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CRC Press eBooks

Quantum Theory of Atom Field Interaction

Pradip Narayan Ghosh

Published Feb 19, 2018• 0 citations
Publisher

Abstract

The coupling of two or more quantum mechanical states representing two different quantum mechanical systems leads to a new class of quantum mechanical states called entangled states. In this case, a two level atom, coupled to a single mode quantized electromagnetic field, results in the dressed state. The Dressed State is an example of Entangled States. This state exhibits a quantum correlation between the two entities, atom and field. The interaction energy of the atom and the quantized field can be written, in the dipolar interaction case, in the same way as in the semi classical theory. The emission of a photon by an atom creates an electromagnetic field that can act with the atom itself. An atom in the excited state, in the absence of a field, decays exponentially with time. This is Wigner Weisskopf model for spontaneous emission.

DOI
10.1201/9780429492396-7

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The coupling of two or more quantum mechanical states representing two different quantum mechanical systems leads to a new class of quantum mechanical states called entangled states. In this case, a two level atom, coupled to a single mode quantized electromagnetic field, results in the dressed state. The Dressed State is an example of Entangled States. This state exhibits a quantum correlation between the two entities, atom and field. The interaction energy of the atom and the quantized field can be written, in the dipolar interaction case, in the same way as in the semi classical theory. The emission of a photon by an atom creates an electromagnetic field that can act with the atom itself. An atom in the excited state, in the absence of a field, decays exponentially with time. This is Wigner Weisskopf model for spontaneous emission.
Abstract One of the greatest successes in quantum theory, and certainly one of the more important parts for application to devices and applications is the prediction of the emission of light through the quantization of an electromagnetic field. Broadly, this is the field of quantum electrodynamics. In this chapter, we develop the Hamiltonian for the classical electromagnetic field. It is seen that the Hamiltonian for each mode (identified by the k-vector and polarization of the field) of the plane wave electromagnetic field is identical to that of the harmonic oscillator. One unit of energy, ℏω, in a mode is a called a photon. The eigenkets for the system are number states (Fock states). We then consider a two-level system described by a Hamiltonian which couples the two-level quantum system to the quantized electromagnetic field. Using the Weisskopf–Wigner formalism developed in Chapter 14, we solve the equations of motion for the time dependent Schrödinger equation assuming the system starts in the excited state with no radiation present in the vacuum field. The results show the creation of one unit of energy in an electromagnetic mode corresponding to the emission of a photon. The excited state probability decays exponentially with the emission of this photon. We consider the important and special case of such a two-level system but in a cavity restricting the radiation field to a single mode. The Jaynes–Cummings Hamiltonian shows that this system, if started in the excited state, Rabi oscillates with no radiation incident on the system.
We investigate (non-relativistic) atomic systems interacting with quantum electromagnetic field (QEF). The resulting model describes spontaneous emission of light from a two-level atom surrounded by various initial states of the QEF. We assume that the quantum field interacts with the atom via the standard, minimal-coupling Hamiltonian, with the A2 term neglected. We also assume that there will appear at most single excitations (photons). By conducting the analysis on a general level we allow for an arbitrary initial state of the QEF (which can be for instance: the vacuum, the ground state in a cavity, or the squeezed state). We derive a Volterra-type equation which governs the time evolution of the amplitude of the excited state. The two-point function of the initial state of the QEF, integrated with a combination of atomic wavefunctions, forms the kernel of this equation.
This chapter considers an atom as a quantum mechanical system. But the electromagnetic radiation will be treated as classical waves described by the Maxwell equations. The treatment is called semi-classical. Quantum mechanics describes an atom as a quantized system with a set of discrete energy levels. Each energy level is designated by a set of quantum numbers like the principal quantum of the Rydberg level and the quantum numbers representing the orbital, spin and total angular momentum. A molecule will have a different set of quantum numbers arising from its rotational and vibrational motions. Atoms in a solid have energy levels in the form of a band. The observed spectrum due to spontaneous emission from a collection of atoms is not monochromatic, but it is spread over a certain range of frequencies. The absorption spectrum also shows that the atom does not absorb at a single frequency, but it is spread over a band of frequencies around the resonance frequency.
In this chapter, we discuss a purely quantum approach to the interaction between an atom and the electromagnetic field. In this treatment, the atom and electromagnetic field form a single quantum system, whose evolution is handled globally within a unified formalism. This will thus have the merit of being fully consistent from the theoretical standpoint. But the main advantage in an entirely quantum approach is that it can treat the full range of matter–radiation interaction phenomena. In particular, it provides a rigorous description of the spontaneous emission of light by an excited atom , something that falls outside the scope of the semi-classical framework applied in Chapters 2 and 3, where the lifetime of an excited atomic state had to be fed in phenomenologically. It can describe other phenomena of the same type, such as parametric fluorescence by a nonlinear crystal subjected to pumping radiation (see Chapter 7), which underlies many recent developments in quantum optics. The fully quantum approach also has the merit of allowing a simple interpretation in terms of photons for the various matter–radiation interaction processes, such as absorption, stimulated emission, scattering, and also the basic processes of nonlinear optics. Indeed, it provides a unified framework for both stimulated and spontaneous processes. Finally, it can be used to tackle completely new situations where matter and radiation interact, which lie outside the scope of any semi-classical description, such as cavity quantum electrodynamics or the production of single-photon or entangled-photons states .
Abstract We investigate (non‐relativistic) atomic systems interacting with quantum electromagnetic field (QEF). The resulting model describes spontaneous emission of light from a two‐level atom surrounded by various initial states of the QEF. We assume that the quantum field interacts with the atom via the standard, minimal‐coupling Hamiltonian, with the A2 term neglected. We also assume that there will appear at most single excitations (photons). By conducting the analysis on a general level we allow for an arbitrary initial state of the QEF (which can be for instance: the vacuum, the ground state in a cavity, or the squeezed state). We derive a Volterra‐type equation which governs the time evolution of the amplitude of the excited state. The two‐point function of the initial state of the QEF, integrated with a combination of atomic wavefunctions, forms the kernel of this equation.
We present a theory of two-photon resonance fluorescence of an atom or molecule in which the excitation by an external electromagnetic field as well as fluorescence emission is mediated by two-photon processes. The treatment is based on first dressing the atom or molecule by the external field and then evaluating perturbatively the effect of the interaction with the vacuum or fluorescent field and so resonance fluorescence can be considered as spontaneous emission from the dressed atom. The introduction of the combined system of atom and external field via dressed states leads to simpler calculations and more transparent physics. The fluorescence spectrum derived by us has similarities as well as differences with that of one-photon resonance fluorescence and earlier theoretical predictions for the two-photon case.