Abstract Microscopic physical laws are time-symmetric, hence, a priori there exists no preferential temporal direction. However, the second law of thermodynamics allows one to associate the “forward” temporal direction to a positive variation of the total entropy produced in a thermodynamic process, and a negative variation with its “time-reversal” counterpart. This definition of a temporal axis is normally considered to apply in both classical and quantum contexts. Yet, quantum physics admits also superpositions between forward and time-reversal processes, whereby the thermodynamic arrow of time becomes quantum-mechanically undefined. In this work, we demonstrate that a definite thermodynamic time’s arrow can be restored by a quantum measurement of entropy production, which effectively projects such superpositions onto the forward (time-reversal) time-direction when large positive (negative) values are measured. Finally, for small values (of the order of plus or minus one), the amplitudes of forward and time-reversal processes can interfere, giving rise to entropy-production distributions featuring a more or less reversible process than either of the two components individually, or any classical mixture thereof.
Abstract Microscopic physical laws are time-symmetric, hence, a priori there exists no preferential temporal direction. However, the second law of thermodynamics allows one to associate the “forward” temporal direction to a positive variation of the total entropy produced in a thermodynamic process, and a negative variation with its “time-reversal” counterpart. This definition of a temporal axis is normally considered to apply in both classical and quantum contexts. Yet, quantum physics admits also superpositions between forward and time-reversal processes, whereby the thermodynamic arrow of time becomes quantum-mechanically undefined. In this work, we demonstrate that a definite thermodynamic time’s arrow can be restored by a quantum measurement of entropy production, which effectively projects such superpositions onto the forward (time-reversal) time-direction when large positive (negative) values are measured. Finally, for small values (of the order of plus or minus one), the amplitudes of forward and time-reversal processes can interfere, giving rise to entropy-production distributions featuring a more or less reversible process than either of the two components individually, or any classical mixture thereof.
A priori, there exists no preferential temporal direction as microscopic physical laws are time-symmetric. Still, the second law of thermodynamics allows one to associate the `forward' temporal direction to a positive entropy variation in a thermodynamic process, and a negative variation with its `time-reversal' counterpart. This definition of a temporal axis is normally considered to apply in both classical and quantum contexts. Yet, quantum physics admits also superpositions between forward and time-reversal processes, thereby seemingly eluding conventional definitions of time's arrow. In this work, we demonstrate that a quantum measurement of entropy can distinguish the two temporal directions, effectively projecting such superpositions of thermodynamic processes onto the forward (time-reversal) time-direction when large positive (negative) values are measured. Remarkably, for small values (of the order of plus or minus one), the amplitudes of forward and time-reversal processes can interfere, giving rise to entropy distributions featuring a more or less reversible process than either of the two components individually, or any classical mixture thereof. Finally, we extend these concepts to the case of a thermal machine running in a superposition of the heat engine and the refrigerator mode, illustrating how such interference effects can be employed to reduce undesirable fluctuations.
This study proposes a time-symmetric framework for quantum measurement that restores microscopic reversibility at the level of the dynamical description while remaining compatible with causality and thermodynamic consistency. Instead of invoking a stochastic wavefunction collapse, the measurement process is modeled as a bidirectional informational update between a forward-evolving state and a backward-propagating effect, governed by a completely positive generator and its adjoint. Within this operator-based formalism, pre- and post-selected statistics are treated on an equal footing, yielding a unified description of both. The proposed scheme rigorously preserves complete positivity, normalization, and the no-signalling principle, and it is shown to satisfy Spohn's inequality for the associated quantum Markov semigroup, thereby ensuring non-negative entropy production within this setting. The framework admits a direct experimental interpretation across a range of scenarios, including weak measurements, EPR-Bell tests, homodyne detection, and photon counting. Furthermore, in the classical limit, the bidirectional update is demonstrated to reduce to the well-established Kalman filter and Rauch-Tung-Striebel (RTS) smoother used in classical estimation theory. These results support the view that the apparent temporal asymmetry of quantum measurement arises not from fundamental dynamical irreversibility, but from informational conditioning, specifically, the one-sided way in which measurement outcomes are incorporated into our description. In this sense, the arrow of time in measurement theory may be understood as an arrow of information.
Irreversibility is one of the most intriguing concepts in physics. While microscopic physical laws are perfectly reversible, macroscopic average behavior has a preferred direction of time. According to the second law of thermodynamics, this arrow of time is associated with a positive mean entropy production. Using a nuclear magnetic resonance setup, we measure the nonequilibrium entropy produced in an isolated spin-1/2 system following fast quenches of an external magnetic field. We experimentally demonstrate that it is equal to the entropic distance, expressed by the Kullback-Leibler divergence, between a microscopic process and its time reversal. Our result addresses the concept of irreversibility from a microscopic quantum standpoint.
All the laws of physics are time-reversible. Time arrow emerges only when ensembles of classical particles are treated probabilistically, outside of physics laws, and the entropy and the second law of thermodynamics are introduced. In quantum physics, no mechanism for a time arrow has been proposed despite its intrinsic probabilistic nature. In consequence, one cannot explain why an electron in an excited state will "spontaneously" transition into a ground state as a photon is created and emitted, instead of continuing in its reversible unitary evolution. To address such phenomena, we introduce an entropy for quantum physics, which will conduce to the emergence of a time arrow. The entropy is a measure of randomness over the degrees of freedom of a quantum state. It is dimensionless; it is a relativistic scalar, it is invariant under coordinate transformation of position and momentum that maintain conjugate properties and under CPT transformations; and its minimum is positive due to the uncertainty principle. To excogitate why some quantum physical processes cannot take place even though they obey conservation laws, we partition the set of all evolutions of an initial state into four blocks, based on whether the entropy is (i) increasing but not a constant, (ii) decreasing but not a constant, (iii) a constant, (iv) oscillating. We propose a law that in quantum physics entropy (weakly) increases over time. Thus, evolutions in the set (ii) are disallowed, and evolutions in set (iv) are barred from completing an oscillation period by instantaneously transitioning to a new state. This law for quantum physics limits physical scenarios beyond conservation laws, providing causality reasoning by defining a time arrow.
The entropy production in dissipative processes is the essence of the arrow of time and the second law of thermodynamics. For dissipation of quantum systems, it was recently shown that the entropy production contains indeed two contributions: a classical one and a quantum one. Here we show that for degenerate (or near-degenerate) quantum systems there are additional quantum contributions which, remarkably, can become negative. Furthermore, such negative contributions are related to significant changes in the ongoing thermodynamics. This includes phenomena such as generation of coherences between degenerate energy levels (called horizontal coherences), alteration of energy exchanges, and, last but not least, reversal of the natural convergence of the populations toward the thermal equilibrium state. Going further, we establish a complementarity relation between horizontal coherences and population convergence, which is particularly enlightening for understanding heat flow reversals. Conservation laws of the different types of coherences are derived. Some consequences for thermal machines and resource theory of coherence are suggested.
We present a unified operational framework for the arrow of time grounded in irreversible information loss. While microscopic physical laws are time-reversal invariant, macroscopic irreversibility arises when systems overwrite metastable records. We show that recent reversible quantum-control experiments do not reverse time, but instead operate in regimes where no logically irreversible record is created. To formalize this, we introduce the **forgetting rate** (Ξcr), a coarse-grained rate defined on physically selected metastable record states (e.g., pointer states, memory registers, or macroscopic configurations). Unlike standard entropy production, which is expressed in terms of microscopic transition asymmetry, (Ξcr) captures the **rate of irreversible record overwriting**. In this formulation, entropy production obeys the lower boundS˙irr≥kBΞcr,consistent with Landauer's principle but expressed at the level of record dynamics. Within this framework, thermodynamic, quantum-measurement, psychological, and cosmological arrows emerge as substrate-dependent manifestations of Ξcr>0. Temporal asymmetry is therefore not a single global property, but a distributed feature of physical information-processing systems. The approach naturally explains the decoupling of arrows in composite systems and identifies experimentally accessible regimes where irreversibility can be locally suppressed. This work does not introduce a new microscopic law but provides a unifying, operational reformulation that connects information thermodynamics, decoherence theory, and memory dynamics through a single coarse-grained rate.