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arXiv:2202.04619 · EMS Press eBooks

Irreversibility and the arrow of time

Jürg Martin Fröhlich

Published Jun 29, 2022• 5 citations
arXivHTMLPDF

Abstract

Within the general formalism of quantum theory irreversibility and the arrow of time and the in the evolution of various physical systems are studied. Irreversible behavior often manifests itself in the guise of “entropy production.” This motivates me to begin this chapter with a brief review of quantum-mechanical entropy, a subject that Elliott Lieb has made outstanding contributions to, followed by an enumeration of examples of irreversible behavior and of an arrow of time analyzed in later sections. Subsequently, a derivation of the laws of thermodynamics from (quantum) statistical mechanics, and, in particular, of the Second Law of thermodynamics, in the forms given to it by Clausius and Carnot, is presented. In a third part, results on diffusive (Brownian) motion of a quantum particle interacting with a quasi-free quantum-mechanical heat bath are reviewed. This is followed by an outline of a theory of friction by emission of Cherenkov radiation of sound waves in a system consisting of a particle moving through a Bose–Einstein condensate and interacting with it. In what may be the most important section of this chapter, the fundamental arrow of time inherent in Quantum Mechanics is discussed.

DOI
10.4171/90-1/17

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Within the general formalism of quantum theory irreversibility and the arrow of time and the in the evolution of various physical systems are studied. Irreversible behavior often manifests itself in the guise of “entropy production.” This motivates me to begin this chapter with a brief review of quantum-mechanical entropy, a subject that Elliott Lieb has made outstanding contributions to, followed by an enumeration of examples of irreversible behavior and of an arrow of time analyzed in later sections. Subsequently, a derivation of the laws of thermodynamics from (quantum) statistical mechanics, and, in particular, of the Second Law of thermodynamics, in the forms given to it by Clausius and Carnot, is presented. In a third part, results on diffusive (Brownian) motion of a quantum particle interacting with a quasi-free quantum-mechanical heat bath are reviewed. This is followed by an outline of a theory of friction by emission of Cherenkov radiation of sound waves in a system consisting of a particle moving through a Bose–Einstein condensate and interacting with it. In what may be the most important section of this chapter, the fundamental arrow of time inherent in Quantum Mechanics is discussed.
This work investigates the fundamental connection between quantum mechanics and thermodynamics through the concept of the arrow of time. While the second law of thermodynamics identifies the arrow of time with the monotonic increase of entropy in isolated systems, closed quantum systems evolve unitarily and conserve von Neumann entropy, making the origin of irreversibility less apparent. Here we establish a no-go theorem proving that correlations in unknown states of closed quantum systems cannot be universally removed by any physical operation. This result demonstrates that correlation generation is inherently irreversible, providing a microscopic and universal basis for the arrow of time. In thermodynamic settings, this irreversibility ensures that heat flows spontaneously from hotter to colder subsystems, reproducing the Clausius formulation of the second law. More generally, the irreversible growth of correlations explains entropy increase, the approach to equilibrium, and decoherence as observable manifestations of the same principle. Our findings ground a quantum-mechanical foundation for the second law of thermodynamics and demonstrate the universality of the arrow of time.
The emergence of irreversibility in physical processes, despite the fundamentally reversible nature of quantum mechanics, remains an open question in physics. This thesis explores the intricate relationship between quantum mechanics and thermodynamics, with a particular focus on minimizing entropy production in finite-time processes. By employing tools from quantum information theory and geometric thermodynamics, we tackle the challenge of deriving irreversible thermodynamic behavior from the reversible microscopic framework of quantum mechanics. We begin with a comprehensive review of the laws of thermodynamics, setting the stage for the subsequent analyses. We introduce novel developments in quantum thermodynamics through a generalized framework for geometric thermodynamics, which enables the derivation of finite-time corrections beyond the Markovian regime. Building on this foundation, we extend Landauer's principle by incorporating a finite-time correction that highlights the necessity of strong coupling for optimal information erasure processes. This result underscores the emergence of Planckian time as a fundamental speed limit to thermalization. Additionally, we explore how collective effects can be harnessed to reduce energy dissipation in thermodynamic operations, revealing that classical correlations between systems can significantly mitigate dissipation, though this may pose new questions regarding the third law of thermodynamics. Finally, we optimize thermodynamic processes in mesoscopic systems, including quantum dot engines and information engines. These findings not only enhance our understanding of the fundamental limits of irreversibility but also open new avenues for research. Future works will focus on fully exploiting collective effects, aligning these with the third law of thermodynamics, and understanding the thermodynamic consistency of master equations.
The concept of time presents a profound challenge at the intersection of quantum mechanics and thermodynamics. While fundamental microscopic laws are largely time-symmetric, macroscopic phenomena universally exhibit a distinct thermodynamic arrow of time, characterized by increasing entropy. This paper explores the hypothesis that quantum entanglement plays a crucial role in the emergence of this thermodynamic arrow. We review how the entanglement between a quantum system and its environment leads to decoherence, effectively driving the system towards a state of higher entropy and classical-like behavior. By analyzing concepts such as von Neumann entropy, entanglement entropy, and the Page-Wootters mechanism, we propose a theoretical framework where the degradation and spreading of entanglement act as the underlying mechanism for the perceived unidirectional flow of time. This approach offers a potential resolution to the "problem of time" in quantum gravity and provides a unified perspective on the genesis of irreversibility from the inherently reversible laws of quantum mechanics. We discuss the implications of this entanglement-driven temporal emergence for our understanding of the universe's initial low-entropy state and the fundamental nature of reality.
The problem of time’s arrow is (roughly) to understand why macroscopic physical processes typically evolve in a specific direction (the one we call “the future”) even though the underlying laws of physics describing the individual microscopic systems are time-reversal invariant. The standard answer to this problem is given by Boltzmann’s explanation of the II law of thermodynamics: a classical system starting in a non-equilibrium state spontaneously (i.e. with a high level of probability) tends towards equilibrium, thus implementing an irreversible process. However, this explanation has two drawbacks: 1. it needs a further assumption on the entropy of the initial state of the universe (past hypothesis); 2. microscopic systems (e.g. molecules in a box) should be represented as quantum states and not classical states. In this talk, I want to propose a different hypothesis to explain the origin of time’s arrow, based on quantum mechanics, specifically on decoherence theory. Differently from isolated systems, open quantum systems described by decoherence theory showirreversible behavior, as they evolve towards decoherence and von Neumann entropy increase. Is this behavior a sign of genuine irreversibility? And, if so, can this be linked to thermodynamic irreversibility?
What is the physical origin of the arrow of time? It is a commonly held belief in the physics community that it relates to the increase of entropy as it appears in the statistical interpretation of the second law of thermodynamics. At the same time, the subjective information-theoretical interpretation of probability, and hence entropy, is a standard viewpoint in the foundations of statistical mechanics. In this article, it is argued that the subjective interpretation is incompatible with the philosophical point of view that the arrow of time is a fundamental property of Nature. The subjectivist can only uphold this philosophy if the role played by the second law of thermodynamics in defining time's arrow is abandoned.
What is the physical origin of the arrow of time? It is a commonly held belief in the physics community that it relates to the increase of entropy as it appears in the statistical interpretation of the second law of thermodynamics. At the same time, the subjective information-theoretical interpretation of probability, and hence entropy, is a standard viewpoint in the foundations of statistical mechanics. In this article, it is argued that the subjective interpretation is incompatible with the philosophical point of view that the arrow of time is a fundamental property of Nature. The subjectivist can only uphold this philosophy if the role played by the second law of thermodynamics in defining time's arrow is abandoned.