The study of quantum thermodynamics is key to the development of quantum thermal machines. Here we investigate a system of parametrically driven quantum harmonic oscillators coupled to heat baths via a collision model. Using a thermodynamically consistent local master equation, we derive the heat flows and work power of the working device which can operate as an engine or a refrigerator and analyse their instantaneous and averages efficiencies and coefficients of performance. Studying the regimes of both slow and fast driving of the system, we find that an increased driving frequency can lead to a change of functioning to an accelerator or a heater. Finally, we investigate the effect of squeezing one of the thermal baths: it leads to an apparent higher efficiency compared to the corresponding Carnot value of an equilibrium bath with the same temperature and to sustained entanglement between the working substance oscillators in the limit cycle.
The study of quantum thermodynamics is key to the development of quantum thermal machines. Here we investigate a system of parametrically driven quantum harmonic oscillators coupled to heat baths via a collision model. Using a thermodynamically consistent local master equation, we derive the heat flows and work power of the working device which can operate as an engine or a refrigerator and analyse their instantaneous and averages efficiencies and coefficients of performance. Studying the regimes of both slow and fast driving of the system, we find that an increased driving frequency can lead to a change of functioning to an accelerator or a heater. Finally, we investigate the effect of squeezing one of the thermal baths: it leads to an apparent higher efficiency compared to the corresponding Carnot value of an equilibrium bath with the same temperature and to sustained entanglement between the working substance oscillators in the limit cycle.
The study of quantum thermodynamics is key to the development of quantum thermal machines. In contrast to most of the previous proposals based on discrete strokes, here we consider a working substance that is permanently coupled to two or more baths at different temperatures and continuously driven. To this end, we investigate parametrically driven quantum harmonic oscillators coupled to heat baths via a collision model. Using a thermodynamically consistent local master equation, we derive the heat flows and power of the working device, which can operate as an engine, refrigerator, or accelerator, and analyze the instantaneous and average efficiencies and coefficients of performance. Studying the regimes of both slow and fast driving of the system, we find that an increased driving frequency can lead to a change of functioning to a dissipator. Finally, we investigate the effect of squeezing one of the thermal baths: it leads to an apparent higher efficiency compared to the corresponding Carnot value of an equilibrium bath with the same temperature and to sustained entanglement between the working substance oscillators in the limit cycle.
We use the theory of open quantum systems to study quantum thermal machines, deriving their master equations to understand how they evolve in time. We consider three different working substances coupled to heat baths that may act as engines, refrigerators, accelerators or dissipators. The first is a network of driven quantum harmonic oscillators where we study the effect that the driving speed has on the operation of the system. We see how squeezing one of the baths may lead to a more efficient engine as well as the generation of entanglement within the system. We then investigate the use of coherence in the baths as a resource to improve the performance of a quantum thermal machine whose working substance consists of a single qubit. Finally, we introduce a rotor to a system of two qubits to create an autonomous quantum machine capable of converting heat flow into useful mechanical work. We also study both the heat and angular momentum rectification that may be accomplished by this machine.
The laws of thermodynamics put limits to the efficiencies of thermal machines. Analogues of these laws are now established for quantum engines weakly and passively coupled to the environment providing a framework to find improvements to their performance. Systems whose interaction with the environment is actively controlled do not fall in that framework. Here we consider systems actively and locally coupled to the environment, evolving with a so-called boundary-driven Lindblad equation. Starting from a unitary description of the system plus the environment we simultaneously obtain the Lindblad equation and the appropriate expressions for heat, work and entropy-production of the system extending the framework for the analysis of new, and some already proposed, quantum heat engines. We illustrate our findings in spin 1/2 chains and explain why an XX chain coupled in this way to a single heat bath relaxes to thermodynamic-equilibrium while and XY chain does not. Additionally, we show that an XX chain coupled to a left and a right heat baths behaves as a quantum engine, a heater or refrigerator depending on the parameters, with efficiencies bounded by Carnot efficiencies.
The study of nanoscopic thermal devices attracts an increasing attention, not only because of their key role in understanding the emergence of thermodynamics from quantum theory, but also for the potential use of quantum-mechanical thermal cycles, especially refrigerators, in quantum technologies. This thesis, is devoted to the performance optimization of autonomous (heat-driven) refrigerators. For a quantum refrigerator, one has a full microscopic description of the simple system serving as a working medium, and of its interaction with the external heat baths. This enables a consistent `finite-time? thermodynamic analysis, not relying on any phenomenological assumptions about the leading sources of irreversibility, and allows to establish arguably general performance bounds, essential to benchmark the operation of realistic devices. In particular, tight and model-independent upper bounds for the coefficient of performance at maximum power, are derived here for a class of strongly coupled refrigerators, and seen to hold more generally for other types of heat and power-driven cycles. Remarkably, these ultimate limitations only depend on the particulars of the system-baths interaction at the interface with the object to be cooled. Strategies might be then defined so as to saturate those limits: It is shown how the working medium of the refrigerator may be, for instance, scaled up into a parallel multi-stage configuration, resembling that of macroscopic multi-effect absorption chillers, as a means to increase its cooling power. Similarly, by applying reservoir engineering techniques on selected transitions between the energy states of the working medium, one can mimic exploitable non-equilibrium fluctuations in the baths, capable of boosting the overall power and COP beyond what would be otherwise allowed by the second law of thermodynamics. In this way, heat-driven chillers could be set to compete on a equal footing with the best power-driven refrigerators.
The rate of temperature decrease of a cooled quantum bath is studied as its temperature is reduced to absolute zero. The third law of thermodynamics is then quantified dynamically by evaluating the characteristic exponent ζ of the cooling process dT(t)/dt∼-T^{ζ} when approaching absolute zero, T→0. A continuous model of a quantum refrigerator is employed consisting of a working medium composed either by two coupled harmonic oscillators or two coupled two-level systems. The refrigerator is a nonlinear device merging three currents from three heat baths: a cold bath to be cooled, a hot bath as an entropy sink, and a driving bath which is the source of cooling power. A heat-driven refrigerator (absorption refrigerator) is compared to a power-driven refrigerator. When optimized, both cases lead to the same exponent ζ, showing a lack of dependence on the form of the working medium and the characteristics of the drivers. The characteristic exponent is therefore determined by the properties of the cold reservoir and its interaction with the system. Two generic heat bath models are considered: a bath composed of harmonic oscillators and a bath composed of ideal Bose/Fermi gas. The restrictions on the interaction Hamiltonian imposed by the third law are discussed. In the Appendices, the theory of periodically driven open systems and its implication for thermodynamics are outlined.
Abstract In the quest for high-performance quantum thermal machines, looking for an optimal thermodynamic efficiency is only part of the issue. Indeed, at the level of quantum devices, fluctuations become extremely relevant and need to be taken into account. In this paper we study the thermodynamic uncertainty relations for a quantum thermal machine with a quantum harmonic oscillator as a working medium, connected to two thermal baths, one of which is dynamically coupled. We show that parameters can be found such that the machine operates both as a quantum engine or refrigerator, with both sizeable efficiency and small fluctuations.