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arXiv:2601.16002

Engineering quantum Mpemba effect by Liouvillian skin effect

Xiang Zhang, Chen Sun, Fuxiang Li

quant-phSubmitted Jan 22, 2026• Announced Jan 23, 2026• 0 citations• Revised Jan 28, 2026 (v2)
v1 · Jan 22, 2026v2 · Jan 28, 2026
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Abstract

We propose a novel approach to engineer the quantum Mpemba effect (QME)-wherein an initial state farther from the steaty state relaxes faster than a closer one-by the Liouvillian skin effect (LSE) in open quantum systems. We show that, in the open quantum chain with LSE, QME can be easily realized by considering only the spatial profile of initial states, since the initial states localized on the left or right edges experience distinctive relaxation process (algebraic or exponential decay). This approach circumvents the necessity of careful initial-state design and fine-tuning of control parameter. Moreover, when the initial correlation matrix contains off-diagonal elements, we uncover a new kind of QME which manifest as two crossings in the Hilbert-Schmidt distance at different times. This work unveils the deep connection between QME and LSE, and provides a physically intuitive understanding of QME and straightforward pathway for the initial state preparation thereby enabling readily accessible experimental preparation.

Comments
7 pages, 2 figures. Comments are welcome!

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We propose a novel approach to engineer the quantum Mpemba effect (QME)-wherein an initial state farther from the steaty state relaxes faster than a closer one-by the Liouvillian skin effect (LSE) in open quantum systems. We show that, in the open quantum chain with LSE, QME can be easily realized by considering only the spatial profile of initial states, since the initial states localized on the left or right edges experience distinctive relaxation process (algebraic or exponential decay). This approach circumvents the necessity of careful initial-state design and fine-tuning of control parameter. Moreover, when the initial correlation matrix contains off-diagonal elements, we uncover a new kind of QME which manifest as two crossings in the Hilbert-Schmidt distance at different times. This work unveils the deep connection between QME and LSE, and provides a physically intuitive understanding of QME and straightforward pathway for the initial state preparation thereby enabling readily accessible experimental preparation.
We unveil a quantum Pontus-Mpemba effect enabled by the Liouvillian skin effect in a dissipative tight-binding chain with asymmetric incoherent hopping and coherent boundary coupling. The skin effect, induced by non-reciprocal dissipation, localizes relaxation modes near the system boundaries and gives rise to non-orthogonal spectral geometry. While such non-normality is often linked to slow relaxation, we show that it can instead accelerate relaxation through a two-step protocol - realizing a quantum Pontus-Mpemba effect. Specifically, we consider a one-dimensional open chain with coherent hopping JJJ, asymmetric incoherent hoppings JR≠JLJ_{\rm R} \neq J_{\rm L}JR​=JL​, and a controllable end-to-end coupling εεε. For ε=0ε=0ε=0, the system exhibits the Liouvillian skin effect, with left and right eigenmodes localized at opposite edges. We compare two relaxation protocols toward the same stationary state: (i) a direct relaxation with ε=0ε=0ε=0, and (ii) a two-step (Pontus) protocol where a brief coherent evolution transfers the excitation across the lattice before relaxation. Although both share the same asymptotic decay rate, the two-step protocol relaxes significantly faster due to its reduced overlap with the slow boundary-localized Liouvillian mode. The effect disappears when JR=JLJ_{\rm R}=J_{\rm L}JR​=JL​, i.e., when the skin effect vanishes. Our results reveal a clear connection between boundary-induced non-normality and protocol-dependent relaxation acceleration, suggesting new routes for controlling dissipation and transient dynamics in open quantum systems.
The Mpemba effect, where a state farther from equilibrium relaxes faster than one closer to it, is a striking phenomenon in both classical and quantum systems. In open quantum systems, however, the quantum Mpemba effect (QME) typically occurs only for specifically chosen initial states, which limits its universality. Here we present a general and experimentally feasible strategy to realize both QME and anti-QME. By applying a temporary bond-dissipation quench, we selectively suppresses or enhances slow relaxation modes, thereby reshaping relaxation pathways independently of both the system and the initial state. We demonstrate this mechanism in systems with dephasing and boundary dissipation, and outline feasible cold-atom implementations. Our results establish controllable dissipation as a versatile tool for quantum control, accelerated relaxation, and efficient nonequilibrium protocols.
The quantum Mpemba effect refers to the counterintuitive phenomenon in which a system initially farther from equilibrium relaxes faster than one prepared closer to it. Several mechanisms have been identified in open quantum systems to explain this behavior, including the strong Mpemba effect, non-Markovian memory, and initial system-reservoir entanglement. Here, we unveil a distinct mechanism rooted in the non-normal nature of the Liouvillian superoperator in Markovian dynamics. When the Liouvillian's eigenmodes are non-orthogonal, transient interference between decaying modes can induce anomalous early-time behavior-such as delayed thermalization or transient freezing-even though asymptotic decay rates remain unchanged. This differs fundamentally from strong Mpemba effects, which hinge on suppressed overlap with slow-decaying modes. We demonstrate this mechanism using a waveguide quantum electrodynamics model, where quantum emitters interact with the photonic modes of a one-dimensional waveguide. The directional and radiative nature of these couplings naturally introduces non-normality into the system's dynamics. As a result, certain initial states-despite being closer to equilibrium-can exhibit slower relaxation at short times. This work reveals a previously unexplored and universal source of Mpemba-like behavior in memoryless quantum systems, expanding the theoretical framework for anomalous relaxation and opening new avenues for control in engineered quantum platforms.
The slowest Liouvillian mode often bottlenecks the relaxation of an open quantum system to its steady state. Standard strategies circumvent this bottleneck by selecting special initial states or engineering the dissipator. Here we show that neither is necessary. We introduce a pre-dissipative geometric steering protocol that reshapes any given pure or mixed state before relaxation begins -- coherent rotations interleaved with nonselective projective measurements -- at fixed Lindblad generator. By steering the state's Bloch direction along geodesic paths, the protocol suppresses its overlap with the slowest Liouvillian modes. The prepared state then starts farther from equilibrium yet relaxes faster, realizing the quantum Mpemba effect, whenever two computable conditions hold: reduced slow-mode overlap and a larger initial distance to stationarity. Our framework treats real and complex spectral gaps uniformly, and we demonstrate robust Mpemba acceleration in driven qubit and multiqubit systems using operations available in trapped-ion and superconducting platforms.
An ancient and counterintuitive phenomenon known as the Mpemba effect (water can cool faster when initially heated up) showcases the critical role of initial conditions in relaxation processes. How to realize and utilize this effect for speeding up relaxation is an important but challenging task in purely quantum system till now. Here, we experimentally study the strong Mpemba effect in a single trapped ion system in which an exponentially accelerated relaxation in time is observed by preparing an optimal quantum initial state with no excitation of the slowest decaying mode. Also, we demonstrate that the condition of realizing such effect coincides with the Liouvillian exceptional point, featuring the coalescence of both the eigenvalues and the eigenmodes of the systems. Our work provides an efficient strategy to engineer the dynamics of open quantum system, and suggests a link unexplored yet between the Mpemba effect and the non-Hermitian physics. The Mpemba effect is an archetype for various anomalous relaxation phenomena. Here, the authors experimentally study a quantum version of the Mpemba effect in a single trapped ion system, where relaxation is exponentially accelerated by removing the excitation of the slowest decaying mode. This phenomenon, seen in Markovian open quantum systems containing Liouvillian exceptional points, indicates a link between the Mpemba effect and non-Hermitian physics.
We investigate the quantum Mpemba effect in the relaxation of open quantum systems whose effective dynamics is described by Davies maps. We introduce a class of unitary transformations constructed from permutation matrices that, when applied to an initial state, (i) suppress the slowest decaying modes of the nonunitary dynamics and (ii) maximize the state's distinguishability from the steady state. The first condition ensures exponentially faster convergence to equilibrium, while the second implies that a quantum system initially further from equilibrium can approach it more rapidly than one that starts closer. This protocol thus realizes a genuine Mpemba effect, and its simulation requires low computational effort. We prove that, for any initial state, there exists a permutation matrix that maximizes its distance from equilibrium with respect to a chosen information-theoretic distinguishability measure. We illustrate our findings for a two-level system, as well as for the nonunitary dynamics of the transverse-field Ising chain and the XXZ chain, each weakly coupled to a bosonic thermal bath. In these cases, the quantum Mpemba effect is demonstrated using the Hilbert-Schmidt distance, quantum relative entropy, and trace distance. Overall, our results provide a versatile framework for engineering a genuine quantum Mpemba effect in Markovian open quantum systems.