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arXiv:2103.07996

Quantum-Entropy Physics

Davi Geiger, Zvi M. Kedem

Published Mar 14, 2021• 2 citations
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Abstract

All the laws of physics are time-reversible. Time arrow emerges only when ensembles of classical particles are treated probabilistically, outside of physics laws, and the entropy and the second law of thermodynamics are introduced. In quantum physics, no mechanism for a time arrow has been proposed despite its intrinsic probabilistic nature. In consequence, one cannot explain why an electron in an excited state will "spontaneously" transition into a ground state as a photon is created and emitted, instead of continuing in its reversible unitary evolution. To address such phenomena, we introduce an entropy for quantum physics, which will conduce to the emergence of a time arrow. The entropy is a measure of randomness over the degrees of freedom of a quantum state. It is dimensionless; it is a relativistic scalar, it is invariant under coordinate transformation of position and momentum that maintain conjugate properties and under CPT transformations; and its minimum is positive due to the uncertainty principle. To excogitate why some quantum physical processes cannot take place even though they obey conservation laws, we partition the set of all evolutions of an initial state into four blocks, based on whether the entropy is (i) increasing but not a constant, (ii) decreasing but not a constant, (iii) a constant, (iv) oscillating. We propose a law that in quantum physics entropy (weakly) increases over time. Thus, evolutions in the set (ii) are disallowed, and evolutions in set (iv) are barred from completing an oscillation period by instantaneously transitioning to a new state. This law for quantum physics limits physical scenarios beyond conservation laws, providing causality reasoning by defining a time arrow.

DOI
10.48550/arxiv.2103.07996

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All the laws of physics are time-reversible. Time arrow emerges only when ensembles of classical particles are treated probabilistically, outside of physics laws, and the entropy and the second law of thermodynamics are introduced. In quantum physics, no mechanism for a time arrow has been proposed despite its intrinsic probabilistic nature. In consequence, one cannot explain why an electron in an excited state will "spontaneously" transition into a ground state as a photon is created and emitted, instead of continuing in its reversible unitary evolution. To address such phenomena, we introduce an entropy for quantum physics, which will conduce to the emergence of a time arrow. The entropy is a measure of randomness over the degrees of freedom of a quantum state. It is dimensionless; it is a relativistic scalar, it is invariant under coordinate transformation of position and momentum that maintain conjugate properties and under CPT transformations; and its minimum is positive due to the uncertainty principle. To excogitate why some quantum physical processes cannot take place even though they obey conservation laws, we partition the set of all evolutions of an initial state into four blocks, based on whether the entropy is (i) increasing but not a constant, (ii) decreasing but not a constant, (iii) a constant, (iv) oscillating. We propose a law that in quantum physics entropy (weakly) increases over time. Thus, evolutions in the set (ii) are disallowed, and evolutions in set (iv) are barred from completing an oscillation period by instantaneously transitioning to a new state. This law for quantum physics limits physical scenarios beyond conservation laws, providing causality reasoning by defining a time arrow.
Physical laws for elementary particles can be described by the quantum dynamics equation given a Hamiltonian. The solution are probability amplitudes in Hilbert space that evolve over time. A probability density function over position and time is given as the magnitude square of such probability amplitude. An entropy can be associated with these probability densities characterizing the position information of a particle. Coherent states are localized wave packets and may describe the spatial distribution for some particle states. We show that due to a dispersion property of Hamiltonians in quantum physics, the entropy of coherent states increases over time. We investigate a partition of the Hilbert space into four sets based on whether the entropy is (i) increasing but not a constant, (ii) decreasing but not a constant, (iii) a constant, (iv) oscillating. We propose a law that entropy (weakly) increases in time in quantum physics. Thus, states in set (ii) are disallowed, and the states in set (iii) cannot complete an oscillation period. Then, according to this law, quantum theory is not time-reversible unless the state is in set (iii), i.e., it is a stationary state (an eigenstate of the Hamiltonian.). This additional law in quantum theory limits physical scenarios beyond conservation laws, providing causality reasoning by defining an arrow of time.
Quantum physics, despite its intrinsically probabilistic nature, lacks a definition of entropy fully accounting for the randomness of a quantum state. For example, von Neumann entropy quantifies only the incomplete specification of a quantum state and does not quantify the probabilistic distribution of its observables; it trivially vanishes for pure quantum states. We propose a quantum entropy that quantifies the randomness of a pure quantum state via a conjugate pair of observables/operators forming the quantum phase space. The entropy is dimensionless, it is a relativistic scalar, it is invariant under canonical transformations and under CPT transformations, and its minimum has been established by the entropic uncertainty principle. We expand the entropy to also include mixed states. We show that the entropy is monotonically increasing during a time evolution of coherent states under a Dirac Hamiltonian. However, in a mathematical scenario, when two fermions come closer to each other, each evolving as a coherent state, the total system's entropy oscillates due to the increasing spatial entanglement. We hypothesize an entropy law governing physical systems whereby the entropy of a closed system never decreases, implying a time arrow for particle physics. We then explore the possibility that as the oscillations of the entropy must by the law be barred in quantum physics, potential entropy oscillations trigger annihilation and creation of particles.
Quantum physics, despite its intrinsically probabilistic nature, lacks a definition of entropy fully accounting for the randomness of a quantum state. For example, von Neumann entropy quantifies only the incomplete specification of a quantum state and does not quantify the probabilistic distribution of its observables; it trivially vanishes for pure quantum states. We propose a quantum entropy that quantifies the randomness of a pure quantum state via a conjugate pair of observables/operators forming the quantum phase space. The entropy is dimensionless, it is a relativistic scalar, it is invariant under canonical transformations and under CPT transformations, and its minimum has been established by the entropic uncertainty principle. We expand the entropy to also include mixed states. We show that the entropy is monotonically increasing during a time evolution of coherent states under a Dirac Hamiltonian. However, in a mathematical scenario, when two fermions come closer to each other, each evolving as a coherent state, the total system’s entropy oscillates due to the increasing spatial entanglement. We hypothesize an entropy law governing physical systems whereby the entropy of a closed system never decreases, implying a time arrow for particle physics. We then explore the possibility that as the oscillations of the entropy must by the law be barred in quantum physics, potential entropy oscillations trigger annihilation and creation of particles.
A quantum coordinate-entropy formulated in quantum phase space has been recently proposed together with an entropy law that asserts that such entropy can not decrease over time. The coordinate-entropy is dimensionless, a relativistic scalar, and it is invariant under coordinate and CPT transformations. We study here the time evolution of this entropy. We show that the entropy associated with coherent states evolving under a Dirac Hamiltonian is increasing. However, for the collisions of two particles, where each is evolving as a coherent state, as they come closer to each other their spatial entanglement causes the total system's entropy to oscillate. We augment time reversal with time translation and show that CPT with time translation can transform particles with decreasing entropy for a finite time interval into anti-particles with increasing entropy for the same finite time interval. We then analyze the impact of the entropy law for the evolution scenarios described above and explore the possibility that entropy oscillations trigger the annihilation and the creation of particles.
This work investigates the fundamental connection between quantum mechanics and thermodynamics through the concept of the arrow of time. While the second law of thermodynamics identifies the arrow of time with the monotonic increase of entropy in isolated systems, closed quantum systems evolve unitarily and conserve von Neumann entropy, making the origin of irreversibility less apparent. Here we establish a no-go theorem proving that correlations in unknown states of closed quantum systems cannot be universally removed by any physical operation. This result demonstrates that correlation generation is inherently irreversible, providing a microscopic and universal basis for the arrow of time. In thermodynamic settings, this irreversibility ensures that heat flows spontaneously from hotter to colder subsystems, reproducing the Clausius formulation of the second law. More generally, the irreversible growth of correlations explains entropy increase, the approach to equilibrium, and decoherence as observable manifestations of the same principle. Our findings ground a quantum-mechanical foundation for the second law of thermodynamics and demonstrate the universality of the arrow of time.
The problem of time’s arrow is (roughly) to understand why macroscopic physical processes typically evolve in a specific direction (the one we call “the future”) even though the underlying laws of physics describing the individual microscopic systems are time-reversal invariant. The standard answer to this problem is given by Boltzmann’s explanation of the II law of thermodynamics: a classical system starting in a non-equilibrium state spontaneously (i.e. with a high level of probability) tends towards equilibrium, thus implementing an irreversible process. However, this explanation has two drawbacks: 1. it needs a further assumption on the entropy of the initial state of the universe (past hypothesis); 2. microscopic systems (e.g. molecules in a box) should be represented as quantum states and not classical states. In this talk, I want to propose a different hypothesis to explain the origin of time’s arrow, based on quantum mechanics, specifically on decoherence theory. Differently from isolated systems, open quantum systems described by decoherence theory showirreversible behavior, as they evolve towards decoherence and von Neumann entropy increase. Is this behavior a sign of genuine irreversibility? And, if so, can this be linked to thermodynamic irreversibility?