NEED FOR QUANTUM MECHANICS AND ITS PHYSICAL BASIS

Abstract

Classical mechanics, which gives a fairly accurate description of large systems (e.g., solar system) as also of mechanical systems in our every day life, however, breaks down when applied to small (microscopic) systems such as molecules, atoms and nuclei. For example, (1) classical mechanics cannot even explain why the atoms are stable at all. A classical atom with electrons moving in circular or elliptic orbits around the nucleus would continuously radiate energy in the form of electromagnetic radiation because an accelerated charge does radiate energy. As a result the radius of the orbit would become smaller and smaller, resulting in instability of the atom. On the other hand, the atoms are found to be remarkably stable in practice. (2) Another fact of observation that classical mechanics fails to explain is wave particle duality in radiation as well as in material particles. It is well known that light exhibits the phenomena of interference, diffraction and polarization which can be easily understood on the basis of wave aspect of radiation. But light also exhibits the phenomena of photo-electric effect, Compton effect and Raman effect which can only be understood in terms of corpuscular or quantum aspect of radiation. The dual behavior of light, or radiation cannot be consistently understood on the basis of classical concepts alone or explained away by saying that light behaves as wave or particle depending on the kind of experiment we do with it (complementarity). Moreover, a beam of material particles, like electrons and neutrons, demonstrates wave-like properties (e.g., diffraction). A brief outline of phenomena that require quantum mechanics for their understanding follows.