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arXiv:2601.14083

Quantum Pontus-Mpemba Effect Enabled by the Liouvillian Skin Effect

Stefano Longhi

quant-phcond-mat.dis-nnSubmitted Jan 20, 2026• Announced Jan 21, 2026
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Abstract

We unveil a quantum Pontus-Mpemba effect enabled by the Liouvillian skin effect in a dissipative tight-binding chain with asymmetric incoherent hopping and coherent boundary coupling. The skin effect, induced by non-reciprocal dissipation, localizes relaxation modes near the system boundaries and gives rise to non-orthogonal spectral geometry. While such non-normality is often linked to slow relaxation, we show that it can instead accelerate relaxation through a two-step protocol - realizing a quantum Pontus-Mpemba effect. Specifically, we consider a one-dimensional open chain with coherent hopping $J$, asymmetric incoherent hoppings $J_{\rm R} \neq J_{\rm L}$, and a controllable end-to-end coupling $ε$. For $ε=0$, the system exhibits the Liouvillian skin effect, with left and right eigenmodes localized at opposite edges. We compare two relaxation protocols toward the same stationary state: (i) a direct relaxation with $ε=0$, and (ii) a two-step (Pontus) protocol where a brief coherent evolution transfers the excitation across the lattice before relaxation. Although both share the same asymptotic decay rate, the two-step protocol relaxes significantly faster due to its reduced overlap with the slow boundary-localized Liouvillian mode. The effect disappears when $J_{\rm R}=J_{\rm L}$, i.e., when the skin effect vanishes. Our results reveal a clear connection between boundary-induced non-normality and protocol-dependent relaxation acceleration, suggesting new routes for controlling dissipation and transient dynamics in open quantum systems.

Journal reference
J. Phys. A: Math. Theor. 59, 065304 (2026)
DOI
10.1088/1751-8121/ae4079
Comments
14 pages, 6 figures, submitted for the special issue on "Mpemba Effects and Anomalous Nonequilibrium Relaxations in Classical and Quantum Systems", J. Phys. A

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We unveil a quantum Pontus-Mpemba effect enabled by the Liouvillian skin effect in a dissipative tight-binding chain with asymmetric incoherent hopping and coherent boundary coupling. The skin effect, induced by non-reciprocal dissipation, localizes relaxation modes near the system boundaries and gives rise to non-orthogonal spectral geometry. While such non-normality is often linked to slow relaxation, we show that it can instead accelerate relaxation through a two-step protocol - realizing a quantum Pontus-Mpemba effect. Specifically, we consider a one-dimensional open chain with coherent hopping JJJ, asymmetric incoherent hoppings JR≠JLJ_{\rm R} \neq J_{\rm L}JR​=JL​, and a controllable end-to-end coupling εεε. For ε=0ε=0ε=0, the system exhibits the Liouvillian skin effect, with left and right eigenmodes localized at opposite edges. We compare two relaxation protocols toward the same stationary state: (i) a direct relaxation with ε=0ε=0ε=0, and (ii) a two-step (Pontus) protocol where a brief coherent evolution transfers the excitation across the lattice before relaxation. Although both share the same asymptotic decay rate, the two-step protocol relaxes significantly faster due to its reduced overlap with the slow boundary-localized Liouvillian mode. The effect disappears when JR=JLJ_{\rm R}=J_{\rm L}JR​=JL​, i.e., when the skin effect vanishes. Our results reveal a clear connection between boundary-induced non-normality and protocol-dependent relaxation acceleration, suggesting new routes for controlling dissipation and transient dynamics in open quantum systems.
We investigate how quasiperiodic spatial structure enables protocol-induced acceleration in open quantum systems by analyzing the Pontus-Mpemba effect in one-dimensional chains subject to Markovian dephasing. The dynamics are governed by a Lindblad superoperator that drives all initial states toward a maximally mixed infinite-temperature steady state, isolating dynamical mechanisms from static equilibrium properties. Considering two representative quasiperiodic models, namely a tight-binding chain with a mosaic potential and its extension with power-law long-range hopping, we show that a properly engineered two-step protocol, in which the system is first steered to a finite temperature intermediate state, yields a strictly shorter overall relaxation time than direct evolution from the same initial configuration. This protocol-induced acceleration persists for both initially localized and extended eigenstates and remains robust in the presence of long-range hopping. A Liouvillian spectral analysis reveals that the mechanism originates from a redistribution of spectral weight that suppresses overlap with the slowest decay modes, rather than from any modification of the decay spectrum itself. Our results establish quasiperiodic chains as a controlled setting for engineering relaxation pathways through Liouvillian spectral structure.
The quantum Mpemba effect refers to the counterintuitive phenomenon in which a system initially farther from equilibrium relaxes faster than one prepared closer to it. Several mechanisms have been identified in open quantum systems to explain this behavior, including the strong Mpemba effect, non-Markovian memory, and initial system-reservoir entanglement. Here, we unveil a distinct mechanism rooted in the non-normal nature of the Liouvillian superoperator in Markovian dynamics. When the Liouvillian's eigenmodes are non-orthogonal, transient interference between decaying modes can induce anomalous early-time behavior-such as delayed thermalization or transient freezing-even though asymptotic decay rates remain unchanged. This differs fundamentally from strong Mpemba effects, which hinge on suppressed overlap with slow-decaying modes. We demonstrate this mechanism using a waveguide quantum electrodynamics model, where quantum emitters interact with the photonic modes of a one-dimensional waveguide. The directional and radiative nature of these couplings naturally introduces non-normality into the system's dynamics. As a result, certain initial states-despite being closer to equilibrium-can exhibit slower relaxation at short times. This work reveals a previously unexplored and universal source of Mpemba-like behavior in memoryless quantum systems, expanding the theoretical framework for anomalous relaxation and opening new avenues for control in engineered quantum platforms.
We propose a novel approach to engineer the quantum Mpemba effect (QME)-wherein an initial state farther from the steaty state relaxes faster than a closer one-by the Liouvillian skin effect (LSE) in open quantum systems. We show that, in the open quantum chain with LSE, QME can be easily realized by considering only the spatial profile of initial states, since the initial states localized on the left or right edges experience distinctive relaxation process (algebraic or exponential decay). This approach circumvents the necessity of careful initial-state design and fine-tuning of control parameter. Moreover, when the initial correlation matrix contains off-diagonal elements, we uncover a new kind of QME which manifest as two crossings in the Hilbert-Schmidt distance at different times. This work unveils the deep connection between QME and LSE, and provides a physically intuitive understanding of QME and straightforward pathway for the initial state preparation thereby enabling readily accessible experimental preparation.
The quantum Pontus-Mpemba effect is a counterintuitive phenomenon in which a quantum system relaxes faster through a two-step evolution protocol than through a single, unquenched relaxation. This work proposes its realization in cavity quantum electrodynamics using the Jaynes-Cummings model with photon loss. The model captures the coherent interaction between a two-level atom and a single quantized mode of a lossy cavity, providing a minimal yet realistic setting to explore dissipative quantum dynamics. Restricting the analysis to the single-excitation sector, the dynamics feature damped vacuum Rabi oscillations for weak dissipation that transition to near-exponential atomic decay under strong dissipation. A sudden quench of the cavity decay rate generates distinct relaxation trajectories from the same initial atom-cavity state. The atomic excitation then displays a non-monotonic, accelerated decay, where a trajectory with a quenched dissipation relaxes faster than fixed-loss evolution. The effect originates from the interplay between coherent atom-photon exchange and cavity dissipation, establishing a clear and experimentally accessible realization of the quantum Pontus-Mpemba effect in both optical and circuit QED platforms.
The slowest Liouvillian mode often bottlenecks the relaxation of an open quantum system to its steady state. Standard strategies circumvent this bottleneck by selecting special initial states or engineering the dissipator. Here we show that neither is necessary. We introduce a pre-dissipative geometric steering protocol that reshapes any given pure or mixed state before relaxation begins -- coherent rotations interleaved with nonselective projective measurements -- at fixed Lindblad generator. By steering the state's Bloch direction along geodesic paths, the protocol suppresses its overlap with the slowest Liouvillian modes. The prepared state then starts farther from equilibrium yet relaxes faster, realizing the quantum Mpemba effect, whenever two computable conditions hold: reduced slow-mode overlap and a larger initial distance to stationarity. Our framework treats real and complex spectral gaps uniformly, and we demonstrate robust Mpemba acceleration in driven qubit and multiqubit systems using operations available in trapped-ion and superconducting platforms.
It is highly nontrivial to what extent we can deduce the relaxation behavior of a quantum dissipative system from the spectral gap of the Liouvillian that governs the time evolution of the density matrix. We investigate the relaxation processes of a quantum dissipative system that exhibits the Liouvillian skin effect, which means that the eigenmodes of the Liouvillian are localized exponentially close to the boundary of the system, and find that the timescale for the system to reach a steady state depends not only on the Liouvillian gap $\mathrm{\ensuremath{\Delta}}$, but also on the localization length $\ensuremath{\xi}$ of the eigenmodes. In particular, we show that the longest relaxation time $\ensuremath{\tau}$ that is maximized over initial states and local observables is given by $\ensuremath{\tau}\ensuremath{\sim}{\mathrm{\ensuremath{\Delta}}}^{\ensuremath{-}1}(1+L/\ensuremath{\xi})$ with LLL being the system size. This implies that the longest relaxation time can diverge for $L\ensuremath{\rightarrow}\ensuremath{\infty}$ without gap closing.