ABSTRACT A theoretical framework is introduced for deriving expressions for electromagnetic (EM) potentials and fields of single atomic or molecular emitters modeled as oscillating dipoles, which follows a recently developed method to solve inhomogeneous wave equations for time‐dependent distributions of charge. This framework is first used to evaluate the physical implications of the simplifying assumptions made in the standard approach to the quantization of EM fields and the impact of such assumptions on the predicted energy and momentum quantization. Then, the exact relationships between the potentials and the oscillating (transition) dipole properties derived under the present framework are used to quantize EM fields radiated by single emitters and to achieve agreement with the classical dipole radiation pattern, while maintaining the quantum mechanical description of electromagnetic radiation in terms of the probability distribution of quantum modes. Contributions of the present analysis to the understanding of photon emission from excited atoms or molecules stimulated by light or vacuum field fluctuations are highlighted, and possible experimental tests and practical applications are proposed.
ABSTRACT A theoretical framework is introduced for deriving expressions for electromagnetic (EM) potentials and fields of single atomic or molecular emitters modeled as oscillating dipoles, which follows a recently developed method to solve inhomogeneous wave equations for time‐dependent distributions of charge. This framework is first used to evaluate the physical implications of the simplifying assumptions made in the standard approach to the quantization of EM fields and the impact of such assumptions on the predicted energy and momentum quantization. Then, the exact relationships between the potentials and the oscillating (transition) dipole properties derived under the present framework are used to quantize EM fields radiated by single emitters and to achieve agreement with the classical dipole radiation pattern, while maintaining the quantum mechanical description of electromagnetic radiation in terms of the probability distribution of quantum modes. Contributions of the present analysis to the understanding of photon emission from excited atoms or molecules stimulated by light or vacuum field fluctuations are highlighted, and possible experimental tests and practical applications are proposed.
Abstract One of the greatest successes in quantum theory, and certainly one of the more important parts for application to devices and applications is the prediction of the emission of light through the quantization of an electromagnetic field. Broadly, this is the field of quantum electrodynamics. In this chapter, we develop the Hamiltonian for the classical electromagnetic field. It is seen that the Hamiltonian for each mode (identified by the k-vector and polarization of the field) of the plane wave electromagnetic field is identical to that of the harmonic oscillator. One unit of energy, ℏω, in a mode is a called a photon. The eigenkets for the system are number states (Fock states). We then consider a two-level system described by a Hamiltonian which couples the two-level quantum system to the quantized electromagnetic field. Using the Weisskopf–Wigner formalism developed in Chapter 14, we solve the equations of motion for the time dependent Schrödinger equation assuming the system starts in the excited state with no radiation present in the vacuum field. The results show the creation of one unit of energy in an electromagnetic mode corresponding to the emission of a photon. The excited state probability decays exponentially with the emission of this photon. We consider the important and special case of such a two-level system but in a cavity restricting the radiation field to a single mode. The Jaynes–Cummings Hamiltonian shows that this system, if started in the excited state, Rabi oscillates with no radiation incident on the system.
We will begin our journey through the background of quantum optics with an elementary, but quantitative, classical theory of radiative fields.Wewill first briefly outline the electromagnetic (EM) theory of radiation, and describe how the EM radiation may be understood as a wavewhich can be represented by a set of harmonic oscillators. We shall describe how the free or non-interacting EM field may be understood as a collection of harmonic oscillators which is quantized in the standard manner, and whose energy cannot be zero as a consequence of the basic non-commutability of the canonical field variables. This chapter discusses the properties of plane EM waves and normalization of the EM field in one dimension. This is followed by a description of the Hamiltonian and the amplitudes of the EM field in terms of the annihilation and creation operators. Based on this chapter, it is possible to considerably simplify the formulation of the physical basis for the mathematical description of the major problems of quantum optics.
Canonical quantization of the electromagnetic (EM) field is carried out for the situation where the total charge and current densities are the sum of contributions from neutral dielectric atoms whose effect is to be described purely classically in terms of spatially dependent electric permittivity and magnetic permeability functions, and neutral, stationary radiative atoms whose interaction with the EM field is to be treated quantum mechanically. The coefficients for the expansion of the vector potential in terms of mode functions determined from a generalized Helmholtz equation are chosen as independent generalized coordinates for the EM field. The spatially dependent electric permittivity and magnetic permeability appear in a generalized Helmholtz's equation and the former also occurs in the mode function orthogonality and normalization conditions. The quantum Hamiltonian is derived in a generalized multipolar form rather than the minimal coupling form obtained in other work. The radiative energy is the sum of quantum harmonic oscillator terms, one for each mode. The modes are independent in the present case of exact mode functions associated with the spatially dependent electric permittivity and magnetic permeability, there being no direct mode-mode coupling terms. In the electric dipole approximation the electric interaction energy contribution for each mode and radiative atom is proportional to the scalar product of the dipole operator with the mode function evaluated at the atom, times the annihilation operator, plus the Hermitian adjoint. This form has been widely used in studies of radiative processes for atomic systems in dielectric media, and it is justified here via the canonical quantization procedure. The results apply to the theoretical treatment of numerous quantum optical experiments involving such interactions in the presence of passive, lossless, dispersionless, linear classical optics devices such as resonator cavities, lenses, beam splitters, and so on. An illustrative application of the theory for atomic decay in a one-dimensional Fabry-Perot cavity is given. \textcopyright{} 1996 The American Physical Society.
Canonical quantization of the electromagnetic (EM) field is carried out for the situation where the total charge and current densities are the sum of contributions from neutral dielectric atoms whose effect is to be described purely classically in terms of spatially dependent electric permittivity and magnetic permeability functions, and neutral, stationary radiative atoms whose interaction with the EM field is to be treated quantum mechanically. The coefficients for the expansion of the vector potential in terms of mode functions determined from a generalized Helmholtz equation are chosen as independent generalized coordinates for the EM field. The spatially dependent electric permittivity and magnetic permeability appear in a generalized Helmholtz's equation and the former also occurs in the mode function orthogonality and normalization conditions. The quantum Hamiltonian is derived in a generalized multipolar form rather than the minimal coupling form obtained in other work. The radiative energy is the sum of quantum harmonic oscillator terms, one for each mode. The modes are independent in the present case of exact mode functions associated with the spatially dependent electric permittivity and magnetic permeability, there being no direct mode-mode coupling terms. In the electric dipole approximation the electric interaction energy contribution for each mode and radiative atom is proportional to the scalar product of the dipole operator with the mode function evaluated at the atom, times the annihilation operator, plus the Hermitian adjoint. This form has been widely used in studies of radiative processes for atomic systems in dielectric media, and it is justified here via the canonical quantization procedure. The results apply to the theoretical treatment of numerous quantum optical experiments involving such interactions in the presence of passive, lossless, dispersionless, linear classical optics devices such as resonator cavities, lenses, beam splitters, and so on. An illustrative application of the theory for atomic decay in a one-dimensional Fabry-Perot cavity is given. \textcopyright{} 1996 The American Physical Society.
Abstract The present chapter is devoted to a description of the procedure by which quantum mechanics is applied to the electromagnetic field. We obtain expressions for the operators that represent the field observables and we examine some of their properties. The quantization introduces characteristic quantum-mechanical effects into the properties of the radiation field, for example field operators that do not commute with each other and thus represent incompatible measured quantities. The Hamiltonian of the coupled radiation-atomic system is expressed wholly in terms of quantum-mechanical operators. We show that the full quantum theory of the interaction between the radiation field and atoms produces the same transition rates for absorption and stimulated emission as does the semiclassical theory. The rate of spontaneous emission confirms that obtained from the phenomenological Einstein theory. The treatment of absorption of radiation by atoms also identifies the quantum-mechanical operator that represents a measurement of the energy or intensity of a light beam, and this has important consequences for the descriptions of the experiments that can be performed in practice.
In this chapter a quantum mechanical treatment of atomic response to the fields of an electromagnetic wave is presented. Absorption and emission of energy by atoms involves transition between their quantized energy levels driven by an interaction Hamiltonian. Schrodinger equation is used to derive the equations of motion for the density matrix of the atom, which is better suited to include the effects of mechanisms other than the interaction Hamiltonian – collisions, level decays, level shifts, etc. that also affect the state of the atom. Using the density matrix equation of motion and focusing on two atomic levels, induced dipole moment for a single two-level atom and polarization and susceptibility for a collection of two-level atoms, including the effects of level decays, and collisions, are calculated. Equations of motion for level populations are also derived. These expressions naturally predict stimulated emission as well as absorption. Expressed in terms of spontaneous emission rate they confirm the validity of equations derived in Chapter 5 using the dipole oscillator model of atomic response. The limit in which quantum mechanical equations for atomic response reduce to the classical dipole oscillator equations is also discussed.