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arXiv:2103.09723 · Physical Review A

Maximally efficient quantum thermal machines fueled by nonequilibrium steady states

Tiago F. F. Santos, Francesco Tacchino, Dario Gerace, Michele Campisi, Marcelo França Santos

Published Jun 29, 2021• 8 citations
arXivHTMLPDF

Abstract

The concept of thermal machines has evolved from the canonical steam engine to the recently proposed nanoscopic quantum systems as working fluids. The latter obey quantum open system dynamics and frequently operate in nonequilibrium conditions. However, the role of this dynamics in the overall performance of quantum heat engines remains an open problem. Here we analyze and optimize the efficiency and power output of two-stage quantum heat engines fueled by nonequilibrium steady states. In a charging first stage, the quantum working fluid consisting of a qutrit or two coupled qubits is connected to two reservoirs at different temperatures, which establish a heat current that stores ergotropy in the system; the second stage comprises a coherent driving force that extracts work from the machine in finite a amount of time; finally, the external drive is switched off and the machine enters a new cycle.

DOI
10.1103/physreva.103.062225

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The concept of thermal machines has evolved from the canonical steam engine to the recently proposed nanoscopic quantum systems as working fluids. The latter obey quantum open system dynamics and frequently operate in nonequilibrium conditions. However, the role of this dynamics in the overall performance of quantum heat engines remains an open problem. Here we analyze and optimize the efficiency and power output of two-stage quantum heat engines fueled by nonequilibrium steady states. In a charging first stage, the quantum working fluid consisting of a qutrit or two coupled qubits is connected to two reservoirs at different temperatures, which establish a heat current that stores ergotropy in the system; the second stage comprises a coherent driving force that extracts work from the machine in finite a amount of time; finally, the external drive is switched off and the machine enters a new cycle.
In this paper, we study the efficiency of charging a quantum battery through optical pumping. The battery consists of a qutrit and is connected to a natural thermal reservoir and an external coherent drive in the limit where its upper energy level can be adiabatically eliminated from the dynamics. In this scenario, the drive plus spontaneous emission optically pumps the intermediate energy level of the qutrit, and the battery can be understood as being charged by an effective higher temperature reservoir that takes it out of equilibrium with the natural reservoir and stores useful energy in it. We also analyze the efficiency of using this battery and charging scheme as the work fluid of a two-stroke thermal machine. The thermal machine includes a fourth level through which work is extracted from the battery via a unitary transformation, therefore setting the limit of maximum efficiency of the machine.
When a quantum system is subject to a thermal gradient it may sustain a steady non-equilibrium heat current, by entering into a so-called non equilibrium steady state (NESS). Here we show that NESS constitute a thermodynamic resource that can be exploited to fuel a quantum heat engine. This adds to the list of recently reported sources available at the nano-scale, such as coherence, entanglement and quantum measurements. We elucidate this concept by showing analytic and numerical studies of a two-qubits quantum battery that is alternatively charged by a thermal gradient and discharged by application of a properly chosen unitary gate. The presence of a NESS for the charging step guarantees steady operation with positive power output. Decreasing the duration of the charging step results in a time periodic steady state accompanied by increased efficiency and output power. The device is amenable to implementation with different nanotechnology platforms.
We use the theory of open quantum systems to study quantum thermal machines, deriving their master equations to understand how they evolve in time. We consider three different working substances coupled to heat baths that may act as engines, refrigerators, accelerators or dissipators. The first is a network of driven quantum harmonic oscillators where we study the effect that the driving speed has on the operation of the system. We see how squeezing one of the baths may lead to a more efficient engine as well as the generation of entanglement within the system. We then investigate the use of coherence in the baths as a resource to improve the performance of a quantum thermal machine whose working substance consists of a single qubit. Finally, we introduce a rotor to a system of two qubits to create an autonomous quantum machine capable of converting heat flow into useful mechanical work. We also study both the heat and angular momentum rectification that may be accomplished by this machine.
Abstract We study the thermodynamic performance of a finite-time non-regenerative quantum Stirling-like cycle used as a heat engine. We consider specifically the case in which the working substance (WS) is a two-level system (TLS). The Stirling cycle is made of two isochoric transformations separated by a compression and an expansion stroke during which the WS is in contact with a thermal reservoir. To describe these two strokes we derive a non-Markovian master equation which allows to study the real-time dynamics of a driven open quantum system with arbitrary fast driving. Following the real-time dynamics of the WS using this master equation, the endpoints of the isotherms can deviate from the equilibrium thermal states. The role of this deviation in the performance of the heat engine is addressed. We found that the finite-time dynamics and thermodynamics of the cycle depend non-trivially on the different time scales at play. In particular, driving the WS at a time scale comparable to the resonance time of the bath enhances the performance of the cycle and allows for an efficiency higher than the efficiency of the quasistatic cycle, but still below the Carnot bound. However, by adding thermalization of the WS with the baths at the end of compression/expansion processes one recovers the conventional scenario in which efficiency decreases by speeding up the processes. In addition, the performance of the cycle is dependent on the compression/expansion speeds asymmetrically, which suggests new freedom in optimizing quantum heat engines. The maximum output power and the maximum efficiency are obtained almost simultaneously when the real-time endpoints of the compression/expansion processes are considered instead of the equilibrium thermal endpoint states. However, the net extractable work always declines by speeding up the drive.
This paper explores quantum heat engines based on qubit and qutrit working media interacting with thermal environments through generalized amplitude damping (GAD) channels. We investigate how quantum channels can be employed to model heat absorption, dissipation, and work extraction in open quantum thermal machines, and derive the conditions required for positive work extraction. The effects of quantum correlations, emission probability, population redistribution, and system--environment interactions on the thermodynamic performance of the engine are systematically analyzed across different operational regimes. In addition, we examine the ergotropy of qubit and qutrit systems under dissipative dynamics to understand how environmental effects influence the maximum extractable work. Our results demonstrate that multilevel quantum systems exhibit enhanced work extraction capability and improved robustness against decoherence compared to two-level systems, providing further insight into the role of dissipative dynamics and quantum resources in realistic quantum thermodynamic devices.
We study the statistical distribution of the ergotropy and of the efficiency of a single-qubit battery ad of a single-qubit Otto engine, respectively fueled by random collisions. The single qubit, our working fluid, is assumed to exchange energy with two reservoirs: a nonequilibrium "hot" reservoir and a zero-temperature cold reservoir. The interactions between the qubit and the reservoirs are described in terms of a collision model of open system dynamics. The qubit interacts with the nonequilibrium reservoir (a large ensemble of qudits all prepared in the same pure state) via random unitary collisions and with the cold reservoir (a large ensemble of qubits in their ground state) via a partial swap. Due to the random nature of the interaction with the hot reservoir, fluctuations in ergotropy, heat, and work are present, shrinking with the size of the qudits in the hot reservoir. While the mean, "macroscopic" efficiency of the Otto engine is the same as in the case in which the hot reservoir is a thermal one, the distribution of efficiencies does not support finite moments, so that the mean of efficiencies does not coincide with the macroscopic efficiency.