When physicists began to explore the world of atoms more precisely, as they endeavoured to understand its structure and the laws governing its behaviour, they soon encountered serious difficulties. Our intuitive concepts, based on our daily experience of the macroscopic world around us, proved to be completely erroneous on the atomic scale; the atom was incomprehensible within the framework of classical physics. In order to uncover these new mysteries, after a great deal of trial and error, entirely new concepts therefore had to be elaborated: the concepts of quantum physics. What are the main stages that have led us to this modern understanding of the atom? What is the present state of atomic physics? How has it contributed to the development of our knowledge and where is it heading?
When physicists began to explore the world of atoms more precisely, as they endeavoured to understand its structure and the laws governing its behaviour, they soon encountered serious difficulties. Our intuitive concepts, based on our daily experience of the macroscopic world around us, proved to be completely erroneous on the atomic scale; the atom was incomprehensible within the framework of classical physics. In order to uncover these new mysteries, after a great deal of trial and error, entirely new concepts therefore had to be elaborated: the concepts of quantum physics. What are the main stages that have led us to this modern understanding of the atom? What is the present state of atomic physics? How has it contributed to the development of our knowledge and where is it heading?
Along with weaving together observations, experiments, and theoretical constructs into a coherent mesh of understanding of the world around us, physics over its past five centuries has continuously refined the base concepts on which the whole framework is built. In quantum physics, first in non-relativistic mechanics and later in quantum field theories, even familiar concepts of position, momentum, wave or particle, are derived constructs from the classical limit in which we live but not intrinsic to the underlying physics. Most crucially, the very idea of the individual, whether an object or an event, distinguished only in a mere label of identity from others identical to it in all the physics, exists only as an approximation, not an element of underlying reality. Failure to recognize this and seeking alternative explanations in many worlds or multiverses leads only to incoherent logic and incorrect physics. As an example, in a physical system such as an atom in a particular state, physics deals with the universal system of all such atoms but makes no meaningful prediction of the position of an electron or the time of decay of any specific atom. Those are incidental, entirely random among all possible positions and times, even while physics makes very precise predictions for the distribution of the outcomes in measurements on atoms in that state. Physics deals with the universal, not the individual.
Abstract The attempt to explain atomic structure was one of the main motives for the genesis of quantum mechanics (Bohr’s atomic model, spectral lines, etc.); at the same time it represented the first true testing ground for the new theory. The explanation of the existence of discrete atomic levels, their quantitative prediction, understanding of the periodic structure of the elements, the correct interpretation of chemical bonds, etc., can be regarded without exaggeration as one of the greatest achievements of the scientific thought of our time. A door to an entirely new world— that of the atomic and subatomic phenomena—opened, triggering an impressive advance in basic scientific knowledge and modern technology, unprecedented in human history. The very concepts and many of the mathematical tools of quantum mechanics have, in many cases, sprung from the efforts to solve these problems. In this chapter, we study atomic structure, and try to illustrate some of these features.
The modern physics is characterized by deeper and deeper penetration into the laws of the world of atoms and other minute particles of matter. These laws require not only new experimental techniques to be developed, but also new notions to formulate them. To describe atomic phenomena new methods that are completely different from those used to investigate larger objects of our world are required. The new problem of description of atomic objects is of particular practical importance since the arising notions could be applied to other fields of knowledge. Therefore on the ground of the modern physics some questions of the philosophical character arise. We are going to consider them here.
Along with weaving together observations, experiments, and theoretical constructs into a coherent mesh of understanding of the world around us, physics over its past five centuries has continuously refined the base concepts on which the whole framework is built. In quantum physics, first in nonrelativistic mechanics and later in quantum field theories, even familiar concepts of position, momentum, wave, or particle, are derived constructs from the classical limit in which we live but not intrinsic to the underlying physics. Most crucially, the very idea of the individual, whether an object or an event, distinguished only in a mere label of identity from others identical to it in all the physics, exists only as an approximation, not an element of underlying reality. It is not an element of physics. Failure to recognize this and seeking alternative explanations in many worlds or multiverses leads only to incoherent logic and incorrect physics. As an example, for an atom in a particular state, physics deals with the universal system of all such atoms but makes no meaningful prediction of the position of an electron or the time of decay of any specific atom. Those are incidental, entirely random among all possible positions and times, even while physics makes very precise predictions for the distribution of the outcomes in measurements on atoms in that state. Physics deals with the universal, not the individual.
Quantum Mechanics is an essential topic in today's physics curriculum at both the undergraduate and graduate levels. Quantum mechanics can explain the microscopic world with fantastic accuracy; the fruits from its insights have created technologies that have revolutionized the world. Computers, lasers, mobile telephones, optical communications are but a few examples. The language of quantum mechanics is now an accepted part of the language of physics and day-to-day usage of this language provides physicists with the intuition that is essential for achieving meaningful results. Nevertheless, most physicists acknowledge that, at least once in their scientific career, they have had difficulties understanding the foundations of quantum theory, perhaps even the impression that a really satisfactory and convincing formulation of the theory is still lacking. Numerous quantum mechanics textbooks are available for explaining quantum formalism and applying it to understand problems such as the properties of atoms, molecules, liquids, and solids; the interactions between matter and radiation; and more generally to understand the physical world that surrounds us. Other texts are available for elucidating the historical development of this discipline and describing the steps through which it went before quantum mechanics reached its modern formulation. In contrast, books are rare that review the conceptual difficulties of the theory and then provide a comprehensive overview of the various attempts to reformulate quantum mechanics in order to solve these difficulties. The present text by Franck Laloë does precisely this.
The early twentieth century was a revolutionary time in the history of physics. People often think of Einstein's special theory of relativity of 1905, which changed our conceptions of time and space. But among physicists, quantum mechanics is usually regarded as an even more radical change in our thinking about the physical world. Quantum mechanics, which was developed between 1900 and 1926, began as a theory of atoms and light but has now become the framework in terms of which all basic physical theories are expected to be cast. We need quantum ideas not only to understand atoms, molecules, and elementary particles, but also to understand the electronic properties of solids and even certain astronomical phenomena such as the stability of white dwarf stars. The theory was radical in part because it introduced probabilistic behavior as a fundamental aspect of the world, but even more because it seems to allow mutually exclusive situations to exist simultaneously in a “quantum superposition.” We will see later that the possibility of quantum superposition is largely responsible for a quantum computer's distinctive advantage over an ordinary computer. The present chapter is devoted to introducing the basic principles of quantum mechanics. There are essentially four components of the mathematical structure of quantum mechanics. We need to know how to represent (i) states, (ii) measurements, (iii) reversible transformations, and (iv) composite systems. We will develop the first three in stages, starting with a very simple case – linear polarization of photons – and working toward the most general case.