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arXiv:2604.05408

Mpemba Effect in an Expanding Lieb-Liniger Bose gas in a hard wall box

Sumita Datta

Published Apr 7, 2026• 0 citations

Abstract

The Mpemba effect, broadly understood as the counterintuitive phenomenon in which a system initially farther from equilibrium relaxes faster than a system closer to equilibrium, has been widely studied in classical stochastic systems and, more recently, in quantum settings. However, its manifestation is strongly dependent on the choice of observable and the dynamical constraints of the system. In this work, we investigate the emergence of a Mpemba-type effect in the density redistribution dynamics of a strongly interacting one-dimensional Bose gas in the Tonks-Girardeau regime undergoing a sudden box expansion from length L_0 to L. By defining a physically motivated distance function based on the difference of densities between spatial regions, we provide evidence that -the relaxation dynamics of the ground and excited symmetry sectors exhibit a clear crossing in time, indicating a reversal in relaxation ordering. We emphasize that the Mpemba effect is not a universal law but rather an observable-dependent phenomenon that arises under specific dynamical conditions. In particular, we show that the interplay between initial state structure, integrability, and spatial redistribution leads to distinct relaxation pathways that enable the effect. Our results clarify common misconceptions linking the Mpemba effect to Newton's law of cooling and highlight the conditions under which such anomalous relaxation behavior can emerge in integrable quantum systems.

DOI: 10.48550/arxiv.2604.05408

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The Mpemba effect, broadly understood as the counterintuitive phenomenon in which a system initially farther from equilibrium relaxes faster than a system closer to equilibrium, has been widely studied in classical stochastic systems and, more recently, in quantum settings. However, its manifestation is strongly dependent on the choice of observable and the dynamical constraints of the system. In this work, we investigate the emergence of a Mpemba-type effect in the density redistribution dynamics of a strongly interacting one-dimensional Bose gas in the Tonks-Girardeau regime undergoing a sudden box expansion from length L_0 to L. By defining a physically motivated distance function based on the difference of densities between spatial regions, we provide evidence that -the relaxation dynamics of the ground and excited symmetry sectors exhibit a clear crossing in time, indicating a reversal in relaxation ordering. We emphasize that the Mpemba effect is not a universal law but rather an observable-dependent phenomenon that arises under specific dynamical conditions. In particular, we show that the interplay between initial state structure, integrability, and spatial redistribution leads to distinct relaxation pathways that enable the effect. Our results clarify common misconceptions linking the Mpemba effect to Newton's law of cooling and highlight the conditions under which such anomalous relaxation behavior can emerge in integrable quantum systems.

The Mpemba effect (MpE), where a far-from-equilibrium state of a system relaxes faster compared to a state closer to it, is a well-known counterintuitive phenomenon in classical and quantum systems. Various system-specific theories have been proposed to explain this anomalous behavior in driven systems, though the fundamental mechanism of MpE in undriven systems, where MpE was first observed, remains unresolved. This paper provides a generic model of MpE for a quantum spin-

1/2

system following Markovian relaxation dynamics, regardless of system structure or environment. The key lies in the overlap of initial states with the fast relaxation mode; here, the constituents create a fast decay mode via interaction through the shared environment to show MpE, indicating that MpE happens due to the collective behavior of the system. I also show that a system with anisotropic relaxation naturally exhibits MpE, even without a shared environment among the particles.

The Mpemba effect, where a system initially farther from equilibrium relaxes faster than one closer to equilibrium, has been extensively studied in classical systems and recently explored in quantum settings. While previous studies of the quantum Mpemba effect (QME) have largely focused on isolated systems with global symmetries, we argue that the QME is ubiquitous in generic, nonintegrable many-body systems lacking such symmetries, including U(1) charge conservation, spatial symmetries, and even energy conservation. Using paradigmatic models such as the quantum Ising model with transverse and longitudinal fields, we show that the QME can be understood through the energy density of initial states and their inverse participation ratio in the energy eigenbasis. Our findings provide a unified framework for the QME, linking it with classical thermal relaxation.

The quantum Mpemba effect refers to the counterintuitive phenomenon in which a system initially farther from equilibrium relaxes faster than one prepared closer to it. Several mechanisms have been identified in open quantum systems to explain this behavior, including the strong Mpemba effect, non-Markovian memory, and initial system-reservoir entanglement. Here, we unveil a distinct mechanism rooted in the non-normal nature of the Liouvillian superoperator in Markovian dynamics. When the Liouvillian's eigenmodes are non-orthogonal, transient interference between decaying modes can induce anomalous early-time behavior-such as delayed thermalization or transient freezing-even though asymptotic decay rates remain unchanged. This differs fundamentally from strong Mpemba effects, which hinge on suppressed overlap with slow-decaying modes. We demonstrate this mechanism using a waveguide quantum electrodynamics model, where quantum emitters interact with the photonic modes of a one-dimensional waveguide. The directional and radiative nature of these couplings naturally introduces non-normality into the system's dynamics. As a result, certain initial states-despite being closer to equilibrium-can exhibit slower relaxation at short times. This work reveals a previously unexplored and universal source of Mpemba-like behavior in memoryless quantum systems, expanding the theoretical framework for anomalous relaxation and opening new avenues for control in engineered quantum platforms.

We investigate the quantum Mpemba effect, whereby a system initially farther from equilibrium relaxes faster than one initially closer to equilibrium, emerging in a quantum harmonic oscillator linearly coupled to a bosonic environment. Starting from factorized thermal states at different temperatures, we derive exact analytical criteria for the occurrence of the quantum Mpemba effect valid also beyond the typically considered weak-coupling and Markovian approximations. Most importantly, we show that the effect is enabled by the initial-slip dynamics generated by the sudden switch-on of the system-bath interaction. Neglecting this contribution completely suppresses the anomalous relaxation, identifying transient system-bath correlations as the key ingredient underlying the quantum Mpemba effect.

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The highly complicated nature of far from equilibrium systems can lead to a complete breakdown of the physical intuition developed in equilibrium. A famous example of this is the Mpemba effect, which states that nonequilibrium states may relax faster when they are further from equilibrium or, put another way, hot water can freeze faster than warm water. Despite possessing a storied history, the precise criteria and mechanisms underpinning this phenomenon are still not known. Here, we study a quantum version of the Mpemba effect that takes place in closed many-body systems with a U(1) conserved charge: in certain cases a more asymmetric initial configuration relaxes and restores the symmetry faster than a more symmetric one. In contrast to the classical case, we establish the criteria for this to occur in arbitrary integrable quantum systems using the recently introduced entanglement asymmetry. We describe the quantum Mpemba effect in such systems and relate the properties of the initial state, specifically its charge fluctuations, to the criteria for its occurrence. These criteria are expounded using exact analytic and numerical techniques in several examples, a free fermion model, the Rule 54 cellular automaton, and the Lieb-Liniger model.