We present a methodology to simulate the quantum thermodynamics of thermal machines which are built from an interacting working medium in contact with fermionic reservoirs at a fixed temperature and chemical potential.Our method works at a finite temperature, beyond linear response and weak systemreservoir coupling, and allows for nonquadratic interactions in the working medium.The method uses mesoscopic reservoirs, continuously damped toward thermal equilibrium, in order to represent continuum baths and a novel tensor-network algorithm to simulate the steady-state thermodynamics.Using the example of a quantum-dot heat engine, we demonstrate that our technique replicates the well-known Landauer-Büttiker theory for efficiency and power.We then go beyond the quadratic limit to demonstrate the capability of our method by simulating a three-site machine with nonquadratic interactions.Remarkably, we find that such interactions lead to power enhancement, without being detrimental to the efficiency.Furthermore, we demonstrate the capability of our method to tackle complex many-body systems by extracting the superdiffusive exponent for high-temperature transport in the isotropic Heisenberg model.Finally, we discuss transport in the gapless phase of the anisotropic Heisenberg model at a finite temperature and its connection to charge conjugation parity, going beyond the predictions of single-site boundary driving configurations.
We present a methodology to simulate the quantum thermodynamics of thermal machines which are built from an interacting working medium in contact with fermionic reservoirs at a fixed temperature and chemical potential.Our method works at a finite temperature, beyond linear response and weak systemreservoir coupling, and allows for nonquadratic interactions in the working medium.The method uses mesoscopic reservoirs, continuously damped toward thermal equilibrium, in order to represent continuum baths and a novel tensor-network algorithm to simulate the steady-state thermodynamics.Using the example of a quantum-dot heat engine, we demonstrate that our technique replicates the well-known Landauer-Büttiker theory for efficiency and power.We then go beyond the quadratic limit to demonstrate the capability of our method by simulating a three-site machine with nonquadratic interactions.Remarkably, we find that such interactions lead to power enhancement, without being detrimental to the efficiency.Furthermore, we demonstrate the capability of our method to tackle complex many-body systems by extracting the superdiffusive exponent for high-temperature transport in the isotropic Heisenberg model.Finally, we discuss transport in the gapless phase of the anisotropic Heisenberg model at a finite temperature and its connection to charge conjugation parity, going beyond the predictions of single-site boundary driving configurations.
Advances in experimental techniques have opened new routes for harnessing non-equilibrium dynamics in mesoscopic quantum systems. In this context, we study the impact of on-site interactions on the transport properties of a continuous quantum thermal machine composed of two coupled oscillators connected to two thermal reservoirs. In the weak system-reservoir coupling regime, where a long-standing debate concerns which reduced description should be preferred, we first show that the Redfield master equation (RME) provides an accurate and unifying framework that interpolates between two well-known limits: the \textit{local} and \textit{global} master equations. By relying on the Hierarchy of Pure States (HOPS), a numerically exact stochastic method, we then explore the full parameter space and show that interactions can be leveraged to tune the efficiency of the thermal machine at high temperatures (while leaving it essentially unchanged at low temperatures), induce non-reciprocal transport under asymmetric reservoir couplings, and generate steady-state entanglement within the junction. We derive expressions for system-bath correlators, such as heat and particle currents, consistently across different frameworks. Our work features on-site interactions to enhance the versatility of quantum thermodynamic junctions and clarifies the role of non-Markovianity and non-linearities in quantum transport.
Technological and scientific advances have given rise to an era in which coherent quantum-mechanical phenomena can be probed and experimentally-realised over unprecedented timescales in condensed matter physics. In turn, scientific interest in non-equilibrium dynamics and irreversibility signatures of thermodynamics has taken place in recent decades, particularly in relation to cold-atom platforms and thermoelectric devices. In this PhD thesis I summarise some of the most important results obtained over the duration of my PhD, on the topic of thermodynamics involving interacting many-body quantum systems. The topics of discussion encompass three main themes: spin/particle transport in non-integrable systems, explorations in eigenstate thermalisation and finite-temperature transport in autonomous thermal machines. By questioning the effect of local integrability-breaking perturbations, I describe the subtle effects that may rise from conservation laws and their connection to linear response transport using microscopic models. Then, I describe thermalisation in the context of the eigenstate thermalisation hypothesis and its consequence to multipartite entanglement and high-order correlation functions. Finally, motivated by the necessity of describing quantum thermal machines in the finite-temperature regime, I introduce a novel tensor-network based method to investigate thermodynamic properties of autonomous machines that employ interacting many-body systems as working media.
The concept of thermal machines has evolved from the canonical steam engine to the recently proposed nanoscopic quantum systems as working fluids. The latter obey quantum open system dynamics and frequently operate in nonequilibrium conditions. However, the role of this dynamics in the overall performance of quantum heat engines remains an open problem. Here we analyze and optimize the efficiency and power output of two-stage quantum heat engines fueled by nonequilibrium steady states. In a charging first stage, the quantum working fluid consisting of a qutrit or two coupled qubits is connected to two reservoirs at different temperatures, which establish a heat current that stores ergotropy in the system; the second stage comprises a coherent driving force that extracts work from the machine in finite a amount of time; finally, the external drive is switched off and the machine enters a new cycle.
Tensor network methods have become a powerful class of tools to capture strongly correlated matter, but methods to capture the experimentally ubiquitous family of models at finite temperature beyond one spatial dimension are largely lacking. We introduce a tensor network algorithm able to simulate thermal states of two-dimensional quantum lattice systems in the thermodynamic limit. The method develops instances of projected entangled pair states and projected entangled pair operators for this purpose. It is the key feature of this algorithm to resemble the cooling down of the system from an infinite temperature state until it reaches the desired finite-temperature regime. As a benchmark, we study the finite-temperature phase transition of the Ising model on an infinite square lattice, for which we obtain remarkable agreement with the exact solution. We then turn to study the finite-temperature Bose-Hubbard model in the limits of two (hard-core) and three bosonic modes per site. Our technique can be used to support the experimental study of actual effectively two-dimensional materials in the laboratory, as well as to benchmark optical lattice quantum simulators with ultracold atoms.
The development of the theory of thermodynamics dates back nearly two centuries, to when the need arose to comprehend and enhance the performance of a novel technology of that era, the heat engine. Extending the classical concepts related to the properties of heat and work into the quantum realm forms the foundation of an emerging field of research known as quantum thermodynamics. To unify the disparate theories of classical thermodynamics and quantum mechanics, a thoroughly developed theoretical framework is necessary. Quantum heat engines provide a fundamental platform for this purpose. Many-body quantum heat engines, in particular, can provide important insights into the potential utilisation of exotic quantum phenomena, such as entanglement and quantum coherence, for building quantum devices that can surpass their classical counterparts in performance. One-dimensional (1D) Bose gases are a paradigmatic example of an interacting quantum many-body system that can be used as a versatile platform for building heat engines to test the thermodynamic theories in the quantum regime. The versatility of this platform comes through the routine experimental realisability of 1D Bose gases, with precise control of their internal and external properties, such as the strength of inter-atomic interactions and external confinement, and the presence of quantum many-body effects. In recent years, there has been an increased focus on exploiting the unique properties of ultracold atomic gases to realize many-body quantum heat engines. Despite this heightened attention and the resulting significant advances at the level of theoretical proposals, experimental feasibility and practical utilization of such engines remains at its infancy. Achieving significant advances at the experimental level requires a deeper understanding of the fundamental components of quantum-gas heat engines. Motivated by this goal, in this thesis we propose a novel and experimentally realistic quantum many-body heat engine that operates in an Otto cycle and uses a weakly interacting harmonically trapped 1D Bose gas as a working fluid. To execute work during the work strokes, we use a quench of the strength of interparticle interactions; when the quench is sudden with respect to the longitudinal dynamics, it maximises the power output. The interaction-induced work strokes are implemented by treating the working fluid as an isolated quantum many-body system undergoing a dynamical evolution starting from a finite temperature thermal equilibrium state. Furthermore, to optimize the performance of this interaction-driven quantum Otto cycle in an experimental scenario, we undertake a comprehensive numerical investigation of the dynamics of the system-reservoir coupling during the heat transfer strokes. We model the heat transfer strokes by treating the working substance as an open quantum many-body system that is coupled to a reservoir.After providing an overview of recent advances in the field of quantum thermodynamics and the background theory of 1D Bose gases in Chapters 1 and 2 we present the main results of this thesis in Chapters 3, 4 and 5. In Chapter 3, we study the individual interaction-induced work strokes of the Otto cycle with a weakly interacting 1D Bose gas as the working fluid. We evaluate the instantaneity of the sudden quench, specifically, identifying the minimum timescales required to perform the sudden quench of the interaction strength without invoking the transverse dynamics. Knowledge of these timescales enables us to perform the sudden quench in an experimental setting while ensuring that the system retains its 1D characteristics and the theory of 1D Bose gas is applicable. Additionally, we determine the time scales governing the opposite scenario of near-adiabatic quench which corresponds to minimum irreversible work in the engine cycle and hence maximum efficiency. This will help us benchmark the sudden quench engine's performance compared to a nearly ideal (near-adiabatic) scenario corresponding to maximum efficiency.Next, in Chapter 4, we analyze the heat transfer strokes of the Otto cycle, where the system is coupled to a reservoir. Using the c-field approach, we simulate the coupling dynamics of the system with both finite and infinite-size reservoirs. During the heat transfer stroke of the quantum Otto cycle, we treat the working fluid as an open quantum many-body system that is in thermal and diffusive contact with another quantum many-body system serving as the reservoir. In our real-time dynamical simulations of the engine strokes, we use a c-field approach based on the stochastic projected Gross-Pitaevskii equation. This approach enables us to treat both the working fluid and the hot and cold reservoirs as independent quantum many-body systems with chemical potential and temperature imbalances. To model the heat transfer strokes of such an engine with a finite-size reservoir, we use a tunnel-coupled model of two quasicondensates that treats both the system and the reservoir microscopically. Our analysis incorporates the impact of both finite-time operation and finite-size reservoirs in the engine cycle to gain a deeper understanding of the operational feasibility of such engines. Our results indicate that, in contrast to the common assumption of near-instantaneous heat transfer between the system and the reservoir, the thermalisation time of the system during these heat transfer strokes is non-negligible when compared to the duration of work strokes even in the near-adiabatic quench. This observation holds true even in the case of coupling the system with an infinite reservoir during the heat transfer strokes. Moreover, we demonstrate that for a finite-size reservoir, the initial dynamics (namely fast initial energy transfer) in the tunnel-coupled model of two quasicondensates can be leveraged to reduce the total driving time and hence increase the power output of the engine. Finally, in Chapter 5, we explore an alternate protocol that involves performing chemical work on the system during the heat transfer strokes to boost the efficiency and power output of the quantum Otto engines with a 1D Bose gas as a working fluid. We compare the performance of the sudden quench engine with an engine driven by a near-adiabatic and a finite-time quench of the interaction strength with respect to the longitudinal dynamics. We then conclude the thesis by summarising our main findings and presenting open questions for future work in the final chapter, Chapter 6.
The study of quantum thermodynamics is key to the development of quantum thermal machines. In contrast to most of the previous proposals based on discrete strokes, here we consider a working substance that is permanently coupled to two or more baths at different temperatures and continuously driven. To this end, we investigate parametrically driven quantum harmonic oscillators coupled to heat baths via a collision model. Using a thermodynamically consistent local master equation, we derive the heat flows and power of the working device, which can operate as an engine, refrigerator, or accelerator, and analyze the instantaneous and average efficiencies and coefficients of performance. Studying the regimes of both slow and fast driving of the system, we find that an increased driving frequency can lead to a change of functioning to a dissipator. Finally, we investigate the effect of squeezing one of the thermal baths: it leads to an apparent higher efficiency compared to the corresponding Carnot value of an equilibrium bath with the same temperature and to sustained entanglement between the working substance oscillators in the limit cycle.