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arXiv:2512.09324

Mpemba as an Emergent Effect of System Relaxation

Gourab Das

quant-phSubmitted Dec 10, 2025• Announced Dec 11, 2025• 0 citations• Revised Sep 5, 2026 (v2)
v1 · Dec 10, 2025v2 · Sep 5, 2026
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Abstract

The Mpemba effect (MpE), where a far-from-equilibrium state of a system relaxes faster compared to a state closer to it, is a well-known counterintuitive phenomenon in classical and quantum systems. Various system-specific theories have been proposed to explain this anomalous behavior in driven systems, though the fundamental mechanism of MpE in undriven systems, where MpE was first observed, remains unresolved. This paper provides a generic model of MpE for a quantum spin-$1/2$ system following Markovian relaxation dynamics, regardless of system structure or environment. The key lies in the overlap of initial states with the fast relaxation mode; here, the constituents create a fast decay mode via interaction through the shared environment to show MpE, indicating that MpE happens due to the collective behavior of the system. I also show that a system with anisotropic relaxation naturally exhibits MpE, even without a shared environment among the particles.

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The Mpemba effect (MpE), where a far-from-equilibrium state of a system relaxes faster compared to a state closer to it, is a well-known counterintuitive phenomenon in classical and quantum systems. Various system-specific theories have been proposed to explain this anomalous behavior in driven systems, though the fundamental mechanism of MpE in undriven systems, where MpE was first observed, remains unresolved. This paper provides a generic model of MpE for a quantum spin-1/21/21/2 system following Markovian relaxation dynamics, regardless of system structure or environment. The key lies in the overlap of initial states with the fast relaxation mode; here, the constituents create a fast decay mode via interaction through the shared environment to show MpE, indicating that MpE happens due to the collective behavior of the system. I also show that a system with anisotropic relaxation naturally exhibits MpE, even without a shared environment among the particles.
The quantum Mpemba effect refers to the counterintuitive phenomenon in which a system initially farther from equilibrium relaxes faster than one prepared closer to it. Several mechanisms have been identified in open quantum systems to explain this behavior, including the strong Mpemba effect, non-Markovian memory, and initial system-reservoir entanglement. Here, we unveil a distinct mechanism rooted in the non-normal nature of the Liouvillian superoperator in Markovian dynamics. When the Liouvillian's eigenmodes are non-orthogonal, transient interference between decaying modes can induce anomalous early-time behavior-such as delayed thermalization or transient freezing-even though asymptotic decay rates remain unchanged. This differs fundamentally from strong Mpemba effects, which hinge on suppressed overlap with slow-decaying modes. We demonstrate this mechanism using a waveguide quantum electrodynamics model, where quantum emitters interact with the photonic modes of a one-dimensional waveguide. The directional and radiative nature of these couplings naturally introduces non-normality into the system's dynamics. As a result, certain initial states-despite being closer to equilibrium-can exhibit slower relaxation at short times. This work reveals a previously unexplored and universal source of Mpemba-like behavior in memoryless quantum systems, expanding the theoretical framework for anomalous relaxation and opening new avenues for control in engineered quantum platforms.
Since its rediscovery in the twentieth century, the Mpemba effect, where a far-from-equilibrium state may relax faster than a state closer to equilibrium, has been extensively studied in classical systems and has recently received attention in quantum systems. Many theories explaining this counter-intuitive behavior in classical systems rely on memory effects. However, in quantum systems, the relation between the Mpemba effect and memory has remained unexplored. In this Letter, we consider general non-Markovian open quantum systems and reveal new classes of quantum Mpemba effects, with no analog in Markovian quantum dynamics. Generically, open quantum dynamics possess a finite memory time and a unique steady state. Because of non-Markovian dynamics, even if the system is initialized in the steady state it can take a long time to relax back. We find other initial states that reach the steady state much faster. Most notably, we demonstrate that there can be an initial state in which the system reaches the steady state within the finite memory time itself, giving the fastest possible relaxation to stationarity. We verify the effect for quantum dot systems coupled to electronic reservoirs in equilibrium and nonequilibrium setups at weak, intermediate and strong coupling. Our Letter provides new insights into the rich physics underlying accelerated relaxation in quantum systems.
The Mpemba effect was originally referred to as the faster icing of a higher-temperature system than a lower-temperature system, and was later generalized to anomalous decays of both classical and quantum observables to equilibrium states. Mpemba effect is mostly considered in classical systems and during cooling processes toward equilibrium states. We investigate the emergence of the effect in nonequilibrium quantum systems where the system has no asymptotic equilibrium state to approach. Instead, the system is put in contact with two different baths, and only a nonequilibrium state exists, sustained by constant energy injection from the surrounding thermal baths. First, we show that the nonequilibrium conditions can dramatically enlarge the parameter regimes where the MPE emerges. Second, we demonstrate that the anomalous MPEs and inverse MPEs emerge in the evolution of quantum correlations in the two-site fermionic system and that nonequilibrium conditions can expedite or delay the MPEs. Third, we show that the nonequilibrium-induced quantum coherence can have considerable contributions to the emergence of the MPE which the conventional Lindbladian dynamics fails to capture. Published by the American Physical Society 2024
Abstract The quantum Mpemba effect (QMPE) is characterized by a state initially farther from equilibrium relaxing faster than one closer to it. In this work, we investigate the QMPE in an open central-spin model, and examine whether the QMPE emerges when the spins’ system is subjected to their independent noisy environment for different initial states. Simultaneously, we analyze the influence of the noisy environment on the dynamics and demonstrate that tuning local noise strengths can induce the QMPE. Furthermore, we systematically explore finite-size effects by varying the number of peripheral spins. In addition, we investigate the Pontus Mpemba effect within the same framework, demonstrating that an auxiliary decohering environment can accelerate the approach to stationarity. To observe the effect, we select the trace distance, energy, and l 1 -norm coherence as observables. By combining initial-state engineering (global rotation operations) with the modulation of the noisy environment, we clearly reveal the physical mechanisms for inducing and controlling the QMPE in this model. Our results show that both rotating the initial states and applying non-uniform local noises can alter the relaxation rate ordering among different states, leading to crossings in the evolution curves of various physical quantities, that is, the realization of the QMPE. This finding provides a new perspective for manipulating anomalous relaxation behavior in the quantum many-body system and open quantum system.
The Mpemba effect, broadly understood as the counterintuitive phenomenon in which a system initially farther from equilibrium relaxes faster than a system closer to equilibrium, has been widely studied in classical stochastic systems and, more recently, in quantum settings. However, its manifestation is strongly dependent on the choice of observable and the dynamical constraints of the system. In this work, we investigate the emergence of a Mpemba-type effect in the density redistribution dynamics of a strongly interacting one-dimensional Bose gas in the Tonks-Girardeau regime undergoing a sudden box expansion from length L_0 to L. By defining a physically motivated distance function based on the difference of densities between spatial regions, we provide evidence that -the relaxation dynamics of the ground and excited symmetry sectors exhibit a clear crossing in time, indicating a reversal in relaxation ordering. We emphasize that the Mpemba effect is not a universal law but rather an observable-dependent phenomenon that arises under specific dynamical conditions. In particular, we show that the interplay between initial state structure, integrability, and spatial redistribution leads to distinct relaxation pathways that enable the effect. Our results clarify common misconceptions linking the Mpemba effect to Newton's law of cooling and highlight the conditions under which such anomalous relaxation behavior can emerge in integrable quantum systems.
In recent years, the quantum Mpemba effect (QME) which occurs when an out-of-equilibrium system reaches equilibrium faster than another that is closer to equilibrium has attracted significant attention from the scientific community as an intriguing and counterintuitive phenomenon. It generalizes its classical counterpart, extending the concept beyond thermal equilibration. This paper approaches the QME for Markovian open quantum systems from different perspectives. Firstly, we propose a physical mechanism based on decoherence-free subspaces. Secondly, we show that a macroscopic enhancement of the decay rate that scales linearly with system size can be obtained, leading to an extreme version of the phenomenon on Markovian open quantum systems. Thirdly, we study the Mpemba effect through the unravelings of Davies maps, revealing subtleties in the figures of merit which are chosen for obtaining the QME. Lastly, we propose a microscopic model for a better understanding of thermal bath dynamics in this context.