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arXiv:2412.09905 · Physical review. E

Subsystem thermalization hypothesis in quantum spin chains with conserved charges

Feng-Li Lin, Jhh-Jing Hong, Ching-Yu Huang

Published Jul 18, 2025• 0 citations
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Abstract

We consider the thermalization hypothesis of pure states in nonintegrable quantum spin chains with conserved charges, including the nonintergable variants of the Ising chain with Z_{2} symmetry, XXZ chain with U(1) symmetry, and XXX chain with SU(2) symmetries. Two kinds of pure states are considered: the energy eigenstates and the typical states evolved unitarily from the random product states for a long enough period. We further group the typical states by their expectation values of the conserved charges and consider the fine-grained thermalization hypothesis. We compare the locally (subsystem) reduced states of typical states/eigenstates with the ones of the corresponding thermal ensemble states. Besides the usual thermal ensembles such as the (micro)canonical ensemble without conserved charges and the generalized Gibbs ensemble (GGE) with all conserved charges included, we also consider the so-called partial-GGEs (p-GGEs), which include only part of the conserved charges in the thermal ensemble. Moreover, in the framework of p-GGE, the Hamiltonian and other conserved charges are on an equal footing. The introduction of p-GGEs extends quantum thermalization to a more general scope. The validity of the subsystem thermalization hypothesis can be quantified by the smallness of the relative entropy of the reduced states obtained from the GGE/p-GGE and the typical states/eigenstates. We examine the validity of the thermalization hypothesis by numerically studying the relative entropy demographics. We show that the thermalization hypothesis holds generically for small enough subsystems for various p-GGEs. Thus, our framework extends the universality of quantum thermalization.

DOI
10.1103/kvn9-s63j

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We consider the thermalization hypothesis of pure states in nonintegrable quantum spin chains with conserved charges, including the nonintergable variants of the Ising chain with Z_{2} symmetry, XXZ chain with U(1) symmetry, and XXX chain with SU(2) symmetries. Two kinds of pure states are considered: the energy eigenstates and the typical states evolved unitarily from the random product states for a long enough period. We further group the typical states by their expectation values of the conserved charges and consider the fine-grained thermalization hypothesis. We compare the locally (subsystem) reduced states of typical states/eigenstates with the ones of the corresponding thermal ensemble states. Besides the usual thermal ensembles such as the (micro)canonical ensemble without conserved charges and the generalized Gibbs ensemble (GGE) with all conserved charges included, we also consider the so-called partial-GGEs (p-GGEs), which include only part of the conserved charges in the thermal ensemble. Moreover, in the framework of p-GGE, the Hamiltonian and other conserved charges are on an equal footing. The introduction of p-GGEs extends quantum thermalization to a more general scope. The validity of the subsystem thermalization hypothesis can be quantified by the smallness of the relative entropy of the reduced states obtained from the GGE/p-GGE and the typical states/eigenstates. We examine the validity of the thermalization hypothesis by numerically studying the relative entropy demographics. We show that the thermalization hypothesis holds generically for small enough subsystems for various p-GGEs. Thus, our framework extends the universality of quantum thermalization.
Understanding how isolated quantum systems thermalize has recently gathered renewed interest almost 100 years after the first work by von Neumann, thanks to the experimental realizations of such systems. Experimental and numerical pieces of evidence imply that nonintegrability of the system plays an important role in thermalization. Nonintegrable systems that conserve energy alone are expected to be effectively described by the (micro)canonical ensemble due to the so-called eigenstate thermalization hypothesis (ETH) in the thermodynamic limit. In contrast, it is expected that stationary states in integrable systems are described not by the canonical ensemble but by the generalized Gibbs ensemble (GGE) due to the existence of many nontrivial conserved quantities. In this thesis, we study thermalization and its mechanism in nonintegrable systems from two perspectives. We first study how well the ETH and its finite-size corrections can be predicted by random matrix theory (RMT). Next, we present our study on the emergence of the GGE in a nonintegrable system with an extensive number of local symmetries.
Integrable quantum systems evolving from non-equilibrium initial states do not thermalize to conventional Gibbs ensembles (GE). Instead, at long times they relax to generalized Gibbs ensembles (GGEs), which incorporate the full set of local and quasi-local conserved quantities. While GGEs have been extensively studied in the literature, a quantitative analytic characterization of how different they are from ordinary GEs is still lacking. In this work, we address this question by employing the concept of athermality, which we define within quantum resource theory as the relative entropy between a given state and the closest thermal state. By means of integrability techniques we compute the athermality for several quantum quenches in paradigmatic integrable models, including the free XY spin chain, the interacting Lieb-Liniger model, the XXZ spin chain, and the harmonic chain. We find that often the athermality becomes anomalously small when the post-quench Hamiltonian is critical in its ground state, despite probing physics at a finite energy density. We also prove that it systematically develops a singularity at criticality, which is inherited from the entropy of the GGE.
Deep thermalization indicates the emergence of universal ensembles of pure states in a subsystem after measuring its environment. We investigate this phenomenon in a free-fermion chain using local measurements that preserve Gaussianity and break particle-number conservation. Although the measurement outcomes provide partial information about local conserved charges within a finite subsystem, we argue that this information becomes negligible in the thermodynamic limit. This effective non-revelation underlies the emergence of a fermionic Gaussian Scrooge ensemble, determined by the subsystem's generalized Gibbs ensemble. We construct this universal ensemble directly at the subsystem level and provide numerical evidence that it describes the late-time projected ensemble at finite temperature. Our results extend the description of thermalization in non-interacting integrable systems beyond the reduced density matrix to universal statistics of conditional pure states.
Abstract We revisit the question of whether and how the steady states arising after non-equilibrium time evolution in integrable models (and in particular in the XXZ spin chain) can be described by the so-called generalized Gibbs ensemble (GGE). Whereas it is known that the micro-canonical ensemble built on a complete set of charges correctly describes the long-time limit of local observables, it has been shown recently by Ilievski et al that the corresponding canonical ensemble is not well defined, and instead a different canonical ensemble was proposed in terms of particle occupation number operators. Here we provide an alternative construction by considering truncated GGEs (tGGEs) that include only a finite number of local and quasi-local conserved operators. It is shown that the tGGEs can approximate the steady states with arbitrary precision, i.e. all physical observables are exactly reproduced in the infinite truncation limit. We trace back the problems encountered in defining an untruncated GGE to the dependence of the associated Lagrange multipliers on the truncation index. Conversely, we show that this problem may be circumvented by considering a new set of (quasi)local charges which are linear combinations of the standard ones, and whose associated Lagrange multipliers are well-defined state functions. Our general arguments are applied to concrete quench situations in the XXZ chain, where the initial states are simple two-site or four-site product states. Depending on the quench we find that numerical results for the local correlators can be obtained with remarkable precision using truncated GGEs with only 10–100 charges.
The investigation of ergodicity or lack thereof in isolated quantum many-body systems has conventionally focused on the description of the reduced density matrices of local subsystems in the contexts of thermalization, integrability, and localization. Recent experimental capabilities to measure the full distribution of quantum states in Hilbert space and the emergence of specific state ensembles have extended this to questions of deep thermalization, introducing the notion of the projected ensemble---ensemble of pure states of a subsystem obtained by projective measurements on its complement. While previous studies examined chaotic unitary circuits and Hamiltonian evolution in systems with or without global conserved charges, we study the projected ensemble in systems where there are an extensive number of conserved charges all of which have (quasi)local support. We employ a strongly disordered quantum spin chain that shows many-body localized dynamics over long timescales, as well as the $\ensuremath{\ell}$-bit model, a phenomenological archetype of a many-body localized system, with the charges being 1-local in the latter. In particular, we discuss the dependence of the projected ensemble on the measurement basis. Starting with random direct product states, we find that the projected ensemble constructed from time-evolved states converges to a Scrooge ensemble at late times and in the large system limit except when the measurement operator is close to the conserved charges. This is in contrast to systems with global conserved charges where the ensemble varies continuously with the measurement basis. We relate these observations to the emergence of the Porter-Thomas distribution in the probability distribution of bitstring measurement probabilities.
A bstract The Generalized Gibbs Ensemble (GGE) is relevant to understand the thermalization of quantum systems with an infinite set of conserved charges. In this work, we analyze the GGE partition function of 2D Conformal Field Theories (CFTs) with a U(1) charge and quantum Benjamin-Ono 2 (qBO 2 ) hierarchy charges. We use the Alday-Gaiotto-Tachikawa (AGT) correspondence to express the thermal trace in terms of the Alba-Fateev-Litvinov-Tarnopolskiy (AFLT) basis of descendants, which diagonalizes all charges. We analyze the GGE partition function in the thermodynamic semiclassical limit, including the first order quantum correction. We find that the equality between GGE averages and primary eigenvalues of the qBO 2 charges is attainable in the strict large c limit and potentially violated at the subleading 1 /c order. We also obtain the finite c partition function when only the first non-trivial charge is turned on, expressed in terms of partial theta functions. Our results should be relevant to the eigenstate thermalization hypothesis for charged CFTs, Warped CFTs and effective field theory descriptions of condensed matter systems.