We investigate how finite quantum systems with strong long-range interactions approach thermal equilibrium. Nearly conserved quantities inherited from the fully connected limit fragment the Hilbert space and give rise to a many-body spectrum split into energy bands. As a result, equilibration becomes anomalously slow and proceeds through long-lived prethermal plateaus. This two-stage equilibration process is, however, not universal. We uncover the mechanism that determines which observables and initial states exhibit, or evade, prethermal plateaus. We also develop a perturbative theory that provides analytical expressions for both the height of the prethermal plateau and its timescale. Despite the lack of global ergodicity, quantum chaos develops within individual energy bands, enabling the definition of microcanonical ensembles within the bands. This supports a band-resolved formulation of thermalization, which we term fragmented eigenstate thermalization hypothesis (fETH). Unlike conventional ETH, finite-size scaling in fETH obeys a symmetry-imposed selection rule that restricts which system sizes can be compared. This band-resolved description has direct consequences for equilibrium statistical mechanics. While microcanonical ensembles remain confined to a single band, canonical ensembles mix different bands. This mismatch explains ensemble inequivalence without invoking equilibrium phase transitions. Our results apply to a broad class of Hamiltonians exhibiting Hilbert-space fragmentation.
We investigate how finite quantum systems with strong long-range interactions approach thermal equilibrium. Nearly conserved quantities inherited from the fully connected limit fragment the Hilbert space and give rise to a many-body spectrum split into energy bands. As a result, equilibration becomes anomalously slow and proceeds through long-lived prethermal plateaus. This two-stage equilibration process is, however, not universal. We uncover the mechanism that determines which observables and initial states exhibit, or evade, prethermal plateaus. We also develop a perturbative theory that provides analytical expressions for both the height of the prethermal plateau and its timescale. Despite the lack of global ergodicity, quantum chaos develops within individual energy bands, enabling the definition of microcanonical ensembles within the bands. This supports a band-resolved formulation of thermalization, which we term fragmented eigenstate thermalization hypothesis (fETH). Unlike conventional ETH, finite-size scaling in fETH obeys a symmetry-imposed selection rule that restricts which system sizes can be compared. This band-resolved description has direct consequences for equilibrium statistical mechanics. While microcanonical ensembles remain confined to a single band, canonical ensembles mix different bands. This mismatch explains ensemble inequivalence without invoking equilibrium phase transitions. Our results apply to a broad class of Hamiltonians exhibiting Hilbert-space fragmentation.
Understanding the stability of integrability in many-body quantum systems is key to controlling dynamics and predicting thermalization. While the breakdown of integrability in short-range interacting systems is well understood, the role of long-range couplings -- ubiquitous and experimentally realizable -- remains unclear. We show that in fully connected models, integrability is either robust or extremely fragile, depending on whether perturbations are non-extensive, extensive one-body, or extensive two-body. In contrast to finite short-range systems, where any of these perturbations can induce chaos at finite strength, in fully connected finite models, chaos is triggered by extensive two-body perturbations and even at infinitesimal strength. Chaos develops within energy bands defined by symmetries, leading to a fragmented realization of the eigenstate thermalization hypothesis and clarifying how microcanonical shells can be constructed in such systems. We also introduce a general symmetry-based framework that explains the stability of integrability.
A plausible mechanism of thermalization in isolated quantum systems is based on the strong version of the eigenstate thermalization hypothesis (ETH), which states that all the energy eigenstates in the microcanonical energy shell have thermal properties. We numerically investigate the ETH by focusing on the large deviation property, which directly evaluates the ratio of athermal energy eigenstates in the energy shell. As a consequence, we have systematically confirmed that the strong ETH is indeed true even for near-integrable systems. Furthermore, we found that the finite-size scaling of the ratio of athermal eigenstates is a double exponential for nonintegrable systems. Our result illuminates the universal behavior of quantum chaos, and suggests that a large deviation analysis would serve as a powerful method to investigate thermalization in the presence of the large finite-size effect.
Despite the unitary evolution of closed quantum systems, long-time expectation of local observables are well described by thermal ensembles, providing the foundation of quantum statistical mechanics. A promising route to understanding this quantum thermalization is the eigenstate thermalization hypothesis (ETH), which posits that individual energy eigenstates already appear locally thermal. Subsequent studies have extended this concept to the full ETH, which captures higher-order correlations among matrix elements through nontrivial relations. In this work, we perform a detailed exact-diagonalization study of finite-size corrections to these relations in the canonical ensemble. We distinguish two distinct sources of corrections: those arising from energy fluctuations, which decay polynomially with system size, and those originating from fluctuations within each energy window, which decay exponentially with system size. In particular, our analysis resolves the puzzle that, for certain observables, finite-size corrections exhibit anomalous growth with increasing system size even in chaotic systems. Our results provide a systematic and practical methodology for validating the full ETH in quantum many-body systems.
Eigenstate thermalization hypothesis (ETH) represents a breakthrough in many-body physics since it allows us to link thermalization of physical observables with the applicability of random matrix theory (RMT). Recent years were also extremely fruitful in exploring possible counterexamples to thermalization, ranging, among others, from integrability, single-particle chaos, many-body localization, many-body scars, to Hilbert-space fragmentation. In all these cases the conventional ETH is violated. However, it remains elusive how the conventional ETH breaks down when one approaches the boundaries of ergodicity, and whether the range of validity of the conventional ETH coincides with the validity of RMT-like spectral statistics. Here we bridge this gap and we introduce a scenario of the ETH breakdown in many-body quantum systems, dubbed fading ergodicity regime, which establishes a link between the conventional ETH and nonergodic behavior. We conjecture this scenario to be relevant for the description of finite many-body systems at the boundaries of ergodicity, and we provide numerical and analytical arguments for its validity in the quantum sun model of ergodicity-breaking phase transition. For the latter, we provide evidence that the breakdown of the conventional ETH is not associated with the breakdown of the RMT-like spectral statistics. Published by the American Physical Society 2024
A very fundamental problem in quantum statistical mechanics involves whether—and how—an isolated quantum system will reach thermal equilibrium after waiting a long time. In quantum systems that do thermalize, the long-time expectation value of any “reasonable” operator will match its predicted value in the canonical ensemble. The Eigenstate Thermalization Hypothesis (ETH) posits that this thermalization occurs at the level of each individual energy eigenstate; in fact, any single eigenstate in a microcanonical energy window will predict the expectation values of such operators exactly. In the first part of this dissertation, we identify, for a generic model system, precisely which operators satisfy ETH, as well as limits to the information contained in a single eigenstate. Remarkably, our results strongly suggest that a single eigenstate can contain information about energy densities—and therefore temperatures—far away from the energy density of the eigenstate.Additionally, we study the possible breakdown of quantum thermalization in a model of itinerant electrons on a one-dimensional chain, with both spin and charge degrees of freedom. This model exhibits peculiar properties in the entanglement entropy, the apparent scaling of which is modified from a “volume law” to an “area law” after performing a partial, site-wise measurement on the system. These properties and others suggest that this model realizes a new, non-thermal phase of matter, known as a Quantum Disentangled Liquid (QDL). The putative existence of this phase has striking implications for the foundations of quantum statistical mechanics.
The typical mechanisms of ergodicity breaking in isolated interacting quantum systems, such as many-body localization and quantum many-body scars, originate from the nonthermal nature of the underlying eigenstates. Here, in the absence of nonthermal eigenstates, we identify a mechanism for collective revivals of multiparticle Wannier states (MWSs) associated with nearly linear bands in a spatially modulated Bose-Hubbard lattice. The MWSs, as superpositions of multiparticle Bloch states within individual energy bands, give rise to band-resolved Wannier-sector fragmentation. The key idea is that spatially periodic modulation folds and separates energy bands of a simple lattice into several sub-bands, among which nearly linear sub-bands inherit the linear segments of the original bands. Although multiparticle Bloch states satisfy the eigenstate thermalization hypothesis (ETH), the MWSs in the nearly linear band still exhibit long-lived collective revivals, due to emergent equally spaced energy levels. Our work provides a route to weak ergodicity breaking in which long-lived revivals arise from spectral phase coherence among ETH-satisfying eigenstates rather than from scar-like nonthermal eigenstates.