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Quantum Radiation Field: Spontaneous Emission and Entangled Photons

Duncan G. Steel

Published Apr 30, 2021• 0 citations
Publisher

Abstract

Abstract One of the greatest successes in quantum theory, and certainly one of the more important parts for application to devices and applications is the prediction of the emission of light through the quantization of an electromagnetic field. Broadly, this is the field of quantum electrodynamics. In this chapter, we develop the Hamiltonian for the classical electromagnetic field. It is seen that the Hamiltonian for each mode (identified by the k-vector and polarization of the field) of the plane wave electromagnetic field is identical to that of the harmonic oscillator. One unit of energy, ℏω, in a mode is a called a photon. The eigenkets for the system are number states (Fock states). We then consider a two-level system described by a Hamiltonian which couples the two-level quantum system to the quantized electromagnetic field. Using the Weisskopf–Wigner formalism developed in Chapter 14, we solve the equations of motion for the time dependent Schrödinger equation assuming the system starts in the excited state with no radiation present in the vacuum field. The results show the creation of one unit of energy in an electromagnetic mode corresponding to the emission of a photon. The excited state probability decays exponentially with the emission of this photon. We consider the important and special case of such a two-level system but in a cavity restricting the radiation field to a single mode. The Jaynes–Cummings Hamiltonian shows that this system, if started in the excited state, Rabi oscillates with no radiation incident on the system.

DOI
10.1093/oso/9780192895073.003.0015

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Proceedings of the National Academy of Sciences•Mar 16, 2017•63 citations
Abstract One of the greatest successes in quantum theory, and certainly one of the more important parts for application to devices and applications is the prediction of the emission of light through the quantization of an electromagnetic field. Broadly, this is the field of quantum electrodynamics. In this chapter, we develop the Hamiltonian for the classical electromagnetic field. It is seen that the Hamiltonian for each mode (identified by the k-vector and polarization of the field) of the plane wave electromagnetic field is identical to that of the harmonic oscillator. One unit of energy, ℏω, in a mode is a called a photon. The eigenkets for the system are number states (Fock states). We then consider a two-level system described by a Hamiltonian which couples the two-level quantum system to the quantized electromagnetic field. Using the Weisskopf–Wigner formalism developed in Chapter 14, we solve the equations of motion for the time dependent Schrödinger equation assuming the system starts in the excited state with no radiation present in the vacuum field. The results show the creation of one unit of energy in an electromagnetic mode corresponding to the emission of a photon. The excited state probability decays exponentially with the emission of this photon. We consider the important and special case of such a two-level system but in a cavity restricting the radiation field to a single mode. The Jaynes–Cummings Hamiltonian shows that this system, if started in the excited state, Rabi oscillates with no radiation incident on the system.
The coupling of two or more quantum mechanical states representing two different quantum mechanical systems leads to a new class of quantum mechanical states called entangled states. In this case, a two level atom, coupled to a single mode quantized electromagnetic field, results in the dressed state. The Dressed State is an example of Entangled States. This state exhibits a quantum correlation between the two entities, atom and field. The interaction energy of the atom and the quantized field can be written, in the dipolar interaction case, in the same way as in the semi classical theory. The emission of a photon by an atom creates an electromagnetic field that can act with the atom itself. An atom in the excited state, in the absence of a field, decays exponentially with time. This is Wigner Weisskopf model for spontaneous emission.
Abstract Chapter 15 derived the fundamental theory and eigenstates for the quantized radiation field and then showed how the quantum vacuum gives rise to spontaneous emission. This chapter now goes more deeply into the meaning and implications of the quantized field. The polarization of a photon can be used as a qubit and the photonic qubit is called a flying qubit. It enables transmission of information from one node to another. Spontaneous emission is shown to enable creation of an entangled state between a photonic qubit and the spin of an electron. Spontaneous emission can also degrade the performance of some device designs and in other devices it can enhance performance such as for a single photon emitter. In this we show how to engineer the vacuum to control spontaneous emission.
This chapter reviews the classical description of radiation. It describes how classical electromagnetic radiation interacts with a quantum mechanical particle. The general rule is that, even though the wave functions and the electromagnetic potentials change with the gauge, all physically observable quantities are independent of the gauge. The chapter also describes the process of the absorption of light by a system in terms of the effect of an external classical electromagnetic field on the system. The total emission rate is the sum of the induced and the spontaneous rates. Spontaneous emission is just the quantum mechanical version of the classical phenomenon of radiation from an accelerating charge. A very important consequence of the fact that the electromagnetic field is quantized is that there are vacuum fluctuations of the field, analogous to the zero point motion of a harmonic oscillator. Einstein gave a simple statistical argument to determine the rate at which spontaneous emission takes place.
Introduction The preceding chapters have focused on atomic transitions induced by applied radiation. That is, there is an optical field illuminating the atoms, and their response is calculated. It is implicitly assumed that an excited atom left alone will spontaneously return to the ground state, and conserve energy by emitting light that satisfies E 2 − E 1 = ħ ω 21 in accordance with the Planck and Bohr pictures. But this spontaneous emission process is not addressed quantitatively in these earlier chapters. Spontaneous emission is one of the most pervasive phenomena of atomic physics, and yet its origins remain among the least well-understood. The number of misconceptions is enormous, and they are to be found in textbooks, journal articles, and lecture notes. Because the natural decay of an excited atom adds energy to what is usually an empty mode of the electromagnetic field, the process is fundamentally quantum mechanical. Classical or even semi-classical descriptions cannot be assured to give correct answers. This is not to say that such discussion is to be avoided, but only that caution is needed in interpreting the results. Toward the end of the nineteenth century, many experimental results made it clear that classical mechanics needed to be supplemented by new theories. The first venture into the new physics was Planck's hypothesis that the energy of classical radiating oscillators like those discussed in Chap. 1 would have to be quantized into integer multiples of ħ ω. This notion led to his famous formula for the spectrum of thermal radiation from a non-reflective object (black body), and this formula describes a radiation field in thermodynamic equilibrium with its environment. The result of Planck's hypothesis in the context of thermal equilibrium plays a vital role in the discussion of spontaneous emission. Einstein A - and B -coefficients Soon after Bohr proposed a model of atomic structure consisting of discrete energy levels, connected by radiation whose energy satisfied Δ E = ħω when atoms made transition between them, Einstein published the first serious attempt to connect the absorption and emission processes. Absorption, he reasoned, could occur only in the presence of applied radiation, whereas spontaneous decay occurred without the application of any field.
In this chapter a quantum mechanical treatment of atomic response to the fields of an electromagnetic wave is presented. Absorption and emission of energy by atoms involves transition between their quantized energy levels driven by an interaction Hamiltonian. Schrodinger equation is used to derive the equations of motion for the density matrix of the atom, which is better suited to include the effects of mechanisms other than the interaction Hamiltonian – collisions, level decays, level shifts, etc. that also affect the state of the atom. Using the density matrix equation of motion and focusing on two atomic levels, induced dipole moment for a single two-level atom and polarization and susceptibility for a collection of two-level atoms, including the effects of level decays, and collisions, are calculated. Equations of motion for level populations are also derived. These expressions naturally predict stimulated emission as well as absorption. Expressed in terms of spontaneous emission rate they confirm the validity of equations derived in Chapter 5 using the dipole oscillator model of atomic response. The limit in which quantum mechanical equations for atomic response reduce to the classical dipole oscillator equations is also discussed.
It was first realized by Purcell (1) that the spontaneous emission rate of a quantum system can be enhanced or suppressed by placing it in a resonant radiofrequency cavity. Spontaneous emission as it was first theoretically described by Einstein (2) is not a pure property of matter. It is described by matter coupled to quantized radiation field modes, which can be manipulated in an artificial structure such as a cavity. Cavity quantum electrodynamics (QED) is used to describe such effects that intimately depend on the fact that light is made of photons. Cavity QED has been extensively studied in atoms and the experimental proof was awarded with the Nobel Prize in 2012 (3). It has been applied to cooling of single atoms and for the detection of single atoms and creating and studying states with few photons and few atoms (4). In more recent developments these ideas have been extended to manipulate electronic states (5) and vibrations in molecules (6, 7). In PNAS, Flick et al. (8) introduce recent theoretical developments for the application of cavity QED to molecules and suggest possible novel applications to photochemistry. These include nonadiabatic dynamics of molecules in cavities, the modification of molecular properties, and the integration of QED with density functional theory. A quantized electromagnetic field mode can be described as a harmonic oscillator whose coordinate is the electric field displacement (Fig. 1 A ). The zero point energy translates into a nonvanishing field intensity ⟨ e 2 ⟩ in the ground state | 0 ⟩ (vacuum fluctuations). The electric vacuum field increases for a small cavity volume e c = ℏ ω c V ϵ 0 , [1] Fig. 1. ( A ) Illustration of the standing wave cavity mode and the resulting field quantization (Fock states). ( B ) Combined matter-field states (dressed states, | ± , n ⟩ … [↵][1]1To whom correspondence should be addressed. Email: smukamel{at}uci.edu. [1]: #xref-corresp-1-1