Irreversibility is one of the most intriguing concepts in physics. While microscopic physical laws are perfectly reversible, macroscopic average behavior has a preferred direction of time. According to the second law of thermodynamics, this arrow of time is associated with a positive mean entropy production. Using a nuclear magnetic resonance setup, we measure the nonequilibrium entropy produced in an isolated spin-1/2 system following fast quenches of an external magnetic field. We experimentally demonstrate that it is equal to the entropic distance, expressed by the Kullback-Leibler divergence, between a microscopic process and its time reversal. Our result addresses the concept of irreversibility from a microscopic quantum standpoint.
Irreversibility is one of the most intriguing concepts in physics.While microscopic physical laws are perfectly reversible, macroscopic average behavior has a preferred direction of time.According to the second law of thermodynamics, this arrow of time is associated with a positive mean entropy production.Using a nuclear magnetic resonance setup, we measure the nonequilibrium entropy produced in an isolated spin-1=2 system following fast quenches of an external magnetic field.We experimentally demonstrate that it is equal to the entropic distance, expressed by the Kullback-Leibler divergence, between a microscopic process and its time reversal.Our result addresses the concept of irreversibility from a microscopic quantum standpoint.
The problem of time’s arrow is (roughly) to understand why macroscopic physical processes typically evolve in a specific direction (the one we call “the future”) even though the underlying laws of physics describing the individual microscopic systems are time-reversal invariant. The standard answer to this problem is given by Boltzmann’s explanation of the II law of thermodynamics: a classical system starting in a non-equilibrium state spontaneously (i.e. with a high level of probability) tends towards equilibrium, thus implementing an irreversible process. However, this explanation has two drawbacks: 1. it needs a further assumption on the entropy of the initial state of the universe (past hypothesis); 2. microscopic systems (e.g. molecules in a box) should be represented as quantum states and not classical states. In this talk, I want to propose a different hypothesis to explain the origin of time’s arrow, based on quantum mechanics, specifically on decoherence theory. Differently from isolated systems, open quantum systems described by decoherence theory showirreversible behavior, as they evolve towards decoherence and von Neumann entropy increase. Is this behavior a sign of genuine irreversibility? And, if so, can this be linked to thermodynamic irreversibility?
The origin of macroscopic irreversibility from microscopically time-reversible dynamical laws-often called the arrow-of-time problem-is of fundamental interest in both science and philosophy. Experimentally probing such questions in quantum theory requires systems with near-perfect isolation from the environment and long coherence times. Ultracold atoms are uniquely suited to this task. We experimentally demonstrate a striking parallel between the statistical irreversibility of wavefunction collapse and the arrow of time problem in the weak measurement of the quantum spin of an atomic cloud. Our experiments include statistically rare events where the arrow of time is inferred backward; nevertheless we provide evidence for absolute irreversibility and a strictly positive average arrow of time for the measurement process, captured by a fluctuation theorem. We further demonstrate absolute irreversibility for measurements performed on a quantum many-body entangled wavefunction-a unique opportunity afforded by our platform-with implications for studying quantum many-body dynamics and quantum thermodynamics.
Abstract Microscopic physical laws are time-symmetric, hence, a priori there exists no preferential temporal direction. However, the second law of thermodynamics allows one to associate the “forward” temporal direction to a positive variation of the total entropy produced in a thermodynamic process, and a negative variation with its “time-reversal” counterpart. This definition of a temporal axis is normally considered to apply in both classical and quantum contexts. Yet, quantum physics admits also superpositions between forward and time-reversal processes, whereby the thermodynamic arrow of time becomes quantum-mechanically undefined. In this work, we demonstrate that a definite thermodynamic time’s arrow can be restored by a quantum measurement of entropy production, which effectively projects such superpositions onto the forward (time-reversal) time-direction when large positive (negative) values are measured. Finally, for small values (of the order of plus or minus one), the amplitudes of forward and time-reversal processes can interfere, giving rise to entropy-production distributions featuring a more or less reversible process than either of the two components individually, or any classical mixture thereof.
The second law permits the prediction of the direction of natural processes, thus defining a thermodynamic arrow of time. However, standard thermodynamics presupposes the absence of initial correlations between interacting systems. We here experimentally demonstrate the reversal of the arrow of time for two initially quantum correlated spins-1/2, prepared in local thermal states at different temperatures, employing a Nuclear Magnetic Resonance setup. We observe a spontaneous heat flow from the cold to the hot system. This process is enabled by a trade off between correlations and entropy that we quantify with information-theoretical quantities.
We present a unified operational framework for the arrow of time grounded in irreversible information loss. While microscopic physical laws are time-reversal invariant, macroscopic irreversibility arises when systems overwrite metastable records. We show that recent reversible quantum-control experiments do not reverse time, but instead operate in regimes where no logically irreversible record is created. To formalize this, we introduce the **forgetting rate**
(Ξcr), a coarse-grained rate defined on physically selected metastable record states (e.g., pointer states, memory registers, or macroscopic configurations). Unlike standard entropy production, which is expressed in terms of microscopic transition asymmetry,
(Ξcr) captures the **rate of irreversible record overwriting**. In this formulation, entropy production obeys the lower bound
S˙irr≥kBΞcr,consistent with Landauer's principle but expressed at the level of record dynamics. Within this framework, thermodynamic, quantum-measurement, psychological, and cosmological arrows emerge as substrate-dependent manifestations of
Ξcr>0. Temporal asymmetry is therefore not a single global property, but a distributed feature of physical information-processing systems. The approach naturally explains the decoupling of arrows in composite systems and identifies experimentally accessible regimes where irreversibility can be locally suppressed. This work does not introduce a new microscopic law but provides a unifying, operational reformulation that connects information thermodynamics, decoherence theory, and memory dynamics through a single coarse-grained rate.