Quantum mechanics has given us a new playground in which to experiment that boasts several unique features. In this thesis, we explore it in the context of thermodynamics: looking at what kind of thermal devices can be constructed and how quantum behaviour affects them. We consider three research strands. In the first part we formulate a selection of heat engines with two-qubit systems, utilising environments that induce quantum correlations into the system. We see that these correlations can have some effects on the work of the engine, but this effect is system dependent. Describing the dynamics of a quantum system in contact with an external environment is often achieved with a master equation. When considering systems comprised of multiple subsystems, the description becomes more complicated and some of the master equations that have been used previously produce unphysical results. In the second part of this thesis we show that if one does the proper analysis of the microscopic derivation of these master equations, then no thermodynamical inconsistencies occur. When one considers a system connected to three or more environments, a whole new set of possible thermodynamical machines becomes available. One notable case of these is the absorption refrigerator, which performs refrigeration without the need for an external work source. For the third part, we show how one can construct an absorption refrigerator using a three-qubit system with two-body interactions and describe its operation. We also show some thermal control properties of the three-qubit system.
Quantum mechanics has given us a new playground in which to experiment that boasts several unique features. In this thesis, we explore it in the context of thermodynamics: looking at what kind of thermal devices can be constructed and how quantum behaviour affects them. We consider three research strands. In the first part we formulate a selection of heat engines with two-qubit systems, utilising environments that induce quantum correlations into the system. We see that these correlations can have some effects on the work of the engine, but this effect is system dependent. Describing the dynamics of a quantum system in contact with an external environment is often achieved with a master equation. When considering systems comprised of multiple subsystems, the description becomes more complicated and some of the master equations that have been used previously produce unphysical results. In the second part of this thesis we show that if one does the proper analysis of the microscopic derivation of these master equations, then no thermodynamical inconsistencies occur. When one considers a system connected to three or more environments, a whole new set of possible thermodynamical machines becomes available. One notable case of these is the absorption refrigerator, which performs refrigeration without the need for an external work source. For the third part, we show how one can construct an absorption refrigerator using a three-qubit system with two-body interactions and describe its operation. We also show some thermal control properties of the three-qubit system.
We propose a three-qubit setup for the implementation of a variety of quantum thermal machines where all heat fluxes and work production can be controlled. An important configuration that can be designed is that of an absorption refrigerator, extracting heat from the coldest reservoir without the need of external work supply. Remarkably, we achieve this regime by using only two-body interactions instead of the widely employed three-body interactions. This configuration could be more easily realized in current experimental setups. We model the open-system dynamics with both a global and a local master equation thermodynamic-consistent approach. Finally, we show how this model can be employed as a heat valve, in which by varying the local field of one of the two qubits allows one to control and amplify the heat current between the other qubits.
The study of nanoscopic thermal devices attracts an increasing attention, not only because of their key role in understanding the emergence of thermodynamics from quantum theory, but also for the potential use of quantum-mechanical thermal cycles, especially refrigerators, in quantum technologies. This thesis, is devoted to the performance optimization of autonomous (heat-driven) refrigerators. For a quantum refrigerator, one has a full microscopic description of the simple system serving as a working medium, and of its interaction with the external heat baths. This enables a consistent `finite-time? thermodynamic analysis, not relying on any phenomenological assumptions about the leading sources of irreversibility, and allows to establish arguably general performance bounds, essential to benchmark the operation of realistic devices. In particular, tight and model-independent upper bounds for the coefficient of performance at maximum power, are derived here for a class of strongly coupled refrigerators, and seen to hold more generally for other types of heat and power-driven cycles. Remarkably, these ultimate limitations only depend on the particulars of the system-baths interaction at the interface with the object to be cooled. Strategies might be then defined so as to saturate those limits: It is shown how the working medium of the refrigerator may be, for instance, scaled up into a parallel multi-stage configuration, resembling that of macroscopic multi-effect absorption chillers, as a means to increase its cooling power. Similarly, by applying reservoir engineering techniques on selected transitions between the energy states of the working medium, one can mimic exploitable non-equilibrium fluctuations in the baths, capable of boosting the overall power and COP beyond what would be otherwise allowed by the second law of thermodynamics. In this way, heat-driven chillers could be set to compete on a equal footing with the best power-driven refrigerators.
Quantum thermal machines, a sub-field of quantum thermodynamics, are actively studied with the aim to understand the connection between quantum mechanics and thermodynamics. In this work, qubits are used as the active medium in an absorption driven heat pump. The dynamics of this thermal machine are computationally simulated by treating the qubits as an open quantum system interacting with three bosonic heat baths. Some thermodynamic bounds for the system parameters are derived and used in order to define a refrigerating regime for the system.
Thermodynamics is one of the core disciplines of physics, and despite its long history it is still a very active area of research. Particularly in the regime of non-equilibrium processes and at small scales many open questions remain. In this thesis we critically study the role that autonomous machines play in the emerging field of quantum thermodynamics. We show that autonomous machines generally comprise several interacting subsystems that can take on various roles. In Part I we look at the issue of external control. Any non-autonomous machine by definition requires some external agent to interact with the machine. This agent is generally assumed to be classical and to not suffer any back-actions from the machine. If all the involved systems are of microscopic size this approximation is no longer valid and we have to include all the control mechanisms within a unified quantum framework. We show that in order to avoid external control and operate autonomously, a machine that is to extract work from another system requires an inbuilt quantum clock. Being itself a finite-size quantum system, such a clock will inevitably experience back-actions and develop correlations with the other systems, which lead to its degradation as a time keeping device. We show that this degradation can be counteracted by a judicious choice of quantum measurements. These measurements not only allow us to stabilise the clock, but also magnify thermodynamic properties such as work from the quantum scale, where their definition can be ambiguous, to the well understood classical scale. In Part II we consider the scenario of an autonomous quantum machine interacting with a thermal environment, for which we are experimentally restricted to only observe a subset of all the possible environment interactions, while the remaining ones are hidden from direct observation. Using a modification of the notion of quantum jump trajectories we show that the visible interactions in many cases still allow us to make some inferences about the hidden interactions. We introduce a new quantity, the coarse-grained hidden entropy, which quantifies the entropy production in the hidden subsystem conditioned on our observations of the visible part. The total entropy production consisting of the sum of visible and coarse-grained hidden entropy is shown to satisfy an integral fluctuations theorem. Depending on the information flow between the subsystems, the hidden entropy can assume negative values in which case the hidden systems acts as a Maxwell's demon. This behaviour is also captured by a modified second law like inequality which gives a refinement of the conventional second law for autonomous quantum machines with continuous information flows between the machine's subsystems.
Quantum thermodynamics (QT) is an emerging field of research that aims to investigate how the laws of thermodynamics and quantum mechanics merge together in small quantum systems.With advances at the necessary technology to control and measure those small physical systems this field has acquired even more importance, not only in the sense that it can be tested, which is a good thing for basic research, but that new applications could be implemented at these scales, so a better comprehension of the limitations imposed by quantum thermodynamics turns out to be of crucial importance for these goals, which forces theoreticians to produce experimentally relevant versions of these new concepts.Another important aspect present at those systems is that part of them work in a regime where its constituents are described by non-thermal states, and in particular non-thermal steady states, which brings to light a different thermodynamic description, usually called steady-state thermodynamics, therefore one of the goals that we are willing to achieve with this thesis is to give an introduction to QT of systems out-of-equilibrium.One of the related subtopics that physicists deal with in QT and the one that we will be focusing on this work are the use of non-thermal stationary states to build heat engines in the quantum domain, and the analyses of the features that this new regime could possibly allow, like the use of quantum resources as a way to overcome classical limitations imposed on its performance, like to attain efficiencies higher than Carnot's or operate in certain regimes unattainable using only classical resources.Therefore, in order to clarify the underlying physics of those systems in a non-thermal regime, any experimentally well suited content is more than welcome.So keeping that in mind we devised an experimentally relevant thermodynamic cycle for a transmon qubit WS interacting with a non-thermal environment composed by two subsystems, an externally excited cavity and a classical heat bath with temperature T. The WS undergoes a non-conventional cycle (different from Otto, Carnot, etc.) through a succession of non-thermal stationary states obtained by slowly varying its bare frequency and the amplitude of the field applied on the cavity.The efficiency of this engine obtains a maximum value up to 47% in the regime of operation used.We also wanted to look for the role played by the different types of coherences, present at the WS, on the behavior of the engine and its efficiency.By different types of coherence we mean the so called modes of coherence, whose definition is based on how they respond to symmetry transformations.We did that for the trivial case of the qubit, that only contains the modes 1 and -1, and that has shown to be extremely important for the efficiency of the machine.The same procedure was repeated for a 3-level system WS.The modes 1 and -1 was again very important, not only to the absolute value of the engine's efficiency but to the regime of operation of the machine.The additional modes, 2 and -2, had a negative impact on the efficiency, reducing its absolute value.This result appears to show some evidences that quantumness won't necessarily bring improvements to the operation of those machines.
Quantum thermodynamics supplies a consistent description of quantum heat engines and refrigerators up to a single few-level system coupled to the environment. Once the environment is split into three (a hot, cold, and work reservoir), a heat engine can operate. The device converts the positive gain into power, with the gain obtained from population inversion between the components of the device. Reversing the operation transforms the device into a quantum refrigerator. The quantum tricycle, a device connected by three external leads to three heat reservoirs, is used as a template for engines and refrigerators. The equation of motion for the heat currents and power can be derived from first principles. Only a global description of the coupling of the device to the reservoirs is consistent with the first and second laws of thermodynamics. Optimization of the devices leads to a balanced set of parameters in which the couplings to the three reservoirs are of the same order and the external driving field is in resonance. When analyzing refrigerators, one needs to devote special attention to a dynamical version of the third law of thermodynamics. Bounds on the rate of cooling when Tc→0 are obtained by optimizing the cooling current. All refrigerators as Tc→0 show universal behavior. The dynamical version of the third law imposes restrictions on the scaling as Tc→0 of the relaxation rate γc and heat capacity cV of the cold bath.