We study the performance of quantum thermal machines in which the working fluid of the model is represented by a many-body quantum system that is periodically connected with external baths via local couplings. A formal characterization of the limit cycles of the set-up is presented in terms of the mixing properties of the quantum channel that describes the evolution of the fluid over a thermodynamic cycle. For the special case in which the system is a collection of spin 1/2 1 / 2 particles coupled via magnetization preserving Hamiltonians, a full characterization of the possible operational regimes (i.e., thermal engine, refrigerator, heater and thermal accelerator) is provided: in this context we show in fact that the different regimes only depend upon a limited number of parameters (essentially the ratios of the energy gaps associated with the local Hamiltonians of the parts of the network which are in direct thermal contact with the baths).
We study the performance of quantum thermal machines in which the working fluid of the model is represented by a many-body quantum system that is periodically connected with external baths via local couplings. A formal characterization of the limit cycles of the set-up is presented in terms of the mixing properties of the quantum channel that describes the evolution of the fluid over a thermodynamic cycle. For the special case in which the system is a collection of spin 1/2 1 / 2 particles coupled via magnetization preserving Hamiltonians, a full characterization of the possible operational regimes (i.e., thermal engine, refrigerator, heater and thermal accelerator) is provided: in this context we show in fact that the different regimes only depend upon a limited number of parameters (essentially the ratios of the energy gaps associated with the local Hamiltonians of the parts of the network which are in direct thermal contact with the baths).
We identify and interpret the possible quantum thermal machine regimes with a transverse-field Ising model as the working substance. In general, understanding the emergence of such regimes in a many-body quantum system is challenging due to the dependence on the many energy levels in the system. By considering infinitesimal work strokes, we can understand the operation from equilibrium properties of the system. We find that infinitesimal work strokes enable both heat engine and accelerator operation, with the output and boundaries of operation described by macroscopic properties of the system, in particular the net transverse magnetization. At low temperatures, the regimes of operation and performance can be understood from quasiparticles in the system, while at high temperatures an expansion of the free energy in powers of inverse temperature describes the operation. The understanding generalises to larger work strokes when the temperature difference between the hot and cold reservoirs is large. For hot and cold reservoirs close in temperature, a sufficiently large work stroke can enable refrigerator and heater regimes. Our results and method of analysis will prove useful in understanding the possible regimes of operation of quantum many-body thermal machines more generally.
The study of quantum thermodynamics is key to the development of quantum thermal machines. Here we investigate a system of parametrically driven quantum harmonic oscillators coupled to heat baths via a collision model. Using a thermodynamically consistent local master equation, we derive the heat flows and work power of the working device which can operate as an engine or a refrigerator and analyse their instantaneous and averages efficiencies and coefficients of performance. Studying the regimes of both slow and fast driving of the system, we find that an increased driving frequency can lead to a change of functioning to an accelerator or a heater. Finally, we investigate the effect of squeezing one of the thermal baths: it leads to an apparent higher efficiency compared to the corresponding Carnot value of an equilibrium bath with the same temperature and to sustained entanglement between the working substance oscillators in the limit cycle.
A quantum thermal machine can be controlled by time-periodic perturbations that define a cycle, as in conventional macroscopic thermal machines. This paper presents a general and unified approach to the study of quantum thermal machines, including both heat engines and refrigerators, which operate under periodic adiabatic driving and are in contact with thermal reservoirs kept at different temperatures. Importantly, many observables characterizing the operation and the performance of these machines are geometric in nature.
Quantum mechanics has given us a new playground in which to experiment that boasts several unique features. In this thesis, we explore it in the context of thermodynamics: looking at what kind of thermal devices can be constructed and how quantum behaviour affects them. We consider three research strands. In the first part we formulate a selection of heat engines with two-qubit systems, utilising environments that induce quantum correlations into the system. We see that these correlations can have some effects on the work of the engine, but this effect is system dependent. Describing the dynamics of a quantum system in contact with an external environment is often achieved with a master equation. When considering systems comprised of multiple subsystems, the description becomes more complicated and some of the master equations that have been used previously produce unphysical results. In the second part of this thesis we show that if one does the proper analysis of the microscopic derivation of these master equations, then no thermodynamical inconsistencies occur. When one considers a system connected to three or more environments, a whole new set of possible thermodynamical machines becomes available. One notable case of these is the absorption refrigerator, which performs refrigeration without the need for an external work source. For the third part, we show how one can construct an absorption refrigerator using a three-qubit system with two-body interactions and describe its operation. We also show some thermal control properties of the three-qubit system.
The study of quantum thermodynamics is key to the development of quantum thermal machines. In contrast to most of the previous proposals based on discrete strokes, here we consider a working substance that is permanently coupled to two or more baths at different temperatures and continuously driven. To this end, we investigate parametrically driven quantum harmonic oscillators coupled to heat baths via a collision model. Using a thermodynamically consistent local master equation, we derive the heat flows and power of the working device, which can operate as an engine, refrigerator, or accelerator, and analyze the instantaneous and average efficiencies and coefficients of performance. Studying the regimes of both slow and fast driving of the system, we find that an increased driving frequency can lead to a change of functioning to a dissipator. Finally, we investigate the effect of squeezing one of the thermal baths: it leads to an apparent higher efficiency compared to the corresponding Carnot value of an equilibrium bath with the same temperature and to sustained entanglement between the working substance oscillators in the limit cycle.
The study of nanoscopic thermal devices attracts an increasing attention, not only because of their key role in understanding the emergence of thermodynamics from quantum theory, but also for the potential use of quantum-mechanical thermal cycles, especially refrigerators, in quantum technologies. This thesis, is devoted to the performance optimization of autonomous (heat-driven) refrigerators. For a quantum refrigerator, one has a full microscopic description of the simple system serving as a working medium, and of its interaction with the external heat baths. This enables a consistent `finite-time? thermodynamic analysis, not relying on any phenomenological assumptions about the leading sources of irreversibility, and allows to establish arguably general performance bounds, essential to benchmark the operation of realistic devices. In particular, tight and model-independent upper bounds for the coefficient of performance at maximum power, are derived here for a class of strongly coupled refrigerators, and seen to hold more generally for other types of heat and power-driven cycles. Remarkably, these ultimate limitations only depend on the particulars of the system-baths interaction at the interface with the object to be cooled. Strategies might be then defined so as to saturate those limits: It is shown how the working medium of the refrigerator may be, for instance, scaled up into a parallel multi-stage configuration, resembling that of macroscopic multi-effect absorption chillers, as a means to increase its cooling power. Similarly, by applying reservoir engineering techniques on selected transitions between the energy states of the working medium, one can mimic exploitable non-equilibrium fluctuations in the baths, capable of boosting the overall power and COP beyond what would be otherwise allowed by the second law of thermodynamics. In this way, heat-driven chillers could be set to compete on a equal footing with the best power-driven refrigerators.