A priori, there exists no preferential temporal direction as microscopic physical laws are time-symmetric. Still, the second law of thermodynamics allows one to associate the `forward' temporal direction to a positive entropy variation in a thermodynamic process, and a negative variation with its `time-reversal' counterpart. This definition of a temporal axis is normally considered to apply in both classical and quantum contexts. Yet, quantum physics admits also superpositions between forward and time-reversal processes, thereby seemingly eluding conventional definitions of time's arrow. In this work, we demonstrate that a quantum measurement of entropy can distinguish the two temporal directions, effectively projecting such superpositions of thermodynamic processes onto the forward (time-reversal) time-direction when large positive (negative) values are measured. Remarkably, for small values (of the order of plus or minus one), the amplitudes of forward and time-reversal processes can interfere, giving rise to entropy distributions featuring a more or less reversible process than either of the two components individually, or any classical mixture thereof. Finally, we extend these concepts to the case of a thermal machine running in a superposition of the heat engine and the refrigerator mode, illustrating how such interference effects can be employed to reduce undesirable fluctuations.
A priori, there exists no preferential temporal direction as microscopic physical laws are time-symmetric. Still, the second law of thermodynamics allows one to associate the forward' temporal direction to a positive entropy variation in a thermodynamic process, and a negative variation with its time-reversal' counterpart. This definition of a temporal axis is normally considered to apply in both classical and quantum contexts. Yet, quantum physics admits also superpositions between forward and time-reversal processes, thereby seemingly eluding conventional definitions of time's arrow. In this work, we demonstrate that a quantum measurement of entropy can distinguish the two temporal directions, effectively projecting such superpositions of thermodynamic processes onto the forward (time-reversal) time-direction when large positive (negative) values are measured. Remarkably, for small values (of the order of plus or minus one), the amplitudes of forward and time-reversal processes can interfere, giving rise to entropy distributions featuring a more or less reversible process than either of the two components individually, or any classical mixture thereof. Finally, we extend these concepts to the case of a thermal machine running in a superposition of the heat engine and the refrigerator mode, illustrating how such interference effects can be employed to reduce undesirable fluctuations.
Abstract Microscopic physical laws are time-symmetric, hence, a priori there exists no preferential temporal direction. However, the second law of thermodynamics allows one to associate the “forward” temporal direction to a positive variation of the total entropy produced in a thermodynamic process, and a negative variation with its “time-reversal” counterpart. This definition of a temporal axis is normally considered to apply in both classical and quantum contexts. Yet, quantum physics admits also superpositions between forward and time-reversal processes, whereby the thermodynamic arrow of time becomes quantum-mechanically undefined. In this work, we demonstrate that a definite thermodynamic time’s arrow can be restored by a quantum measurement of entropy production, which effectively projects such superpositions onto the forward (time-reversal) time-direction when large positive (negative) values are measured. Finally, for small values (of the order of plus or minus one), the amplitudes of forward and time-reversal processes can interfere, giving rise to entropy-production distributions featuring a more or less reversible process than either of the two components individually, or any classical mixture thereof.
This study proposes a time-symmetric framework for quantum measurement that restores microscopic reversibility at the level of the dynamical description while remaining compatible with causality and thermodynamic consistency. Instead of invoking a stochastic wavefunction collapse, the measurement process is modeled as a bidirectional informational update between a forward-evolving state and a backward-propagating effect, governed by a completely positive generator and its adjoint. Within this operator-based formalism, pre- and post-selected statistics are treated on an equal footing, yielding a unified description of both. The proposed scheme rigorously preserves complete positivity, normalization, and the no-signalling principle, and it is shown to satisfy Spohn's inequality for the associated quantum Markov semigroup, thereby ensuring non-negative entropy production within this setting. The framework admits a direct experimental interpretation across a range of scenarios, including weak measurements, EPR-Bell tests, homodyne detection, and photon counting. Furthermore, in the classical limit, the bidirectional update is demonstrated to reduce to the well-established Kalman filter and Rauch-Tung-Striebel (RTS) smoother used in classical estimation theory. These results support the view that the apparent temporal asymmetry of quantum measurement arises not from fundamental dynamical irreversibility, but from informational conditioning, specifically, the one-sided way in which measurement outcomes are incorporated into our description. In this sense, the arrow of time in measurement theory may be understood as an arrow of information.
While the microscopic laws of physics are often symmetric under time reversal, most natural processes that we observe are not. The emergent asymmetry between typical and time-reversed processes is referred to as the arrow of time. In quantum physics, an arrow of time emerges when a sequence of measurements is performed on a system. We introduce quantum control tools that can yield dynamics more consistent with time flowing backward than forward. The control tools are based on the explicit construction of a Hamiltonian that can replicate the stochastic trajectories of a monitored quantum system. Such a Hamiltonian can reverse the effect of monitoring and, via a feedback process, generate trajectories consistent with a reversed arrow of time. It can also be used to simulate the backward-in-time dynamics of an open quantum system. Finally, we design a feedback-driven continuous measurement engine powered by the energy pumped into the system by the monitoring process. We show that the engine can operate under experimentally realizable conditions with feedback delay and finite-efficiency measurements.
The second law permits the prediction of the direction of natural processes, thus defining a thermodynamic arrow of time. However, standard thermodynamics presupposes the absence of initial correlations between interacting systems. We here experimentally demonstrate the reversal of the arrow of time for two initially quantum correlated spins-1/2, prepared in local thermal states at different temperatures, employing a Nuclear Magnetic Resonance setup. We observe a spontaneous heat flow from the cold to the hot system. This process is enabled by a trade off between correlations and entropy that we quantify with information-theoretical quantities.
The Second Law of Thermodynamics is considered to be one of the most fundamental and important laws of Physics. Both Clausius and Kelvin reformulated the Second Law as statements concerning the behaviour of two communicating systems, set to interact at different temperatures. The average positive entropy production of any process, described by the Second Law, is often understood as a "thermodynamic arrow of time" capable of discerning the direction in which physical events should arrange. By studying a microscopic system described by two initially correlated qubits, in this thesis we explore the phenomenon of reverse energy flow. Differently from an often standard uncorrelated case, the correlated one shows properties that seem to suggest that a further generalization of both Clausius and Kelvin's statements is needed
All the laws of physics are time-reversible. Time arrow emerges only when ensembles of classical particles are treated probabilistically, outside of physics laws, and the entropy and the second law of thermodynamics are introduced. In quantum physics, no mechanism for a time arrow has been proposed despite its intrinsic probabilistic nature. In consequence, one cannot explain why an electron in an excited state will "spontaneously" transition into a ground state as a photon is created and emitted, instead of continuing in its reversible unitary evolution. To address such phenomena, we introduce an entropy for quantum physics, which will conduce to the emergence of a time arrow. The entropy is a measure of randomness over the degrees of freedom of a quantum state. It is dimensionless; it is a relativistic scalar, it is invariant under coordinate transformation of position and momentum that maintain conjugate properties and under CPT transformations; and its minimum is positive due to the uncertainty principle. To excogitate why some quantum physical processes cannot take place even though they obey conservation laws, we partition the set of all evolutions of an initial state into four blocks, based on whether the entropy is (i) increasing but not a constant, (ii) decreasing but not a constant, (iii) a constant, (iv) oscillating. We propose a law that in quantum physics entropy (weakly) increases over time. Thus, evolutions in the set (ii) are disallowed, and evolutions in set (iv) are barred from completing an oscillation period by instantaneously transitioning to a new state. This law for quantum physics limits physical scenarios beyond conservation laws, providing causality reasoning by defining a time arrow.