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arXiv:2606.30762

Athermality of generalized Gibbs ensembles

Riccardo Senese, Bruno Bertini, Katja Klobas, Pasquale Calabrese

cond-mat.stat-mechquant-phSubmitted Jun 29, 2026• Announced Jul 1, 2026• 0 citations
v1 · Jun 29, 2026v2 · Jul 8, 2026v3 · Sep 2, 2026
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Abstract

Integrable quantum systems evolving from non-equilibrium initial states do not thermalize to conventional Gibbs ensembles (GE). Instead, at long times they relax to generalized Gibbs ensembles (GGEs), which incorporate the full set of local and quasi-local conserved quantities. While GGEs have been extensively studied in the literature, a quantitative characterization of how different they are from ordinary GEs is still lacking. In this work, we address this question by employing the concept of athermality, which we define within quantum resource theory as the relative entropy between a given state and the closest thermal state. We compute the athermality for several quantum quenches in paradigmatic integrable models, including the free XY spin chain, the interacting Lieb-Liniger model, the XXZ spin chain, and the harmonic chain. We find that often the athermality becomes anomalously small when the post-quench Hamiltonian is critical in its ground state, despite probing physics at a finite energy density. We also prove that it systematically develops a singularity at criticality, which is inherited from the entropy of the GGE.

Journal reference
JQUANT 1 (2026) 001006
DOI
10.22323/421920260816212446
Comments
23 + 19 pages, 15 + 7 figures

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Integrable quantum systems evolving from non-equilibrium initial states do not thermalize to conventional Gibbs ensembles (GE). Instead, at long times they relax to generalized Gibbs ensembles (GGEs), which incorporate the full set of local and quasi-local conserved quantities. While GGEs have been extensively studied in the literature, a quantitative characterization of how different they are from ordinary GEs is still lacking. In this work, we address this question by employing the concept of athermality, which we define within quantum resource theory as the relative entropy between a given state and the closest thermal state. We compute the athermality for several quantum quenches in paradigmatic integrable models, including the free XY spin chain, the interacting Lieb-Liniger model, the XXZ spin chain, and the harmonic chain. We find that often the athermality becomes anomalously small when the post-quench Hamiltonian is critical in its ground state, despite probing physics at a finite energy density. We also prove that it systematically develops a singularity at criticality, which is inherited from the entropy of the GGE.
Abstract We revisit the question of whether and how the steady states arising after non-equilibrium time evolution in integrable models (and in particular in the XXZ spin chain) can be described by the so-called generalized Gibbs ensemble (GGE). Whereas it is known that the micro-canonical ensemble built on a complete set of charges correctly describes the long-time limit of local observables, it has been shown recently by Ilievski et al that the corresponding canonical ensemble is not well defined, and instead a different canonical ensemble was proposed in terms of particle occupation number operators. Here we provide an alternative construction by considering truncated GGEs (tGGEs) that include only a finite number of local and quasi-local conserved operators. It is shown that the tGGEs can approximate the steady states with arbitrary precision, i.e. all physical observables are exactly reproduced in the infinite truncation limit. We trace back the problems encountered in defining an untruncated GGE to the dependence of the associated Lagrange multipliers on the truncation index. Conversely, we show that this problem may be circumvented by considering a new set of (quasi)local charges which are linear combinations of the standard ones, and whose associated Lagrange multipliers are well-defined state functions. Our general arguments are applied to concrete quench situations in the XXZ chain, where the initial states are simple two-site or four-site product states. Depending on the quench we find that numerical results for the local correlators can be obtained with remarkable precision using truncated GGEs with only 10–100 charges.
We consider the thermalization hypothesis of pure states in nonintegrable quantum spin chains with conserved charges, including the nonintergable variants of the Ising chain with Z_{2} symmetry, XXZ chain with U(1) symmetry, and XXX chain with SU(2) symmetries. Two kinds of pure states are considered: the energy eigenstates and the typical states evolved unitarily from the random product states for a long enough period. We further group the typical states by their expectation values of the conserved charges and consider the fine-grained thermalization hypothesis. We compare the locally (subsystem) reduced states of typical states/eigenstates with the ones of the corresponding thermal ensemble states. Besides the usual thermal ensembles such as the (micro)canonical ensemble without conserved charges and the generalized Gibbs ensemble (GGE) with all conserved charges included, we also consider the so-called partial-GGEs (p-GGEs), which include only part of the conserved charges in the thermal ensemble. Moreover, in the framework of p-GGE, the Hamiltonian and other conserved charges are on an equal footing. The introduction of p-GGEs extends quantum thermalization to a more general scope. The validity of the subsystem thermalization hypothesis can be quantified by the smallness of the relative entropy of the reduced states obtained from the GGE/p-GGE and the typical states/eigenstates. We examine the validity of the thermalization hypothesis by numerically studying the relative entropy demographics. We show that the thermalization hypothesis holds generically for small enough subsystems for various p-GGEs. Thus, our framework extends the universality of quantum thermalization.
Relaxed quantum systems with conservation laws are believed to be approximated by the generalized Gibbs ensemble (GGE), which incorporates the constraints of certain conserved quantities serving as integrals of motion. By drawing an analogy between eigenstate reduced density matrix and GGE, we conjecture that a natural set of conserved quantities for GGE can emerge from the reduced density matrices of properly chosen eigenstates by the entanglement Hamiltonian superdensity matrix (EHSM) framework, and we demonstrate this explicitly for models mappable to free fermions. The framework proposes that such conserved quantities are linear superpositions of eigenstate entanglement Hamiltonians of a larger auxiliary system, where the eigenstates are Fock states occupying what we call the common eigenmodes, which remain eigenmodes when truncated within the physical subsystem. For 1D homogeneous free fermions with (anti)periodic boundary conditions, which maps to 1D hardcore bosons with nearest neighbor hoppings, these conserved quantities lead to a non-Abelian GGE, which predicts the relaxation of both fermion and boson bilinears more accurately than the conventional Abelian GGE. Generalization of this framework may provide novel numerical insights for quantum integrability.
We investigate the crossover of the entanglement entropy toward its thermal value in nearly integrable systems. We employ equations-of-motion techniques to study the entanglement dynamics in a lattice model of weakly interacting spinless fermions after a quantum quench. For weak enough interactions we observe a two-step relaxation of the entanglement entropies of finite subsystems. Initially, the entropies follow a nearly integrable evolution, approaching the value predicted by the generalized Gibbs ensemble (GGE) of the unperturbed model. Then, they start a slow drift toward the thermal stationary value described by a standard Gibbs ensemble (GE). While the initial relaxation to the GGE is independent of the interaction, the slow drift from GGE to GE values happens on timescales proportional to the inverse interaction squared. For asymptotically large times and subsystem sizes the dynamics of the entropies can be predicted using a modified quasiparticle picture that keeps track of the evolution of the fermionic occupations caused by the integrability breaking. This picture gives a quantitative description of the results as long as the integrability-breaking timescale is much larger than the one associated with the (quasi)saturation to the GGE. In the opposite limit, the quasiparticle picture still provides the correct late-time behavior, but it underestimates the initial slope of the entanglement entropy.
It is widely accepted that local subsystems in isolated integrable quantum systems equilibrate to generalized Gibbs ensembles. Here, we identify a particular class of initial states in interacting integrable models that evade canonical generalized thermalization. Particularly, we demonstrate that in the easy-axis regime of the quantum XXZ chain, pure nonequilibrium initial states that lack magnetic fluctuations instead locally relax to squeezed generalized Gibbs ensembles governed by nonlocal equilibrium Hamiltonians, representing exotic equilibrium states with subextensive charge fluctuations that violate the self-affine scaling. At the isotropic point, we find exceptional behavior and explicit dependence on the initial state. Particularly, we find that relaxation from the Néel state is governed by extensive fluctuations and a superdiffusive dynamical exponent compatible with the Kardar-Parisi-Zhang universality. On the other hand, there are other nonfluctuating initial states that display diffusive scaling, e.g., a product state of spin singlets. Our predictions provide examples of anomalous quantum transport and fluctuations in strictly quantum states which can be directly tested in state-of-the-art cold atomic experimental settings.
Although statistical mechanics describes thermal equilibrium states, these states may or may not emerge dynamically for a subsystem of an isolated quantum many-body system. For instance, quantum systems that are near-integrable usually fail to thermalize in an experimentally realistic time scale, and instead relax to quasi-stationary prethermal states that can be described by statistical mechanics, when approximately conserved quantities are included in a generalized Gibbs ensemble (GGE). We experimentally study the relaxation dynamics of a chain of up to 22 spins evolving under a long-range transverse-field Ising Hamiltonian following a sudden quench. For sufficiently long-range interactions, the system relaxes to a new type of prethermal state that retains a strong memory of the initial conditions. However, the prethermal state in this case cannot be described by a standard GGE; it rather arises from an emergent double-well potential felt by the spin excitations. This result shows that prethermalization occurs in a broader context than previously thought, and reveals new challenges for a generic understanding of the thermalization of quantum systems, particularly in the presence of long-range interactions.