In the initial stages of its development, atomic theory had to bypass the laws of classical electromagnetism in an ad hoc manner in order to explain the stability of atoms. In quantum mechanics, however, the classical theory may find again some room even for a microscopic structure such as the atom. Provided, of course, that certain classical concepts are reexamined and suitably reinterpreted...
In the initial stages of its development, atomic theory had to bypass the laws of classical electromagnetism in an ad hoc manner in order to explain the stability of atoms. In quantum mechanics, however, the classical theory may find again some room even for a microscopic structure such as the atom. Provided, of course, that certain classical concepts are reexamined and suitably reinterpreted...
The nature of the problem The quantum world is inexplicable in classical terms. The predictions pertaining to the interaction of matter and light embodied in Newton's laws for the motion of particles and Maxwell's equations governing the propagation of electromagnetic fields are in flat contradiction with the experimental facts at the microscopic scale. A key feature of quantum effects is their apparent indeterminism, that individual atomic events are unpredictable, uncontrollable and literally seem to have no cause. Regularities emerge only when one considers a large ensemble of such events. This indeed is generally considered to constitute the heart of the conceptual problem posed by quantum phenomena, necessitating a fundamental revision of the deterministic classical world view. Some of the principal phenomena, among those discussed in this book, are as follows: ( a ) Self-interference: a beam of electrons sent one at a time through a barrier containing two apertures builds up through a series of localized detection events on a screen an interference pattern characteristic of waves (cf. the frontispiece and §5.1). ( b ) Tunnelling: an α-particle trapped in a nucleus can pass through a potential barrier in a manner forbidden to a classical particle (§5.3). ( c ) The stability of matter: atoms and molecules are found to exist only in certain discrete, or ‘stationary’, energy states. For this reason they do not ‘collapse’, the result predicted by classical electrodynamics. During transitions between stationary states (quantum jumps) an atom exchanges a discrete quantity of energy with the electromagnetic field (§§4.5, 7.6). […]
Classical mechanics, which gives a fairly accurate description of large systems (e.g., solar system) as also of mechanical systems in our every day life, however, breaks down when applied to small (microscopic) systems such as molecules, atoms and nuclei. For example, (1) classical mechanics cannot even explain why the atoms are stable at all. A classical atom with electrons moving in circular or elliptic orbits around the nucleus would continuously radiate energy in the form of electromagnetic radiation because an accelerated charge does radiate energy. As a result the radius of the orbit would become smaller and smaller, resulting in instability of the atom. On the other hand, the atoms are found to be remarkably stable in practice. (2) Another fact of observation that classical mechanics fails to explain is wave particle duality in radiation as well as in material particles. It is well known that light exhibits the phenomena of interference, diffraction and polarization which can be easily understood on the basis of wave aspect of radiation. But light also exhibits the phenomena of photo-electric effect, Compton effect and Raman effect which can only be understood in terms of corpuscular or quantum aspect of radiation. The dual behavior of light, or radiation cannot be consistently understood on the basis of classical concepts alone or explained away by saying that light behaves as wave or particle depending on the kind of experiment we do with it (complementarity). Moreover, a beam of material particles, like electrons and neutrons, demonstrates wave-like properties (e.g., diffraction). A brief outline of phenomena that require quantum mechanics for their understanding follows.
When physicists began to explore the world of atoms more precisely, as they endeavoured to understand its structure and the laws governing its behaviour, they soon encountered serious difficulties. Our intuitive concepts, based on our daily experience of the macroscopic world around us, proved to be completely erroneous on the atomic scale; the atom was incomprehensible within the framework of classical physics. In order to uncover these new mysteries, after a great deal of trial and error, entirely new concepts therefore had to be elaborated: the concepts of quantum physics. What are the main stages that have led us to this modern understanding of the atom? What is the present state of atomic physics? How has it contributed to the development of our knowledge and where is it heading?
Quantum mechanics was developed as a response to the inability of the classical theories of mechanics and electromagnetism to provide a satisfactory explanation of some of the properties of electromagnetic radiation and of atomic structure. As a result, a theory has emerged whose basic principles can be used to explain not only the structure and properties of atoms, molecules and solids, but also those of nuclei and of “elementary” particles such as the proton and neutron. Although there are still many features of the physics of such systems that are not fully understood, there are presently no indications that the fundamental ideas of quantum mechanics are incorrect. In order to achieve this success, quantum mechanics has been built on a foundation that contains a number of concepts that are fundamentally different from those of classical physics and which have radically altered our view of the way the physical universe operates. This book aims to elucidate and discuss the conceptual basis of the subject as well as explaining its success in describing the behaviour of atomic and subatomic systems.
The motion of macroscopic objects such as soccer balls, vehicles and planets can be well described using classical mechanics. However, classical mechanics is inadequate to describe the movements or the structure of microscopic objects such as atoms, molecules or nuclei. To properly describe the properties of microscopic objects, the theory of quantum mechanics was developed. While quantum mechanics can be applied to macroscopic objects, it turns out that for objects of large dimensions the quantum mechanical laws evolve naturally into classical mechanics. In general, solving a problem in quantum mechanics is far more difficult than solving it in classical mechanics. Therefore, the laws of classical mechanics are employed when they can be applied safely.
By the end of the nineteenth century all the important elements of classical physics were fully mature. Newton's Laws had been applied with success to everything from industrial machines to planetary orbits. Classical thermodynamics had extended energy conservation arguments into thermal processes, and scientists including J. Willard Gibbs and Ludwig Boltzmann had developed the statistical interpretation of entropy. James Clerk Maxwell had explained all electromagnetic phenomena, from AC generators/motors to light, with the four Maxwell's equations and three material-dependent constitutive relations. There was serious discussion that physics was on the verge of being “finished” – becoming a closed system of knowledge like classical geometry with only essentially routine tasks left of determining how the known laws could be applied to engineering problems. Yet by 1930 the foundations of mechanics, electromagnetics, and atomic-scale systems had been shaken to the core by the new revolutions in the Theory of Relativity, the photon picture of light, and quantum physics. We are still reaping the benefits of the application of these new scientific paradigms in our technology today, including semiconductor electronic devices, lasers, and GPS systems. But the description of reality that these theories provide is still deeply anti-intuitive and disturbing. Nevertheless, quantum physics is one of the most extensively experimentally verified theories that we know. Even when quantum theory and common sense seem to diverge, quantum theory gives the right answers when tested by experiment. In the next chapter we will develop the framework of quantum theory that has been so successful when people “shut up and calculate,” as one scientist suggested as the way through the philosophical thicket of quantum physics. But in this chapter, we will spend a brief time considering the historical development and continuing paradoxical implications of quantum theory. The photoelectric effect and photons In 1905, Albert Einstein, who was a key figure in the revolution of modern physics, was working as a clerk in the patent office in Zurich, Switzerland. Einstein had finished his studies in physics, but had not obtained a coveted position as a university professor. He was intensely interested in the latest developments in classical physics and was aware of a few of the remaining loose ends that were resisting explanation in the classical model.