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arXiv:2311.08486 · Scientific Reports

Emergence of opposing arrows of time in open quantum systems

Thomas Guff, Chintalpati Umashankar Shastry, Andrea Rocco

Published Jan 29, 2025• 13 citations
arXivHTMLPDF

Abstract

Deriving an arrow of time from time-reversal symmetric microscopic dynamics is a fundamental open problem in many areas of physics, ranging from cosmology, to particle physics, to thermodynamics and statistical mechanics. Here we focus on the derivation of the arrow of time in open quantum systems and study precisely how time-reversal symmetry is broken. This derivation involves the Markov approximation applied to a system interacting with an infinite heat bath. We find that the Markov approximation does not imply a violation of time-reversal symmetry. Our results show instead that the time-reversal symmetry is maintained in the derived equations of motion. This imposes a time-symmetric formulation of quantum Brownian motion, Lindblad and Pauli master equations, which hence describe thermalisation that may occur into two opposing time directions. As a consequence, we argue that these dynamics are better described by a time-symmetric definition of Markovianity. Our results may reflect on the formulations of the arrow of time in thermodynamics, cosmology, and quantum mechanics.

DOI
10.1038/s41598-025-87323-x

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Deriving an arrow of time from time-reversal symmetric microscopic dynamics is a fundamental open problem in many areas of physics, ranging from cosmology, to particle physics, to thermodynamics and statistical mechanics. Here we focus on the derivation of the arrow of time in open quantum systems and study precisely how time-reversal symmetry is broken. This derivation involves the Markov approximation applied to a system interacting with an infinite heat bath. We find that the Markov approximation does not imply a violation of time-reversal symmetry. Our results show instead that the time-reversal symmetry is maintained in the derived equations of motion. This imposes a time-symmetric formulation of quantum Brownian motion, Lindblad and Pauli master equations, which hence describe thermalisation that may occur into two opposing time directions. As a consequence, we argue that these dynamics are better described by a time-symmetric definition of Markovianity. Our results may reflect on the formulations of the arrow of time in thermodynamics, cosmology, and quantum mechanics.
It is one of the most important and long-standing issues of physics to derive the irreversibility out of a time-reversal symmetric equation of motion. The present paper considers the breaking of the time-reversal symmetry in open quantum systems and the emergence of an arrow of time. We claim that the time-reversal symmetric Schrödinger equation can have eigenstates that break the time-reversal symmetry if the system is open in the sense that it has at least a countably infinite number of states. Such eigenstates, namely the resonant and anti-resonant states, have complex eigenvalues. We show that, although these states are often called "unphysical", they observe the probability conservation in a particular way. We also comment that the seemingly Hermitian Hamiltonian is non-Hermitian in the functional space of the resonant and anti-resonant states, and hence there is no contradiction in the fact that it has complex eigenvalues. We finally show how the existence of the states that break the time-reversal symmetry affects the quantum dynamics. The dynamics that starts from a time-reversal symmetric initial state is dominated by the resonant states for t > 0 ; this explains the phenomenon of the arrow of time, in which the decay excels the growth. The time-reversal symmetry holds in that the dynamic ending at a time-reversal symmetric final state is dominated by the anti-resonant states for t < 0 .
The Markov approximation is arguably the most ubiquitous tool in physics, underpinning quantum master equations, stochastic processes, and -- via Shannon's channel model and Lamport's logical clocks -- the foundational assumptions of distributed computing. It is widely assumed that Markovianity inherently implies temporal asymmetry: that the Markov property is a forward-in-time-only (FITO) construct. We show that this assumption is a category mistake in the sense of Ryle (1949). Guff, Shastry, and Rocco (2025) have recently demonstrated that the Markov approximation applied to the Caldeira-Leggett model -- a paradigmatic open quantum system -- maintains time-reversal symmetry in the derived equations of motion. The resulting time-symmetric formulations of quantum Brownian motion, Lindblad master equations, and Pauli master equations describe thermalisation that can occur in two opposing temporal directions. Asymmetry arises not from the dynamics but from boundary conditions. We trace how Markovianity's assumed directionality propagated from physics through Shannon's information theory to Lamport's happens-before relation and the impossibility theorems of distributed computing (FLP, CAP, Two Generals). Each step encodes FITO as convention, then treats it as physical law -- the same category mistake repeated across domains. The Surrey result establishes that this conflation is not merely philosophically suspect but mathematically unnecessary: the most fundamental approximation used to derive irreversibility is itself time-symmetric.
This paper presents a unified formulation of the origin of the arrow of time in classical and quantum mechanics. We begin with a mechanical analysis of a one-dimensional three-particle system, which provides a concrete example in which macroscopic irreversibility emerges despite microscopically reversible dynamics. By abstracting this mechanism, we identify coarse-graining as the essential ingredient responsible for macroscopic time asymmetry. We then formulate a general structural criterion for the thermodynamic arrow of time. We show that when microscopic time evolution forms a group while the induced macroscopic evolution forms only a semigroup, macroscopic time-reversal symmetry is necessarily broken. We prove that this semigroup structure arises if and only if the coarse-graining map from microscopic to macroscopic states is non-injective. This result holds independently of whether the underlying system is classical or quantum. In the quantum case, using density matrices, antiunitary time reversal, and CPTP coarse-graining maps, we show that macroscopic irreversibility follows inevitably from information loss, without requiring any asymmetry in the microscopic laws. Our results demonstrate that the thermodynamic arrow of time has a universal structural origin: the loss of microscopic information inherent in coarse-graining.
Within the general formalism of quantum theory irreversibility and the arrow of time and the in the evolution of various physical systems are studied. Irreversible behavior often manifests itself in the guise of “entropy production.” This motivates me to begin this chapter with a brief review of quantum-mechanical entropy, a subject that Elliott Lieb has made outstanding contributions to, followed by an enumeration of examples of irreversible behavior and of an arrow of time analyzed in later sections. Subsequently, a derivation of the laws of thermodynamics from (quantum) statistical mechanics, and, in particular, of the Second Law of thermodynamics, in the forms given to it by Clausius and Carnot, is presented. In a third part, results on diffusive (Brownian) motion of a quantum particle interacting with a quasi-free quantum-mechanical heat bath are reviewed. This is followed by an outline of a theory of friction by emission of Cherenkov radiation of sound waves in a system consisting of a particle moving through a Bose–Einstein condensate and interacting with it. In what may be the most important section of this chapter, the fundamental arrow of time inherent in Quantum Mechanics is discussed.
It is brought forward that viable theories of the physical world that have no variable at all that can play the role of time, do not exist; some notion of time is one of the very first ingredients a candidate theory should possess. Almost by definition, time has an arrow. In contrast, time reversibility, or even the possibility to run the equations of motion backwards in time, is not at all a primary requirement. This means that the direction of the arrow of time may well be uniquely defined in the theory, even locally. It is explained that a rigorous definition of time, as well as a formulation of the causality and locality concepts, can only be given when one has a model for the physical phenomena described. The only viable causality condition is one that is symmetric under time reversal. We explain these statements in terms of the author’s favoured deterministic cellular automaton interpretation of quantum mechanics, also to be referred to as 'vector space analysis', and expand on these ideas. It is also summarised how our more rigorous causality condition affects Bell’s theorems. What distinguishes quantum systems from classical ones is our fundamental inability to control the microscopic details of the initial state when phenomena are studied in the light of some theoretical model.
Abstract Microscopic physical laws are time-symmetric, hence, a priori there exists no preferential temporal direction. However, the second law of thermodynamics allows one to associate the “forward” temporal direction to a positive variation of the total entropy produced in a thermodynamic process, and a negative variation with its “time-reversal” counterpart. This definition of a temporal axis is normally considered to apply in both classical and quantum contexts. Yet, quantum physics admits also superpositions between forward and time-reversal processes, whereby the thermodynamic arrow of time becomes quantum-mechanically undefined. In this work, we demonstrate that a definite thermodynamic time’s arrow can be restored by a quantum measurement of entropy production, which effectively projects such superpositions onto the forward (time-reversal) time-direction when large positive (negative) values are measured. Finally, for small values (of the order of plus or minus one), the amplitudes of forward and time-reversal processes can interfere, giving rise to entropy-production distributions featuring a more or less reversible process than either of the two components individually, or any classical mixture thereof.