin in an electromagnetic field

Ritwik Mondal, Peter M. Oppeneer

Published Jul 15, 2020• 10 citations

Abstract

A relativistic spin operator cannot be uniquely defined within relativistic quantum mechanics. Previously, different proper relativistic spin operators have been proposed, such as spin operators of the Foldy-Wouthuysen and Pryce type, that both commute with the free-particle Dirac Hamiltonian and represent constants of motion. Here we consider the dynamics of a relativistic electron spin in an external electromagnetic field. We use two different Hamiltonians to derive the corresponding spin dynamics. These two are: (a) the Dirac Hamiltonian in the presence of an external field, and (b) the semirelativistic expansion of the same. Considering the Foldy-Wouthuysen and Pryce spin operators we show that these lead to different spin dynamics in an external electromagnetic field, which offers possibilities to distinguish their action. We find that the dynamics of both spin operators involve spin-dependent and spin-independent terms, however, the Foldy-Wouthuysen spin dynamics additionally accounts for the relativistic particle-antiparticle coupling. We conclude that the Pryce spin operator provides a suitable description of the relativistic spin dynamics in a weak-to-intermediate external field, whereas the Foldy-Wouthuysen spin operator is more suitable in the strong field regime.

DOI: 10.1088/1361-648x/aba675

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A relativistic spin operator cannot be uniquely defined within relativistic quantum mechanics. Previously, different proper relativistic spin operators have been proposed, such as spin operators of the Foldy-Wouthuysen and Pryce type, that both commute with the free-particle Dirac Hamiltonian and represent constants of motion. Here we consider the dynamics of a relativistic electron spin in an external electromagnetic field. We use two different Hamiltonians to derive the corresponding spin dynamics. These two are: (a) the Dirac Hamiltonian in the presence of an external field, and (b) the semirelativistic expansion of the same. Considering the Foldy-Wouthuysen and Pryce spin operators we show that these lead to different spin dynamics in an external electromagnetic field, which offers possibilities to distinguish their action. We find that the dynamics of both spin operators involve spin-dependent and spin-independent terms, however, the Foldy-Wouthuysen spin dynamics additionally accounts for the relativistic particle-antiparticle coupling. We conclude that the Pryce spin operator provides a suitable description of the relativistic spin dynamics in a weak-to-intermediate external field, whereas the Foldy-Wouthuysen spin operator is more suitable in the strong field regime.

Different operators have been suggested in the literature to describe the electron's spin degree of freedom within the relativistic Dirac theory. We compare concrete predictions of the various proposed relativistic spin operators in different physical situations. In particular, we investigate the so-called Pauli, Foldy-Wouthuysen, Czachor, Frenkel, Chakrabarti, Pryce, and Fradkin-Good spin operators. We demonstrate that when a quantum system interacts with electromagnetic potentials the various spin operators predict different expectation values. This is explicitly illustrated for the scattering dynamics at a potential step and in a standing laser field and also for energy eigenstates of hydrogenic ions. Therefore, one may distinguish between the proposed relativistic spin operators experimentally.

Although the spin is regarded as a fundamental property of the electron, there is no universally accepted spin operator within the framework of relativistic quantum mechanics. We investigate the properties of different proposals for a relativistic spin operator. It is shown that most candidates are lacking essential features of proper angular momentum operators, leading to spurious zitterbewegung (quivering motion) or violation of the angular momentum algebra. Only the Foldy–Wouthuysen operator and the Pryce operator qualify as proper relativistic spin operators. We demonstrate that ground states of highly charged hydrogen-like ions can be utilized to identify a legitimate relativistic spin operator experimentally.

The classical dynamics for a charged spin particle is governed by the Lorentz force equation for orbital motion and by the Thomas-Bargmann-Michel-Telegdi (T-BMT) equation for spin precession. In static and homogeneous electromagnetic fields, it has been shown that the Foldy-Wouthuysen (FW) transform of the Dirac-Pauli Hamiltonian, which describes the relativistic quantum theory for a spin-

1/2

particle, is consistent with the classical Hamiltonian (with both the orbital and spin parts) up to the order of

1/{m}^{14}

(

m

is the particle's mass) in the low-energy and weak-field limit. In this paper, we extend this correspondence to the case of inhomogeneous fields. Regardless of the field gradient (e.g. Stern-Gerlach) force, the T-BMT equation is unaltered and thus the classical Hamiltonian remains the same, but subtleties arise and need to be clarified. For the relativistic quantum theory, we apply Eriksen's method to obtain the exact FW transformations for the two special cases, which in conjunction strongly suggest that, in the weak-field limit, the FW transformed Dirac-Pauli Hamiltonian (except for the Darwin term) is in agreement with the classical Hamiltonian in a manner that classical variables correspond to quantum operators via a specific Weyl ordering. Meanwhile, the Darwin term is shown to have no classical correspondence.

The time evolution of the density corresponding to the polarization operator, originally constructed to commute with the Dirac Hamiltonian in the absence of an external electromagnetic field, is investigated in terms of the time-dependent Dirac equation taking the presence of an external electromagnetic field into account. It is found that this time evolution leads to ‘tensorial’ and ‘vectorial’ particle current densities and to the interaction of the spin density with the external electromagnetic field. As the time evolution of the spin density does not refer to a constant of motion (continuity condition) it only serves as auxiliary density. By taking the non-relativistic limit, it is shown that the polarization, spin and magnetization densities are independent of electric field effects and, in addition, no preferred directions can be defined.